• Title/Summary/Keyword: Low Tc phase

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Processing, structure, and properties of lead-free piezoelectric NBT-BT

  • Mhin, Sungwook;Lee, Jung-Il;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.160-165
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    • 2015
  • Lead-free piezoelectric materials have been actively studied to substitute for conventional PZT based solid solution, $Pb(Zr_xTi_{1-x}O_3)$, which occurs unavoidable PbO during the sintering process. Among them, Bismuth Sodium Titanate, $Na_{0.5}Bi_{0.5}TiO_3$ (abbreviated as NBT) based solid solution is attracted for the one of excellent candidates which shows the strong ferroelectricity, Curie temperature (Tc), remnant polarization (Pr) and coercive field (Ec). Especially, the solid solution of rhombohedral phase NBT with tetragonal perovskite phase has a rhombohedral - tetragonal morphotropic phase boundary. Modified NBT with tetragonal perovskite at the region of MPB can be applied for high frequency ultrasonic application because of not only its low permittivity, high electrocoupling factor and high mechanical strength, but also effective piezoelectric activity by poling. In this study, solid state ceramic processing of NBT and modified NBT, $(Na_{0.5}Bi_{0.5})_{0.93}Ba_{0.7}TiO_3$ (abbreviated as NBT-7BT), at the region of MPB using 7 % $BaTiO_3$ as a tetragonal perovskite was introduced and the structure between NBT and NBT-7BT were analyzed using rietveld refinement. Also, the ferroelectric and piezoelectric properties of NBT-7BT such as permittivity, piezoelectric constant, polarization hysteresis and strain hysteresis loop were compared with those of pure NBT.

Effect of Li2CO3 Doping on Phase Transition and Piezoelectric Properties of 0.96K0.5Na0.5NbO3-0.04SrTiO3 Ceramics (0.96K0.5Na0.5NbO3-0.04SrTiO3 세라믹스의 상전이와 압전 특성에 대한 Li2CO3 도핑 효과)

  • Jae Young Park;Trang An Duong;Sang Sub Lee;Chang Won Ahn;Byeong Woo Kim;Hyoung-Su Han;Jae-Shin Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.5
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    • pp.513-519
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    • 2023
  • It was reported that a tetragonal phase can be stabilized with maintaining good piezoelectric properties when Na0.5K0.5NbO3 (KNN) is modified with 0.06 mol SrTiO3. However, such a high amount of SrTiO3 leads not only to poor sinterability but low Curie temperature (TC). To maintain high TC with good piezoelectric properties in KNN-based lead-free piezoelectric ceramics, this study investigates the effect of Li-doping on the dielectric and piezoelectric properties of 0.96Na0.5K0.5NbO3-0.04SrTiO3 (KNN-4ST) ceramics. As a result, the orthorhombic-tetragonal phase transition was observed at 2 mol% Li2CO3 modified KNN-4ST ceramics, whose TC, d33 and kp values are 328℃, 165pC/N and 0.33, respectively.

Performance of Underwater Communication in Low Salinity Layer at the Western Sea of Jeju (제주도 서부 해역의 저염수층을 고려한 수중통신 성능)

  • Bok, Tae-Hoon;Kim, Ju-Ho;Lee, Chong-Hyun;Bae, Jin-Ho;Paeng, Dong-Guk;Pang, Ig-Chan;Lee, Jong-Kil
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.48 no.1
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    • pp.16-24
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    • 2011
  • The sound speed of seawater can be calculated by the empirical formula as a function of temperature, salinity and pressure. It is little affected by salinity because the average salinity is 34 psu and varies within a few psu seasonally and spatially in the ocean. Recently, low-salinity water of 24 psu flows into the western sea area of Jeju Island due to the flood of the Yangtze River in China during summer, affecting sound speed profile. In this paper, it was analyzed how environmental changes affected to the underwater communication - the sound speed of low-salinity water was calculated, and the communication channel was estimated by the simulated acoustic rays while the transmitting and receiving depth and the range were varied with and without the low-salinity layer. And The BER (Bit error rate) was calculated by BPSK(Binary phase shift key) modulation and the effects of the low-salinity water on the BER was investigated. The sound speed profile was changed to have positive slope by the low-salinity layer at the sub-surface up to 20 m of depth, forming acoustic wave propagation channel at the sub-surface resulting in the decrease of most of the BER Consequently, this paper suggests that it is important to consider changes of the ocean environment for correctly analyzing the underwater communication and the detection capability.

Low Phase Noise VCO Using Novel Harmonic Control Circuit Based on Composite Right/Left-Handed Transmission Line (혼합 우좌향 전송 선로 기반의 새로운 고조파 조절 회로를 이용한 저위상 잡음 전압 제어 발진기)

  • Choi, Jae-Won;Seo, Chul-Hun
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.47 no.1
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    • pp.84-90
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    • 2010
  • In this paper, a novel voltage-controlled oscillator (VCO) using the harmonic control circuit based on the composite right/left-handed (CRLH) transmission lines (TLs) is presented to reduce the phase noise without the reduction of the frequency tuning range and miniaturize the circuit size. The phase noise is reduced by the novel harmonic control circuit having the short impedances for the second- and third-harmonic components. The proposed harmonic control circuit is designed by using the CRLH TLs with the dual-band characteristic by the frequency offset and phase slope of the CRLH TLs. The high-Q resonator has been used to reduce the phase noise, but has the problem of the frequency tuning range reduction. However, the frequency tuning range of the proposed VCO has not been reduced because the phase noise has been reduced without the high-Q resonator. The miniaturization of the circuit size is achieved by using the CRLH TLs instead of the conventional right-handed (RH) TLs. The phase noise of VCO is -119.17 ~ -117.50 dBc/Hz at 100 kHz in the tuning range of 5.731 ~ 5.938 GHz.

A Study on the Fabrication of K-band Local Oscillator Used Frequency Doubler Techniques (주파수 체배 기법을 이용한 K-대역 국부발진기 구현에 관한 연구)

  • 김장구;박창현;최병하
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.41 no.10
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    • pp.109-117
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    • 2004
  • In this paper, a K-band local oscillator composed of a VCDRO(Voltage Controlled Dielectric Resonator Oscillator), GaAs MESFET, and Reflector type frequency doubler has been designed and fabricated. TO obtain a good phase noise performance of a VCDRO, a active device was selected with a low noise figure and a low flicker noise MESFET and a dielectric resonator was used for selecting stable and high oscillation frequency. Especially, to have a higher conversion gain than a conventional doubler as well as a good harmonic suppression performance with circuit size reduced a doubler structure was employed as the Reflector type composed of a reflector and a open stub of quarter wave length for rejecting the unwanted harmonics. The measured results of fabricated oscillator show that the output power was 5.8 dBm at center frequency 12.05 GHz and harmonic suppression -37.98 dBc, Phase noise -114 dBc at 100 KHz offset frequency, respectively, and measured results show of fabricated frequency doubler, the output power at 5.8 dBm of input power is 1.755 dBm conversion gain 1.482 dB, harmonic suppression -33.09 dBc, phase noise -98.23 dBc at 100 KHz offset frequency, respectively. This oscillator could be available to a local oscillator in K-band which used frequency doubler techniques.

Low Phase Noise VCO with X -Band Using Metamaterial Structure of Dual Square Loop (메타구조의 이중 사각 루프를 이용한 X-Band 전압 제어 발진기 구현에 관한 연구)

  • Shin, Doo-Soub;Seo, Chul-Hun
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.47 no.12
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    • pp.84-89
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    • 2010
  • In this paper, a novel voltage-controlled oscillator (VCO) using the microstrip square open loop dual split ring resonator is presented for reducing the phase noise. The square-shaped dual split ring resonator having the form of the microstrip square open loop is investigated to reduce the phase noise. Compared with the microstrip square open loop resonator and the microstrip square open loop split ring resonator as well as the conventional microstrip line resonator, the microstrip square dual split ring resonator has the larger coupling coefficient value, which makes a higher Q value, and has reduced the phase noise of VCO. The VCO with 1.7V power supply has the phase noise of -123.2~-122.0 dBc/Hz @ 100 kHz in the tuning range, 11.74~11.75 GHz. The figure of merit (FOM) of this VCO is-214.8~-221.7 dBc/Hz dBc/Hz @ 100 kHz in the same tuning range. Compared with VCO using the conventional microstrip line resonator, VCO using microstrip square open loop resonator, the phase noise of VCO using the proposed resonator has been improved in 26 dB, 10 dB, respectively.

An Integrated Balun Using Bondwire Transformer (본드와이어 트랜스포머를 이용한 집적형 발룬)

  • 방현국;송병욱;이중호;이해영
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.39 no.12
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    • pp.553-558
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    • 2002
  • In this paper, an integrated balun using bondwire transformer is fabricated and measured. The bondwire transformer has 1ow conductor and substrate loss and kas high resonance frequency. So it is available to implement low loss broadband balun. From the measured results, 0.7 dB amplitude imbalance and about 2.5 $^{\circ}$ phase imbalance was achieved from 8.15 to 16.18 GHz. It is expected that the proposed balun can improve the performance of mixers, amplifiers and matching networks of antennas. It can also be integrated with other components due to its easier fabrication and smaller size than spiral transformer balun.

Effect of K/Na ratio on Piezoelectric Properties of Modified-$(K_{1-x}Na_x)NbO_3$ "Hard" Lead-free Materials

  • Im, Jong-Bong;Jeon, Jae-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.50.1-50.1
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    • 2011
  • Lead-free ceramics with a composition of 0.55 mol%$K_4CuNb_8O_23-(K_{1-x}Na_x)NbO_3$ (KCN-KNNx) where $0.45{\leq}x{\leq}0.60$ were synthesized by conventional ceramic processing. Results revealed that the addition of Na was effective in changing the microstructure and relative density of KCN-KNNx. Further, the addition of Na resulted in a slight shift of the phase transition temperatures (To-t and Tc) toward low values. A high mechanical quality factor (Qm) of 1850 was found atx=0.54, which might be due to the build-up of an internal bias field (Ei) within KCN. Thermal hysteresis in KNNx was confirmed with an increase in the Na content during the heating and cooling cycles, resulting from structural changes. Thus, KCN-KNNx with x=0.54 exhibits excellent piezoelectric properties with d33 (97 pC/N), kp (36%), and Qm (1850), being promising candidates for application in high-power piezoelectric devices.

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A study on the superconducting properties of Bi-Pb-Sr-Ca-Cu-O superconducting wire with cooling conditions. (냉각 조건에 의한 Bi-Pb-Sr-Ca-Cu-O 초전도 선재의 특성 연구)

  • Kim, Min-Ki;Choi, Hyo-Sang;Choi, Sung-Hyan;Park, Sung-Jin;Han, Byoung-Sung
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.213-215
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    • 1993
  • Silver-sheathed Bi-Pb-Sr-Ca-Cu-O wires by the powder-in-tube method were preparated to study on the superconducting properties with cooling conditions. Superconducting wires were cooled down in the furnace, air and liquid $N_2$ after sintering at $840^{\circ}C$. Critical current density of sample cooled in the furnace is $5.1{\times}10^3\;A/cm^2$ at 77K, zero magnetic field and Jc of sample cooled in the air is very low. 2223 high-Tc superconducting phase of sample cooled in the air was distroyed. Therefore, we knew that superconducting wire need to cool slowly to get the high critical current density.

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Low-power Frequency Offset Synchronization for IEEE 802.11a Using CORDIC Algorithm (CORDIC을 이용한 IEEE 802.11a용 저전력 주파수 옵셋 동기화기)

  • Jang, Young-Beom;Han, Jae-Woong;Hong, Dae-Ki
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.46 no.2
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    • pp.66-72
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    • 2009
  • In this paper, an efficient frequency offset synchronization structure for OFDM(Orthogonal Frequency Division Multiplexing) is proposed. Conventional CORDIC(Coordinate Rotation Digital Computer) algorithm for frequency offset synchronization utilizes two CORDIC hardware i.e., one is vector mode for phase estimation, the other is rotation mode for compensation. But proposed structure utilizes one CORDIC hardware and divider. Through simulation, it is shown that hardware implementation complexity is reduced compared with conventional structures. The Verilog-HDL coding and front-end chip implementation results for the proposed structure show 22.1% gate count reduction comparison with those of the conventional structure.