• Title/Summary/Keyword: Low-chlorine

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AC Electrical Treeing Phenomena in an Epoxy System with Low-chlorine BDGE at Various Electric Field Frequencies

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.6
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    • pp.324-328
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    • 2013
  • An alternating current (AC) electrical treeing phenomena in an epoxy system with low chlorine BDGE (1,4-butanediol diglycidyl ether) was studied in a needle-plate electrode arrangement. To measure the treeing propagation rate and breakdown time, a constant AC of 10 kV with three different electric field frequencies (60, 500, and 1,000 Hz) was applied to the needle-plate electrode specimen at $130^{\circ}C$ in aninsulating oil bath. The treeing propagation rate of the DGEBA/high-chlorine BDGE system was higher than that of the DGEBA/low-chlorine BDGE system and the breakdown time of the system with high-chlorine BDGE was lower than that of the system with low-chlorine BDGE. These results implied that chlorine had a negative effect on the electrical insulation property of the epoxy system. As the electric field frequency increased, the treeing propagation rate increased and the breakdown time decreased.

Behavior of Organic Matter, Chlorine Residual and Disinfection By-Products (DBPs) Formation during UV Treatment of Wastewater Treatment Plant Effluents (하수처리장 방류수의 UV 처리시 유기물질, 잔류염소 및 소독부산물 생성 거동)

  • Han, Jihee;Sohn, Jinsik
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.1
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    • pp.61-72
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    • 2014
  • Study on effluent organic matter (EfOM) characteristic and removal efficiency is required, because EfOM is important in regard to the stability of effluents reuse, quality issues of artificial recharge and water conservation of aqueous system. UV technology is widely used in wastewater treatment. Many reports have been conducted on microbial disinfection and micro pollutant reduction with UV treatment. However, the study on EfOM with UV has limited because low/medium pressure UV lamp is not sufficient to affect refractory organics. The high intensity of pulsed UV would mineralize EfOM itself as well as change the characteristics of EfOM. Chlorine demand and DBPs formation is affected on the changed amounts and properties of EfOM. The objective of this study is to investigate the effect on EfOM, chlorine residual, and chlorinated DBPs formation with low pressure and pulsed UV treatment. The removal of organic matter through low pressure UV treatment is insignificant effect. Pulsed UV treatment effectively removes/transforms EfOM. As a result, the chlorine consumption is changed and chlorine DBPs formation is decreased. However, excessive UV treatment caused problems of increasing chlorine consumption and generating unknown by-products.

An Equilibrium Analysis to Determine the Speciation of Metals in the Incineration of Waste Containing Chlorine and Sulfur (염소와 황을 함유한 폐기물의 소각시 생성되는 유해 중금속류 결정에 대한 화학평형 계산)

  • Lee, Jung-Jin;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.1 no.1
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    • pp.31-39
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    • 1996
  • An equilibrium analysis was carried out to determine principal species in the incineration of hazardous waste, which was assumed as a compound of hydrocarbon fuel, chlorine, sulfur, and heavy metals, and their behaviors with variation of temperature, chlorine and sulfur concentrations. Calculated results showed that the most important parameter influencing the principal species was temperature. Chlorine concentration affected on mole fractions of the species, especially at high temperature. Existence of sulfur had a significant effect on the species at low temperature, regardless of surfur concentration. Generally, principal species at high temperature were chlorides and oxides, while the principal species at low temperature were sulfides. As temperature increased, mole fractions of the principal species increased at low temperature, however, mole fractions of some metal species decreased at high temperature.

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Trihalomethane Formation by Chlorine Dioxide in Case of Water Containing Bromide Ion (브롬이온을 함유한 상수 원수에 이산화염소 주입시 THM생성거동에 관한 연구)

  • Lee, Yoon-Jin;Lee, Hwan;Nam, Sang-Ho
    • Journal of Environmental Health Sciences
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    • v.25 no.3
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    • pp.83-88
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    • 1999
  • This study was carried out to examine the behavior of THM formation in water treated with chlorine dioxide where humic acid was used as THM precursor. THM was not detected in bromide-free water, but formed in water containing bromide. When 10 mg/l of chlorine dioxide was added to water containing 5 mg/l of humic acid and bromide respectively, 20.46 ${\mu}$g/l of THM was formed. It is postulated that chlorine dioxide oxidize bromide to hydrobromous acid, which subsequently reacted with humic acids similar to chlorine reaction. The formation of THM could be reduced at low pH. Among THM formed, CHBr$_3$ was the predominant species in the alkaline solution, while CHCl$_3$ in the acidic solution. A sample pretreated with chlorine dioxide for 24h before addition of chlorine showed a reduction of 75.1% in THM formation, compared with a sample not pretreated with chlorine dioxide and a sample treated by chlorine for 24h prior to addition of chlorine dioxide also showed a reduction of 37.8% in THM formation, compared with a sample not added with chlorine dioxide. It may explain that chlorine dioxide oxidizes directly a fraction of THM.

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STUDIES ON THE CHLORINE OF BURLEY TOBACCO PLANTS I. CHLORINE CONTENT OF THE SOIL AND CURED LEAF IN BURLEY TOBACCO GROWING AREA (버어리종 담배의 염소에 관한 연구 I. 버어리종 담배산지의 토양과 잎담배의 염소함량 실태)

  • 김상범;배길관
    • Journal of the Korean Society of Tobacco Science
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    • v.8 no.1
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    • pp.49-56
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    • 1986
  • To obtain the information of low chlorine leaf production, the chlorine content of the soil and cured leaf in Burley tobacco growing area was investigated. The results obtained are as follows. 1. The chlorine concentration in soil at transplanting time in Kwang-ju growing area was higher than in Jeon-ju(1983), and paddy field sell showed higher concentration of chlorine than upland field in Jeon-ju(1984). The chlorine concentration in soil was different between years, locations, and cultivated land (paddy field and upland field), but the concentration, on the whole, was under the levels that might effect the leaf quality. 2. The chlorine concentration In soil was highest around todays after transplanting, and after harvesting, the concentration decreased to half of transplanting time. 3. The distribution of chlorine through the parts of tobacco plant showed remarkable difference between years, locations, cultivated land and growing stages. 4. There was significant positive correlation between chlorine concentration in top soil and chlorine content of cured leaf. 5. Chlorine content of cured leaf in Kwang-ju area(1.79%) was higher than that of Jeon-ju area(O.79%), relatively. 6. It was considered that the accumulation of salt from the sea by sea. wind did not main factor of high leaf chlorine content in seaside district.

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Mathematical Model Simulations Assessing the Effects of Temperature on Residual Chlorine Concentrations in Water Storage Tanks (온도 변화에 따른 수돗물 저장 저수조 내 잔류염소에 관한 수학적 모형 시뮬레이션)

  • Noh, Yoorae;Park, Joonhong
    • Journal of Korean Society on Water Environment
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    • v.33 no.2
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    • pp.187-196
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    • 2017
  • To ensure hygienic safety of drinking water in a water storage tank, the concentrations of residual chlorine should be above a certain regulation level. In this study, we conducted model simulations to investigate the effects of temperature on residual chlorine in water storage tank conditions typically used in Seoul. For this, values of model parameters (decomposition rate constant, sorption coefficient, and evaporation mass transfer coefficient) were experimentally determined from laboratory experiments. The model simulations under continuous flow conditions showed that the residual chlorine concentrations were satisfied the water quality standard level (0.1 mg/L) at all the temperature conditions ($5^{\circ}C$, $10^{\circ}C$, $15^{\circ}C$, $20^{\circ}C$ and $25^{\circ}C$). Meanwhile, when the tanks had a no flow condition (i.e., no tap-water influent due to a sudden shut-down), the concentrations became lower than the regulatory level after certain periods. The findings from this modeling works simulating Seoul's water storage tanks suggested disappearance rate of residual chlorine could be reduced through the tanks design optimization with maintenance of low water temperature, minimization of air flow and volume, suppression of dispersion and the use of wall materials with low sorption ability.

Chlorine Residual Prediction in Drinking Water Distribution System Using EPANET (EPANET을 이용한 상수도 관망의 잔류염소 거동 예측)

  • 유희종;김주원;정효준;이홍근
    • Journal of Environmental Health Sciences
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    • v.29 no.1
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    • pp.8-15
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    • 2003
  • In this study, chlorine dose at water storage tank was predicted to meet the recommended guideline for free chlorine residual in drinking water distribution system, using EPANET which is a computer program that performs extended Period simulation of hydraulic and water quality behavior within pressurized pipe networks. The results may be summarized as follows. The decay of chlorine residual by season varied considerably in the following order; in summer ($25^{\circ}C$) > spring and fall (15$^{\circ}C$) > winter (5$^{\circ}C$). For re-chlorination at water storage tank by season, season-varying chlorine dose was required at its maximum of 1.00 mg/l in summer and minimum of 0.40 mg/l in winter as free chlorine residual. The decay of chlorine residual through out the networks increased with water age spent by a parcel of water in the network except for some points with low water demand. In conclusion, the season-varying chlorine dose as well as the monitoring of water quality parameters at the some points which showed high decay of chlorine residual may be necessary to deliver the safe drinking water.

Effect of Electrochemical Treatment on the Chlorine Generation Efficiency of Ballast Water in the Brackish Zone (기수지역 선박평형수의 염소 생성 효율에 미치는 전기화학 처리의 영향)

  • Choi, Yong-Sun;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.16-22
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    • 2019
  • Indirect oxidation using chlorine species oxidizing agents is often effective in wastewater treatment using an electrochemical oxidation process. When chlorine ions are contained in the wastewater, oxidizing agents of various chlorine species are produced during electrolysis. In a ballast water management system, it is also used to treat ballast water by electrolyzing seawater to produce a chlorine species oxidizer. However, ballast water in the brackish zone and some wastewater has a low chlorine ion concentration. Therefore, it is necessary to study the chlorine generation current efficiency at various chlorine concentration conditions. In this study, the chlorine generating current efficiency of a boron-doped diamond(BDD) electrode and insoluble electrodes are compared with various chloride ion concentrations. The results of this study show that the current efficiency of the BDD electrode is better than that of the insoluble electrodes. The chlorine generation current efficiency is better in the order of BDD, MMO(mixed metal oxide), $Ti/RuO_2$, and $Ti/IrO_2$ electrodes. In particular, when the concentration of sodium chloride is 10 g/L or less, the current efficiency of the BDD electrode is excellent.

An Equilibrium Analysis to Determine the Speciation of Metals in the Incineration of Waste Containing Chlorine (염소를 함유한 폐기물의 소각시 생성되는 유해 중금속류 결정에 대한 화학 평형 계산)

  • ;;Hwang, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.12
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    • pp.3372-3381
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    • 1995
  • An equilibrium analysis was carried out to determine principal species of heavy metals in waste incineration and their behaviors with variation of temperature, chlorine concentration, excess air ratio, and C/H ratio. The waste was assumed as a compound of hydrocarbon fuel, chlorine, and metals. Calculated results showed that the most important parameter to determine the principal species was temperature. Chlorine concentration also affected on mole fractions of the principal species. Generally principal species at high temperature were chlorides while there were some metals of which principal species were oxides. At low temperature mole fractions of the principal species increased, but at high temperature mole fractions of some metal species decreased. C/H ratio of the hydrocarbon fuel and excess air ratio had little effect on mole fractions of the metal species, compared to the temperature and chlorine concentration.

STUDIES ON THE CHLORINE OF BURLEY TOBACCO PLANTS. V. THE EFFECT OF NITROGEN FERTILIZER TYPE ON THE CHLORINE ABSORPTION BY TOBACCO PLANTS. (버어리종 담배의 염소에 관한 연구 V. 질소질 비료의 형태가 담배의 염소흡수에 미치는 영향)

  • 김상범;배길관
    • Journal of the Korean Society of Tobacco Science
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    • v.10 no.1
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    • pp.3-9
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    • 1988
  • Effect of several nitrogen fertilizer sources on the chlorine absorption by the burley tobacco plants was investigated under the field and pot condition. The nitrogen sources included compound fertilize.(containing 3.9% NH4-N and 6.1% NH2-N), (NH4)2SO4, NaNO3. (NH2)2CO and NH4NO3. The chlorine content of leaf during growing stage was high in (NH4)2SO4 plot , and the differences among nitrogen sources was remarkable at maximum growing stage. The chlorine content of cured leaf was high in (NH4)2SO4 plot. When the (NH4)2SO4 was applied, the total alkaloid content of cured leaf was increased and the color of cured leaf became undesirable with the increment of leaf chlorine. The yield, quality and value of cured leaf were high in NaNO3 plot , while low in (NH4)2SO4 plot.

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