• 한국환경과학회지
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• 제16권1호
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• pp.1-8
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• 2007

Atmospheric photochemistry of $O_3-NOx-RH$ were considered theoretically, to clarify the reasons for the different trends of between the formation of photochemical oxidants (Ox) and its primary pollutants for the Low-and High-NOx regimes. Equations of OH, $HO_2$, and production of ozone ($O_3$) as a function of nitrogen oxides (NOx) and reactive hydrocarbons (RH) were represented in this study. For the Low-NOx regime, $HO_2$ radical is proportional to RH but independent of NOx. OH radical is proportional to NOx but inversely-proportional to RH. $O_3$ production is proportional to NOx but has a weak dependence on RH. For the High-NOx regime, OH and $HO_2$ radicals concentrations and $O_3$ production are proportional to RH but inversely-proportional to NOx. In addition, the Osaka Bay and surrounding areas of Japan were evaluated with the mass balance of odd-hydrogen radicals (Odd-H) using CBM-IV photochemical mechanism, in order to distinguish the Low- and High-NOx regimes. The Harima area (emission ratio, RH/NOx = 6.1) was classified to the Low-NOx regime. The Hanshin area (RH/NOx = 3.5) and Osaka area (RH/NOx = 4.3) were classified to the High-NOx regime.

• Journal of Advanced Marine Engineering and Technology
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• 제31권1호
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• pp.44-50
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• 2007

Diesel engines have high thermal efficiency, and they have less CO & HC emissions than another engines. while NOx & Soot emissions are very much. compared with exhaust emission standards. However, the limit level is more and more strengthened yearly due to the importance of environmental protection. So, the optimal countermeasures for the reduction of NOx & Soot emissions below limit level are required. Therefore. the author has investigated the effects of emulsified fuel on the characteristics of exhaust emissions. using an four-cycle, four-cylinder and direct injection diesel engine because the using of emulsified fuel among various methods for reducing NOx & Soot emissions is simple in installation low in cost and high in efficiency. The results of investigation according to various operating conditions are as follows : 1) Specific fuel consumption increase maximum 19.8% at low load. but is not affected at full load. 2) In case of emulsion ratio 25%, NOx emission decrease 32% at 75% load. 30% at full load. 3) In case of emulsion ratio 25%, Soot emission decrease 84% at 75% load, 59% at full load.

• 대한기계학회논문집B
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• 제29권10호
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• pp.1148-1155
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• 2005

In this study, the influence of changing combustor pressure on nitric oxide emission was investigated. Expansion of reaction region was more clear in the P$^{*}$ <1 conditions compared to the P$^{*}\geq1$ conditions, and it could be observed that flames are distinct in the P$^{*}\geq1$ conditions and that brightness is relative low and wide distribution is shown in the P$^{*}$ <1 conditions. In the respect of temperature distribution, narrow and high-temperature region was shown in the P$^{*}\geq1$ conditions. On the other hands, overall uniform temperature distributions were shown in the P$^{*}$ <1 conditions. Nitric oxide emission decreased with decreasing combustor pressure. This tendency was explained by the mean flame temperature distribution. Low NOx combustion is ascribed to wide-spread reaction region in the low combustor Pressure and oscillation were shown P$^{*}\leq0.97$, and strength and sizes of oscillation were more increased with lower pressure index. These results demonstrate that flame shape and nitric oxide emission can be controlled with changing combustor pressure.

• 한국항공우주학회지
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• 제33권7호
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• pp.70-75
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• 2005

본 연구에서는 스월 연소기에서 연료스월유동이 NOx 배출특성에 미치는 영향을 실험적으로 조사하였다. 공기와 연료스월각을 변화시키기 위해 환형베인을 사용하였고 베인각의 변화에 따라 혼합공정을 변화시켰다. 공기스월이 강한 조건에서 연료 Counter-swirl의 경우, 비연소장에서 큰 난류강도의 특성을 나타내고 상대적으로 고주파 영역까지 높은 에너지를 가지고 있으며, 고온 영역이 좁게 나타났다. 이러한 연료 counter-swirl 영향으로 저NOx 배출특성이 나타났으며, NOx 저감 기구가 논의되었다.

• 에너지공학
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• 제13권2호
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• pp.144-151
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• 2004

희박 예혼합 연소방식을 채용한 150MW급 대형 저 NOx 가스터빈 연소기에서 발생하는 급격한 연소진동 발생을 저감하였다. 희박 예혼합 연소기에서는 연소튜닝이 적절히 이루어지지 많은 경우에 연소불안정에 기인한 높은 연소진동의 발생과 함께 NOx 배출량이 높아질 가능성이 있다. 대상 가스터빈의 연소 모드 전환 중에 발생하는 연소진동의 주파수와 크기는 각각 80Hz및 4-9psi로 나타났으며, 대기온도가 낮아짐에 따라 연소진동의 크기가 증가하는 경향을 보였다. 연소진동에 영향을 미치는 인자로서 버너노즐로 공급되는 연료유량을 균등화하기 위한 연소튜닝과 연소모드 전환시 연료라인에 연료를 미리 공급(prefilling)하는 것이 화염안정에 매우 큰 효과가 있었다. 그 결과 연소모드 전환 중에 발생하는 연소진동을 2.5psi까지 저감할 수 있었으며, 150 MW기저부하 운전 중에 NOx 발생량을 35-43ppm(15% $O_2$)으로 유지할 수 있었다.

• 한국연소학회지
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• 제14권1호
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• pp.19-24
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• 2009

A novel low NOx oil burner of 0.7 MW (for a 1 ton steam/hr industrial boiler) was designed and tested to investigate the combustion characteristics through in-flame measurement and flue gas analysis. Flame shape was observed by CCD camera and $CH^*/{C_2}^*$ radical distribution in the flame were observed, along with measurement of flue gas composition such as NOx and CO, for various heat inputs, excess airs and pressure of the fuel spary nozzles. The flame showed the two-zone structure: fuel-rich and fuel-lean zone, which was very favorable for the low-NOx combustion, and the NOx emission for haevy oil combustion was significantly reduced to < 150 ppm at 4 % $O_2$, compared with the NOx level of a conventional heavy oil burner.

• 한국분무공학회지
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• 제21권3호
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• pp.130-136
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• 2016

NOx and PM are important air pollutants as vehicle management policy aspect. Medium-duty truck is the main source of the pollutants although the vehicle market share is only 3.5%. National emission portion of NOx and PM form the mobile sourece are 14% and 16% respectively. In this study it was investigated that characteristics of air pollutants emission on medium duty truck equipped with EGR and SCR system. Vehicle's test reflected driving cycle on the chassis dynamometer, and applied test cycle was WHVC(World Harmonized Vehicle Cycle) mode. The test cycle include three segments, represent urban, rural and motorway driving. Based on the test results NOx, PM, HC were less emitted form SCR vehicle than EGR vehicle. And CO was less emitted form EGR vehicle than SCR vehicle due to CO oxidation reaction on DPF surface. And most air pollutants reduced as average vehicle speed increased. Pollutants were less emitted on motorway section than urban and rural sections. But highly NOx emission on motorway section was verified according to increased EGR ratio on fast vehicle speed. HC and CO additional emission was identified as 68%, 58% respectively during SCR vehicle's cold engine start emission test. NOx additional emission was detected by 24% on SCR vehicle's condition of engine cold start while not detected on vehicle equipped with EGR. SCR vehicle's additional NOx emission was derived from low reaction temperature during engine cold start condition. medium-duty truck emission characteristics were investigated in this study and expected to used to improve air pollutants management policy of medium-duty truck equipped with SCR & EGR.

• 한국연소학회지
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• 제11권4호
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• pp.22-26
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• 2006

To meet the environmental requirements, Doosan Heavy Industries & Construction Co., Ltd. (Doosan) had developed low NOx pulverized coal burner and it was applied to boiler retrofit project, 130 ton/hr coal fired cogeneration boiler, in 2003. NOx emissionand unburned carbon (UBC) in fly ash were measured during the commissioning tests. In this paper, the operation results of low NOx pulverized coal burner installed in 130 ton/hr coal fired boiler are presented. Burners emitted 160 ppm (@6 % $O_2$ basis) NOx and 3 % UBC with Chinacoal containing 0.86 % fuel nitrogen. And also it was shown that NOx emission rate of low NOx pulverized coal burner is linearly increased with fuel-nitrogen fraction of coal.

• 대한기계학회논문집
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• 제19권1호
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• pp.277-283
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• 1995

For the development of low NO$_{x}$ gas burners aimed for absorption chiller/heater unit, three proto type burners of different capacity (265000, 498000, and 664000 kcal/h) have been manufactured through a combustion method of step-by-step air injection. In order to characterize the overall features of the flame and the properties of the emission gas, the temperature of the flame and the concentration of NO$_{x}$ and CO were determined. The main factors in the design of burners (the area of primary air injection, the diameter of secondary air injection hole, fuel nozzle diameter) were observed to increase linearly with the scale-up of burner capacity. The flame temperature profiles of the burners were observed to be almost similar, irrespective of their capacity. However, as their capacity increased, the flame temperature slightly increased and the hot region of the flames moved to ward the flame tip along with the expansion to the direction of radius. From the proto type units, the amount of their NO$_{x}$ emission was determined to be around 25 - 30 vppm(3% )$_{2}$) and the CO emission was less than 19 vppm (3% $O_{2}$).TEX>).

• International Journal of Automotive Technology
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• 제6권6호
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• pp.591-598
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• 2005

A three-way catalyst system of a natural gas vehicle (NGV) has characteristics of higher fuel consumption and higher thermal load than a lean-bum catalyst system. To meet stringent emission standards in the future, NGV with the lean-bum engine may need a catalyst system to reduce the amounts of HC, CO and NOx emission, although natural gas system has low emission characteristics. We conducted experiments to evaluate the conversion efficiency of the NOx reduction catalyst for the lean-burn natural gas engine. The NOx reduction catalysts were prepared with the ${\gamma}-Al_{2}O_3$ washcoat including Ba based on Pt, Pd and Rh precious metal. In the experiments, effective parameters were space velocity, spike duration of the rich condition, and the temperature of flowing model gas. From the results of the experiments, we found that the temperature for maximum NOx reduction was around $450^{\circ}C$, and the space velocity for optimum NOx reduction was around $30,000\;h^{-1}$ And we developed an evaluation model of the NOx reduction catalyst to evaluate the conversion performance of each other catalysts.