• 한국재료학회지
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• 제29권5호
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• pp.304-310
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• 2019

Chemical vapor deposition method using $CH_4$ gaseous hydrocarbons is generally used to synthesize large-area graphene. Studies using non-gaseous materials such as ethanol, hexane and camphor have occasionally been conducted. In this study, large-area graphene is synthesized via chemical vapor deposition using polyethylene as a carbon precursor. In particular, we used a poly glove, which is made of low-density polyethylene. The characteristics of the synthesized graphene as functions of the growth time of graphene and the temperature for vaporizing polyethylene are evaluated by optical microscopy and Raman spectroscopy. When the polyethylene vaporizing temperature is over $150^{\circ}C$, large-area graphene with excellent quality is synthesized. Raman spectroscopy shows that the D peak intensity increased and the 2D peak intensity decreased with increasing growth time. The reason for this is that sp3 bonds in the graphene can form when the correct amount of carbon source is supplied. The quality of the graphene synthesized using polyethylene is similar to that of graphene synthesized using methane gas.

• 한국안전학회지
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• 제4권1호
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• pp.5-14
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• 1989

低密度 Polyethylene film을 冷延伸된 方向에 對해서 直勇方向으로 延伸하면, 延伸比 1.2~1.8 付近에서 部分放電에 의한 劣化가 顯著히 增加하고, Void發生에 의한 部分放電 開始電壓이 低下한다. 延伸 film에 對해 强制振動法에 의해 求한 彈性率 및 力學的 tan$\delta$는 上記의 延伸比代近에서 名名 極小 및 極大를 나내고 上記의 傳奇的特性과 密接한 關係가 있다. 더욱이 微結晶은 延伸에 의해 작은 結晶으로 分解되는 것을 X線回折로 認定할 수 있고, 또한 非晶領城의 分子鎖는 高延伸에서 再配向하는 것을 赤外吸收에 의해 認定할 수 있다.

• 한국조명전기설비학회지:조명전기설비
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• 제6권6호
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• pp.23-31
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• 1992

Charged particle in the polymers is supposed to affect the electrical conduction and to lead them th dielectrical breakdown finally. So we measured the space charge distribution made by application of high electric field and evaluated the polarity of the charged particle affected on electrical conduction and space charge formed in the insulating materials by using temperature gradient thermally stimulated current measurement method(TG-TSC measurement). As a result, in the cross-linked polyethylene, A-peak was caused from dipole polarization, C-peak was caused from ionic space charge polarization and D-peak was injected trap hole. Also we found it crossible the evaluated the polarity of injected trap carrier and electron(or hole) of carrier trap in the cross-lined polyethylene. We found that ${\gamma}$-ray irradiated low density polyethylene had a relation to the electronic trap and we also could get the value of electric field distribution in the samples of which evaluation was available.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1617-1620
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• 1999

In this work, the effect of blend on physical and electrical properties investigated. The two kinds of low-density polyethylene (LDPE) whose densities are evaluated at $0.9179[g/cm^3]$ and $0.9192[g/cm^3]$, respectively, were used and blended according to the different blend ratio. The LDPE with the blend ratio of 50[wt%] represented the lowest impulse breakdown strength, $F_{BImp}$ at $30[^{\circ}C]$, but the highest $F_{BImp}$ at $90[^{\circ}C]$. DC breakdown strength, $F_{BDC}$. decreased with the increase of blend ratio at $30[^{\circ}C$, but increased at $60[^{\circ}C]$. The current density decreased with a blend ratio up to 75 [wt%] at $90[^{\circ}C]$. By analyzing the diffraction patterns of XRD, we found that the LDPE with the blend ratio of 50 [wt%] represented the largest crystal size of (020) plane. We investigated the relationship between the effect of blend and electrical properties and these results are discussed.

• Macromolecular Research
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• 제14권4호
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• pp.430-437
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• 2006

The ultra-drawing process of an ultra high molecular weight polyethylene (UHMWPE) gel film was examined by incorporating linear low-density polyethylene (LLDPE) and $BaTiO_3$ nanoparticles. The effects of LLDPE and the draw ratios on the morphological development and mechanical properties of the nanocomposite membrane systems were investigated. By incorporating $BaTiO_3$ nanoparticles in the UHMWPE/LLDPE blend systems, the ultra-drawing process provided a highly extended, fibril structure of UHMWPE chains to form highly porous, composite membranes with well-dispersed nanoparticles. The ultra-drawing process of UHMWPE/LLDPE dry-gel films desirably dispersed the highly loaded $BaTiO_3$ nanoparticles in the porous membrane, which could be used to form multi-layered structures for electronic applications in various embedded, printed circuit board (PCB) systems.

• Macromolecular Research
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• 제11권5호
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• pp.357-367
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• 2003

The linear low density polyethylene (LLDPE)/zeolite composite using novel inorganic filler, zeolite, is prepared by a conventional compounding procedure using a twin-screw extruder. The observed scanning electron microscopic (SEM) morphology shows a good dispersion and adhesion of zeolite in the LLDPE matrix. The mechanical properties in terms of the Young's modulus, the yield stress, the impact strength, and the elongation at break were enhanced with a successive increment of zeolite content up to 40 wt%. The X-ray diffraction measurement is of supportive for the improved mechanical properties and the complex melt viscosity is as well. Upon applying a certain level of strain on the composites, the dewetting, the air hole formation and its growth are characterized. The dewetting originates around the filler particles at low strain and induces elliptical micropores upon further stretching. The microporosity such as the aspect ratio, the number and the total area of the air holes is also characterized. Thus, the composites loaded 40 % zeolite and 300 % elongation may be applicable for breathable microporous films with improved modulus, impact and yield stress, elongation at break, microporosity and air hole properties.

• 동아시아식생활학회지
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• 제23권4호
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• pp.461-469
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• 2013

This research is performed to investigate the changes in the physicochemical properties and microbial growths of seasoned anchovies with various packaging materials (PET/CPP : polyethylene terephthalate/cast polypropylene, PET/EVOH : polyethylene terephthalate/ethylene-vinyl alcohol, PET/AL/LDPE: polyethylene terephthalate/aluminum/low density polyethylene), which are stored at various temperatures (25, 35, $45^{\circ}C$) for 60 days. Generally, it is being observed that changes in physicochemical properties (i.e., moisture content, color, brown intensity, TBA value, TMA, VBN etc) of seasoned anchovies are significant when stored at higher temperatures. Particularly, the packaging materials are found to influence substantially on the physicochemical properties of seasoned anchovies. With packaging materials of high oxygen transmission rates and moisture vapor transmission rates (i.e., PET/CPP), the changes in physicochemical properties of seasoned anchovies are significant, while being low with low oxygen transmission rates and low moisture vapor transmission rates (i.e., PET/EVOH). In addition, results of microbial growths in seasoned anchovies show that significant increases in total aerobic bacteria counts (about 100-fold after 60 day of storage) are observed in samples with packaging materials of high oxygen transmission rates and moisture vapor transmission rates (i.e, PET/CPP), while with only small increases for samples of low oxygen transmission rates and low moisture vapor transmission rates (i.e., PET/EVOH). Based on the changes in the physicochemical properties and results of microbial growths, it is being concluded that PET/EVOH film is suitable for the packaging of seasoned anchovies.

• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.453-460
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• 1997

In order to investigate the electrical conduction properties of polyethylene thin film for power cable with manufacturing methods, the thickness of specimen was the 30, 100[${\mu}{\textrm}{m}$] of LDPE and 200[${\mu}{\textrm}{m}$] of XLPE were manufactured. The experimental condition for conduction properties was measured until the breakdown occurs at temperature ranges from 30 to 110[$^{\circ}C$] and the electric field from 1$\times$10$^3$to 5$\times$10$^{6}$ [V/cm]. As for increase of temperature, the current density of LDPE was increased with constant ratio in low field, but changes with exponential function in high electric field. The tunnel current of pre-breakdown region is shifted toward low field as much as thermal excitation energy. At low electric field, the XLPE showed dominant electrical conduction properties by thermal excitation, and transformation of the electron was resisted by the crystal at high electric field.

• 폴리머
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• 제29권2호
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• pp.127-134
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• 2005

포장용 필름 등으로 사용되는 폴리프로필렌(PP)계 필름[PP/polyethylene(PE)/aluminum(Al)poly(ethylene terephthalate)(PET)]과 나일론(Nylon)계 필름[Nylon/PE/linear-low density polyethylene(LLDPE)] 등 혼합 폐포장 필름의 상용성 증진과 강인화를 위해 시판되는 여러 가지 상용화제 중 ethylene vinylacetate(EVA), styrene-ethylene/butylene-styrene triblock copolymer(SEBS), styrene-ethylene/butylene-styrene-graft-maleic anhydride copolymer(SEBS-g-MA), polyethylene-graft-maleic anhydride (PE-g-MA), polypropylene-graft-maleic anhydride(PP-g-MA), polyethylene-graft-acrylic acid(PE-g-AA), polypropylene-araft-acrylic acid(PP-g-AA) 등을 사용하여 반응 압출 공정에 의한 기계적 물성, 유성학적 성질과 형태학적 변화를 살펴보았다. 단순 용융 블렌드와 비교하여 상용화제로 SEBS와 EVA를 사용하였을 때 약 $50\%$의 물성 향상을 보였으나 나일론의 말단기인 아민기와의 반응성 향상을 위해 무수말레인산이 그래프트된 열가소성 탄성체 SEBS-g-MA의 사용시 분산 입자의 감소 및 접촉면적의 증가에 의한 계면 접착력의 증가로 약 $200\%$ 이상의 내충격성의 향상을 이룰 수 있었다.

• 한국안전학회지
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• 제17권4호
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• pp.101-109
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• 2002

The electrical properties of polyethylene are changed by the superstructure. Such crystalline polymer as polyethylene or polypropylene changes crystallinity and products spherulite or trans-crystal when it is cooled slowly. In this study, after thermal treatment of LDPE at 100[${circ}C$], in silicone oil for an hour, we made specimens in order of slow cooling, water cooling, quenching according to cooling speed. Also, to study the influence of electrical properties due to the superstructure change, we analyzed physical properties and performed dielectric breakdown experiments using DC and impulse voltage Moreover we measured space charges in bulk using Laser Induced Pressure Pulse(LIPP) method. Trap level of specimen is 0.064[eV] at the low temperature region 0.31[eV] at the high temperature region in DC dielectric strength, 0.03[eV] at the low temperature region 0.0925[eV] at the high temperature region in impulse dielectric strength. As its result shows that the quantity of charges induced from the electrode surface increases with applied voltage time, and the distribution of space charges in samples increases the quantity of charges in proportion to applied voltage.