• Title/Summary/Keyword: Low Temperature Performance

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Comparison of the Real-time Measurements for PM2.5 and Quality Control Method (PM2.5 자동측정장비 비교 및 정도관리 방안)

  • Park, Mikyung;Park, Jin Su;Jo, Mira;Lee, Yong Hwan;Kim, Hyun Jae;Oh, Jun;Choi, Jin Soo;Ahn, Joon Young;Hong, You Deog
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.6
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    • pp.616-625
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    • 2017
  • Measurements using five real-time particle samplers were compared to measurements using three NRM (National Reference Method system) filter-based samplers(Gravimetric method) at Incheon, Korea, between May and August, 2014. The purpose of this study was to suggest the quality assurance/quality control (QA/QC) method of each instrument for use in a real-time continuous particle sampler to measure the mass of airborne particles with an aerodynamic diameter less than $2.5{\mu}m$ ($PM_{2.5}$). Five real-time particle samplers of BAM1020, FH62C_14, TEOM, PM-711 and SPM-613 were evaluated by comparing its measured 23 hr average $PM_{2.5}$ concentrations with those measured with NRM filter-based samplers simultaneously. The parameters(e.g. Inlet heating condition, Slope factor, Film response, Intercept, Background, Span value) of the real-time samplers were optimized respectively by conducting test performance evaluation during 7 days in field sampling. For example, inlet heating temperature of TEOM sampler controls $35{\sim}40^{\circ}C$ to minimize the fluctuation of the real-time measurement data and background value of BAM1020 is the key factor affecting the accuracy of $PM_{2.5}$ mass concentration. We classified the $PM_{2.5}$ concentration according to relative humidity (80%) to identify water absorbed in aerosols by measuring the ${\beta}$-ray samplers(BAM1020, FH62C_14) and TEOM. ${\beta}$-ray samplers were not strongly affected by relative humidity that the difference of the average $PM_{2.5}$ concentration was about 5%. On the other hand, The TEOM sampler overestimated $PM_{2.5}$ mass concentration about 15% at low relative humidity (<80%).

Effect of Ozone Injection into Exhaust Gas on Catalytic Reduction of Nitrogen Oxides (촉매 공정의 배기가스 질소산화물 저감 성능에 미치는 오존주입의 영향)

  • Yun, Eun-Young;Mok, Young-Sun;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.330-336
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    • 2005
  • The ozone injection method was proposed to improve the catalytic process for the removal of nitrogen oxides ($NO_x$). Nitric oxide (NO) in the exhaust gas was first oxidized to nitrogen dioxide ($NO_2$) by ozone produced by dielectric barrier discharge, and then the exhaust gas containing the mixture of NO and $NO_2$ was directed to the catalytic reactor where both NO and $NO_2$ were reduced to $N_2$ in the presence of ammonia as the reducing agent. A commercially available $V_2O_5-WO_3/TiO_2$ catalyst was used as the catalytic reactor. The $NO_2$ content in the mixture of NO and $NO_2$ was changed by the amount of ozone added the exhaust gas. The effect of reaction temperature, initial $NO_x$ concentration, feed gas flow rate, and ammonia concentration on the removal of $NO_x$ at various $NO_2$ contents was examined and discussed. The increase in the content of $NO_2$ by the ozone injection remarkably improved the performance of the catalytic reactor, especially at low temperatures. The present ozone injection method appears to be promising for the improvement of the catalytic reduction of $NO_x$.

Influence of Operating Parameters on Nitrite Accumulation in a Biofilm Reactor and Supplement of External Carbon Source for Denitrification by Sewage Sludge Solubilization (생물막 반응조에서 아질산염 축적에 미치는 운전인자 영향과 하수슬러지 가용화에 의한 탈질반응의 외부탄소원 공급에 관한 연구)

  • Ahn, Hye Min;Lee, Dae Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.57-63
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    • 2013
  • A combined process consisted of a biofilm reactor and a continuously stirred-tank reactor (CSTR) was investigated for highly loaded ammonium wastewater treatment via nitrite accumulation. To enhance ammonium oxidizing bacteria over nitrite oxidizing bacteria on the surface of carriers, the biofilm reactor was operated at temperature of $35^{\circ}C$ for more than three months but the influent ammonium (500 mg-N/L) was partially oxidized to nitrite (240 mg-N/L). As pH was increased from 7.5 to 8.0, nitrite accumulation was fully achieved due to the inhibition of nitrite oxidizing bacteria under high free ammonia concentration. The biofilm reactor performance was severely deteriorated at the hydraulic retention time of 12 hr, at which incomplete nitrification of ammonia was observed. Various solubilization methods were applied to sewage sludge for enhancing its biodegradability and the combined method, alkaline followed by ultrasonic, gave the highest solubilization efficiency (58%); the solubilized solution was used as the external carbon source for denitrification reaction in CSTR. FISH analysis showed that the dominant microorganisms on the carriers were ammonium oxidizing bacteria such as Nitrosomonas spp. and Nitrospirar spp. but low amounts of nitrite oxidizing bacteria as Nitrobacter spp. was also detected.

Development of Mechanistic-empirical Joint Spacing Design Method for Concrete Pavements (역학적-경험적 콘크리트 포장 줄눈간격 설계방법 개발)

  • Park, Joo-Young;Hong, Dong-Seong;Lim, Jin-Sun;Jeong, Jin-Hoon
    • International Journal of Highway Engineering
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    • v.13 no.4
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    • pp.51-59
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    • 2011
  • Tensile stress occurs and random crack develops in concrete pavement slab when it contracts by variation of temperature and humidity. The tensile stress decreases and the random crack is minimized by sawcutting the slab and inducing the crack with regular spacing. The random crack, joint damage, decrease of load transfer efficiency are caused by too wide joint spacing while too narrow joint spacing leads to increase of construction cost and decrease of comfort. A mechanistic-empirical joint spacing design method for the concrete pavement was developed in this study. Structurally and environmentally weakest sections were found among the sections showing good performance, and design strengths were determined by finite element analysis on the sections. The joint width for which the load transfer efficiency is suddenly lowered was determined as allowable joint with referring to existing research results. The maximum joint spacing for which the maximum tensile stress calculated by the finite element analysis did not exceed the design strength were found. And the maximum joint width expected by the maximum joint spacing were compared to the allowable joint width. The new method developed in this study was applied to two zones of Hamyang-Woolsan Expressway being designed. The same joint spacing as a test section constructed by 8.0m of joint spacing wider than usual was calculated by the design method. Very low cracking measured at 6 years after opening of the test section verified the design method developed in this study.

Synthesis of TiO2/active carbon composites via hydrothermal process and their photocatalytic performance (수열합성법에 의한 TiO2/active carbon 복합체의 제조 및 광촉매특성)

  • Kim, Dong Jin;Lee, Jin Hee;Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.5
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    • pp.241-245
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    • 2013
  • Granular bamboo-derived active carbons (AC) were impregnated (or coated) with $TiO_2$ nano crystalline powders. The photocatalytic activity of the $TiO_2$-impregnated active carbons ($TiO_2$/AC) were determined on the basis of the degradation rate of methylene-blue aqueous solution under UV irradiation. The active compounds of $TiO_2$ were impregnated onto the AC under moderate hydrothermal conditions (${\leq}200^{\circ}C$, pH 11). The mean size of $TiO_2$ particles calculated from BET surface area were found to be as 50 nm. The $TiO_2$ precipitates were coated on the cavities or pores on the surfaces of highly activated carbons. Since the hydrothermal process led to a lowering of the on-set temperature of the anatase-to-rutile transition of $TiO_2$ as low as $200^{\circ}C$, $TiO_2$ crystallites of a pure anatase or a mixed form with rutile were successfully coated on the AC depending on the synthesis temperatures.

Preliminary Design of the NISS onboard NEXTSat-1

  • Jeong, Woong-Seob;Park, Sung-Joon;Moon, Bongkon;Lee, Dae-Hee;Park, Won-Kee;Lee, Duk-Hang;Ko, Kyeongyeon;Pyo, Jeonghyun;Kim, Il-Joong;Park, Youngsik;Nam, Ukwon;Park, Chan;Im, Myungshin;Lee, Hyung Mok;Lee, Jeong-Eun;Shin, Goo-Hwan;Chae, Jangsoo;Matsumoto, Toshio
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.102-102
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    • 2014
  • The NISS (Near-infrared Imaging Spectrometer for Star formation history) onboard NEXTSat-1 is the near-infrared instrument onboard NEXTSat-1 which is being developed by KASI. The main scientific targets are nearby galaxies, galaxy clusters, star-forming regions and low background regions in order to study the cosmic star formation history in local and distant universe. After the Preliminary Design Review, we have fixed major specifications of the NISS. The off-axis optical design with 15cm apertureis optimized to obtain a wide field of view ($2deg.{\times}2deg.$), while minimizing the sensitivity loss. The opto-mechanical structure of the NISS was designed to be safe enough to endure in the launching condition as well as the space environment. The tolerance analysis was performed to cover the wide wavelength range from 0.95 to $3.8{\mu}m$ and to reduce the degradation of optical performance due to thermal variation at the target temperature, 200K. The $1k{\times}1k$ infrared sensor is operated in the dewar at 80K stage. We confirmed that the NISS can be cooled down to below 200K in the nominal orbit through a radiative cooling. Here, we report the preliminary design of the NISS.

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Synthesis and Electrochemical Characterization of Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine Composite as Polymer Cathode Material (Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine 복합체 고분자 양극재료의 합성과 전기화학적 특성)

  • Oh, Ji-Woo;Ryu, Kwang-Sun
    • Journal of the Korean Electrochemical Society
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    • v.15 no.4
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    • pp.222-229
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    • 2012
  • We studied the electrochemical phenomena and increase of capacity according to the polymer composite electrode of two different polymeric materials with different the voltage range and capacity. Polyaniline (PANI) with relatively high voltage and small capacity and poly [1,2] bis-thio[1,8]-naphthylidine (PTND) with slightly low voltage and large capacity were used as polymer composite electrode materials. After PTND was synthesized, PANI was synthesized on the surface of PTND. The synthesis and the fine structure were analyzed by FT-IR, XPS, FE-SEM, and FE-TEM. Charge/discharge capacity and cyclic voltammetry measurements were carried out for the electrochemical performance as a polymer cathode active material for lithium secondary batteries. The discharge capacities of PANI/PTND after 1,5, and 10 cycles at 1.3~4.0 V voltage range and room temperature 167 mAh/g, 90 mAh/g, and 81 mAh/g. When we compared with PANI (80, 67, and 62 mAh/g), the discharge capacity after 10 cycles was improved about 30%. After 50 cycles, the discharge capacity of PANI/PTND was 67 mAh/g.

A Method for Correcting Air-Pressure Data Collected by Mini-AWS (소형 자동기상관측장비(Mini-AWS) 기압자료 보정 기법)

  • Ha, Ji-Hun;Kim, Yong-Hyuk;Im, Hyo-Hyuc;Choi, Deokwhan;Lee, Yong Hee
    • Journal of the Korean Institute of Intelligent Systems
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    • v.26 no.3
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    • pp.182-189
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    • 2016
  • For high accuracy of forecast using numerical weather prediction models, we need to get weather observation data that are large and high dense. Korea Meteorological Administration (KMA) mantains Automatic Weather Stations (AWSs) to get weather observation data, but their installation and maintenance costs are high. Mini-AWS is a very compact automatic weather station that can measure and record temperature, humidity, and pressure. In contrast to AWS, costs of Mini-AWS's installation and maintenance are low. It also has a little space restraints for installing. So it is easier than AWS to install mini-AWS on places where we want to get weather observation data. But we cannot use the data observed from Mini-AWSs directly, because it can be affected by surrounding. In this paper, we suggest a correcting method for using pressure data observed from Mini-AWS as weather observation data. We carried out preconditioning process on pressure data from Mini-AWS. Then they were corrected by using machine learning methods with the aim of adjusting to pressure data of the AWS closest to them. Our experimental results showed that corrected pressure data are in regulation and our correcting method using SVR showed very good performance.

The Electrochemical Property Studies on Polyacenic Semiconductor Anode Material (음극 폴리아센 반도체 재료의 전기화학적 특성연구)

  • Kim Han-Joo;Park Jong-Eun;Son Won-Keun;Lee Hong-Ki;Park Soo-Gil;Lee Ju-Seong
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.134-137
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    • 1999
  • The polyacenic semiconductor material (PAS) electrode prepared by the pyrolytic treatment of phenol-formaldehyde resin is one of useful electrodes. As an anode material of lithium rechargeable batteries, amorphous carbon materials have been studied extensively because of their high electrochemcal performance and cyclicability. Carbon materials do not lead to the formation of lithium dendrite which is one of the most serious problems in applying Li-based materials to an electrode of batteries. The polyacene materials prepared from phenol resin at relatively low temperatures $(550\~750^{\circ}C)$ show a highly Li\doped state up to $C_2Li$ state without liberation of Li cluster. We prepared each polyacene materials at various temperature and investigated electro- chemical properties. We tried to change the mole ratio of [H]/[C] which is $0.24\~0.4$ range. Considering of electrochemical properties of PAS material, the PAS material is one of the most suitable materials for electrodes of a polymer battery.

Effect of Seed Priming on the Germination Performance and Membrane Integrity of Tomato(Lycopersicon esculentum Mill.) Seeds (Priming 처리에 의한 토마토 종자의 발아력과 Membrane Integrity에 미치는 영향)

  • Kang, Jum-Soon;Son, Beung-Gu;Ahn, Chong-Kil
    • Journal of Bio-Environment Control
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    • v.12 no.4
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    • pp.221-227
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    • 2003
  • The objective of this research was to determine the effect of seed priming on membrane integrity during poriming and germination. Among the five chemicals, $KNO_3$at 150 mL gave the shortest $T_{50}$ (days required to reach 50% of the final germination percentage). Compared to unprimed, the seeds primed with 150 mL $KNO_3$ at 20$^{\circ}C$ for 4 days had reduced $T_{50}$ values when germinated at 15$^{\circ}C$. These results indicated that seed priming is an effective way for rapid and synchronized germination, especially at low temperature. Changes in conductivity of priming solutions during the 4-days period of priming were highly dependent upon the priming agents. Conductivity of the $KNO_3$ and $K_3PO_4$ solution slowly declined during the first 3 hours ad then increased Amount of amino acids, sugars and proteins exuded from seeds into $KNO_3$ solution were less than those into distilled water and $K_3PO_4$. All the results suggested that the $KNO_3$ priming play a positive role in regulating the permeability of cell membranes.