• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.129-129
• /
• 2016

Graphene, as a single layer of $sp^2$-bonded carbon atoms packed into a 2D honeycomb crystal lattice, has attracted much attention due to its outstanding properties. In order to synthesize high quality graphene, transition metals, such as nickel and copper, have been widely employed as catalysts, which needs transfer to desired substrates for various applications. However, the transfer steps are not only complicated but also inevitably induce defects, impurities, wrinkles, and cracks of graphene. Furthermore, the direct synthesis of graphene on dielectric surfaces has still been a premature field for practical applications. Therefore, cost effective and concise methods for transfer-free graphene are essentially required for commercialization. Here, we report a facile transfer-free graphene synthesis method through nickel and carbon co-deposited layer. In order to fabricate 100 nm thick NiC layer on the top of $SiO_2/Si$ substrates, DC reactive magnetron sputtering was performed at a gas pressure of 2 mTorr with various Ar : $CH_4$ gas flow ratio and the 200 W DC input power was applied to a Ni target at room temperature. Then, the sample was annealed under 200 sccm Ar flow and pressure of 1 Torr at $1000^{\circ}C$ for 4 min employing a rapid thermal annealing (RTA) equipment. During the RTA process, the carbon atoms diffused through the NiC layer and deposited on both sides of the NiC layer to form graphene upon cooling. The remained NiC layer was removed by using a 0.5 M $FeCl_3$ aqueous solution, and graphene was then directly obtained on $SiO_2/Si$ without any transfer process. In order to confirm the quality of resulted graphene layer, Raman spectroscopy was implemented. Raman mapping revealed that the resulted graphene was at high quality with low degree of $sp^3$-type structural defects. Additionally, sheet resistance and transmittance of the produced graphene were analyzed by a four-point probe method and UV-vis spectroscopy, respectively. This facile non-transfer process would consequently facilitate the future graphene research and industrial applications.

• Journal of Embryo Transfer
• /
• v.4 no.1
• /
• pp.1-13
• /
• 1989

This paper reviews the most important steps that have generated consistent progress in principles and developmental progress of embryo cryopreservation, and also study on freezing procedure and its application by conventional method and current improved method for freezing procedure and its appilcation of embryo cryopreservation in farm animals. Four were of particular interest: 1.The transport of water across the ccli membrane (zona pellucida) during freezing and thawing accordinglyplays a role in determing whether the celi survives. This movement of water is controlied mainly by extracellular phase changes and by the nature and concentration of any cryoprotective agent present. Therates of cooling, freezing and warming, and the intervals over which they are applied are further decisi've factors in determining whether a cryopreservation procedure allows survival after thawing. 2.The first successful deep freezing experiments with sheep morula and blastocysts during the seventies were based on the early procedures used for mouse embryos.Current research during the eighties is developed with the aim of simplifying and improving current procedures such as one-step dilution and rapid or ultra-rapid cooling by using the model of laboratory animals. 3.The conventional method for the embryo cryopreservation is described. An alternative to this method which may result in high survival and also in reducing of the freezing and thawing time is done by combing a permeable cryoprotectant such as glycerol, DMSO or propanediol and a non-permeable compound such as sucrose, trehalose, raffinose or lactose. 4.Finally a different approach to the preservation of embryos, named vitrification, is introduced. This procedure depends upon the ability of concentrated solutions of cryoprotective agents such as glycerol and propanediol to supercool to very low temperature (-196$^{\circ}C$) during rapid cooling before solidifying without formation of ice. However, more complete data are necessary for successful vitrification of blastocysts.

• Journal of the Korean Ceramic Society
• /
• v.31 no.6
• /
• pp.637-642
• /
• 1994

Using SHS(Self-propagating High-temperature Synthesis) method, the optimum synthetic condition of titanium carbonitride was established by controlling the parameters such as relative density of mixture (Ti+C), nitrogen pressure, additive amounts of titanium hydride(TiH1.924) and protecting heat loss. Under 1 atm nitrogen pressure, nitridation ratio with changing relative density of the sample compacts has a maximum (87.2%) at about 55%, and in the case of enveloping the pellet with a quartz tube, the highest nitridation ratio of 90% was obtained at about 68%. At relative density of 55%, nitridation ratio with the nitrogen pressure has a miximum (87.3%) at 7 atm. As the amounts of additive titanium hydride increased, nitridation ratio decreased at below 7 atm nitrogen pressure and, increased at above this pressure until percent of addition percent reached 15 wt% and decreased abruptly upon futher increases in titanium hydride. In the synthesis of TiCxNy by combustion reaction, heat transfer from combustion zone to preheating zone and nitrogen gas penetration into the compact were found to be important factors affecting the TiCxNy formation. It was difficult to obtain high nitridation ratio when the conbustion temperature was either too high or too low, and it seems that the retention of high temperature after a combustion wave sweeped through the reactant mixture pellet is critical to obtain a satisfactory nitridation ratio.

• Journal of the Society of Naval Architects of Korea
• /
• v.46 no.2
• /
• pp.148-154
• /
• 2009

Type A LPG Carrier is the ship using the low temperature independent cargo tank separate from the hull, which has various support structures for laying independent tanks on the hull. In this paper, the direct strength analysis for the support structures has been performed through the direct load analysis, load transfer, stress analysis and strength assessment. Also, a rational modeling method of support structures has been proposed to obtain the dynamic load between the hull and the separate tank.

• Journal of Biosystems Engineering
• /
• v.41 no.2
• /
• pp.108-115
• /
• 2016

Purpose: Radio frequency (RF) heating is a promising thawing method, but it frequently causes undesirable problems such as non-uniform heating. This can occur because of the food shape, component distribution, and initial temperature differences between food parts. In this study, RF heating was applied to the thawing of cylindrically shaped pork sirloin by changing the shape of electrodes and the surrounding temperature. Methods: Curved electrodes were utilized to increase the thawing uniformity of cylindrically shaped frozen meat. Pork sirloin in the shape of a half-circle column was frozen in a deep freezer at $-70^{\circ}C$ and then thawed by RF heating with flat and curved electrodes. In order to prevent fast defrosting of the food surface by heat transfer from air to the food, the temperature of the thawing chamber was varied by -5, -10, and $-20^{\circ}C$. The temperature values of the frozen pork sirloin during RF thawing were measured using fiber-optic thermo sensors. Results: After multiple applications of curved electrodes resembling the food shape, and a cooled chamber at $-20^{\circ}C$ the half-cylindrically shaped meat was thawed without surface burning, and the temperature values of each point were similarly increased. However, with the parallel electrode, the frozen meat was partially burned by RF heating and the temperature values of center were overheated. The uniform heating rate and heat transfer prevention from air to the food were crucial factors for RF thawing. In this study, these crucial factors were accomplished by using a curved electrode and lowering the chamber temperature. Conclusions: The curved shape of the electrode and the equipotential surface calculated from the modeling of the parallel capacitor showed the effect of uniform heating of cylindrically shaped frozen food. Moreover, the low chamber temperature was effective on the prevention of the surface burning during RF thawing.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.18 no.3
• /
• pp.267-272
• /
• 2012

Carbon emission generated by energy issues is one of the major problems which all countries concern. The International Energy Agency recommends to improve 15-30[%] of energy efficiency than now. Government has pushed the domestic energy saving policies and incentives and penalties were also given in that direction. Pumps are widely used to transfer fluids and they consume at least 20[%] power of each nation. Their loss of energy is huge if they have been operated at low efficiency for long time. Low efficiency of these pumps is often due to incorrect design or degradation. Pump efficiency can be measured to estimate energy loss. If it is low, the pump may be repaired or replaced with new one. This paper introduces thermodynamic method to measure pump efficiency using only two kinds of sensors for temperature and pressure. It can calculate best efficiency point(BEP) of actual systems easily and fast. Its values were compared with the real performance curve provided by pump maker and we got almost similar performance curves from the repeated experiment.

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2989-2994
• /
• 2007

Gas hydrates are ice-like crystalline compounds that form under low temperature and elevated pressure conditions. Although hydrate formation can pose serious flow-assurance problems in the gas pipelines or facilities, gas hydrates present a novel means for natural gas storage and transportation with potential applications in a wide variety of areas. An important property of hydrates that makes them attractive for use in gas storage and transportation is their very high gas-to-solid ratio. In addition to the high gas content, gas hydrates are remarkably stable. The main barrier to development of gas hydrate technology is the lack of an effective method to mass produce gas hydrate in solid form. The first objective of this study is investigating the characteristics of gas hydrate formation related to several factors such as pressure, temperature, water-to-storage volume ratio, concentration of SDS, heat transfer and whether stirred or not respectively. And the second objective is clarifying the relation between the formation efficiency and each factor in order to find the proper way or direction to improve the formation performance.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2001.11a
• /
• pp.341-349
• /
• 2001

Heat distortion of the non-contacting mechanical face seal is affected by friction heat between primary seal and seal sheet. The fluid or gas in mechanical face seal maintains operating gap, cooling friction heat and lubricates at the face of seal. So we designed face of seal for inclined face. inclined face of seal improves fluid or gas flow at the face of seal and it increases circumferential velocity at outer radius of the seal so temperature of the seal is decreased by low heat transfer coefficient at there. In this paper, inclined face seal are analysed numerically using finite element method for proof improve inclined face seal performance. Angle of the incline face used for FEA is from 50$^{\circ}$to 90$^{\circ}$and for explaining the effects of inclined face in seal, we get temperature, face distortion, and stress in the seal with variable operating gap and rotating speeds. Result of analysis shows that angle of the incline face is 60$^{\circ}$come to good thermal distortion characteristics.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.7 no.3
• /
• pp.366-381
• /
• 1995

A performance analysis of refrigeration system using the HFC-134a and scroll compressor is performed numerically. The refrigeration system mainly consists of various standard components such as heat exchanger, compressor, and expansion device. The model for heat exchanger performance is based on a tube-by-tube method which is analyzed separately by considering the cross-flow heat transfer with the outdoor air flow and pressure drop. Compressor is used the scroll-type compressor which has many merits such as high efficiency, low noise and vibration, and small in size. Short-tube is included as an expansion device. Vapour and liquid line are also considered for the performance analysis of refrigeration system. Using the modeling of various components of refrigeration system, a performance comparison of CFC-12 and HFC-134a is performed numerically for the various outdoor air temperature and various values of short-tube diameter. As the results of this study, the refrigeration system performance decreases as the outdoor air temperature increases. And the optimum short-tube diameter based on COP is 1.37mm for this system.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.15 no.5
• /
• pp.432-438
• /
• 2003

This paper describes a modified Roebuck compression device as a potential compression device of a rotating cryogenic refrigeration system in superconducting machine such as generator or motor. The conventional cryogen transfer method from stationary refrigeration system to rotating system can be eliminated by an on-board cryogenic refrigeration system that utilizes well-designed multi-stage modified Roebuck compression device. This paper shows basic thermodynamic analysis of modified Roebuck compression device and its application for compressing neon at 77 K with substantial pressure ratio when the rotor diameter is 0.8 m with rotating speed of 3600 rpm. The device does not require any moving part in rotating frame, but two separate thermal reservoirs to convert thermal energy into mechanical compression work. The high temperature thermal reservoir is atmospheric environment at 300 K and the low temperature thermal reservoir is assumed as a liquid nitrogen bath at 77 K. The concept of the compression device in this paper demonstrates its usefulness of generating high-pressure neon at 77 K for rotating J-T neon refrigeration cycle of superconducting rotor.