• Journal of Environmental Science International
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• v.16 no.11
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• pp.1247-1255
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• 2007

Soil biofiltration is an environmentally-sound technology for elimination of VOCs, odorous and $NO_X$ compounds from a low concentration, high volume waste gas streams because of its simplicity and cost-effectiveness. This study investigated the optimal mixture fraction of briquet ash, compost, soil and loess for $NO_X$ degradation. Extreme vertices design was used to examine the role of four components on $NO_X$ degradation. Under our experimental conditions, 74.5% of $NO_X$ degradation was observed, using a model mixture(25% briquet ash, 10% compost, 30% soil and 40% loess) containing 100 ppb of NO. It was shown that experimental design analysis could allow selecting optimal conditions in such biodegradation processes in this study.

• Carbon letters
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• v.3 no.4
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• pp.198-204
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• 2002

In this paper, impregnated activated carbon fiber (IACF) was manufactured to pitch-based activated carbon fibers (ACF) with potassium hydroxide (KOH) by using wet impregnation method to raise nitrogen oxides ($NO_x$) adsorptivity. The properties of IACF were observed using EPMA, TGA and DSC and $NO_x$ adsorptivity was observed at high and low temperature. Before and after adsorption was analyzed using ToF-SIMS for examine surface characterization of adsorbed $NO_x$. The results showed that the better adsorptivity appeared for increasing KOH ratio. So, $NO_x$ adsorptivity showed result that is proportional between KOH and the adsorbed amount. On the other hand, adsorbent that manufactured without washing was better $NO_x$ adsorptivity than adsorbent that manufactured with washing. The behavior of adsorption show that crossing time of NO and $NO_2$ delayed for a rising adsorptivity. And NO ratio increased but $NO_2$ ratio decreased according as KOH ratio increases. $NO_x$ was confirmed through surface analysis that remain in $NO_2^-$ and $NO_3^-$ form on IACF surface.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.131-131
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• 2012

We present our recent temperature-programmed desorption (TPD) study on catalytic reductions of $NO_x$ such as NO, $NO_2$, and $N_2O$ over rutile $TiO_2$(110) surfaces. Our results indicate that $NO_2$/NO readily reacts to give NO/$N_2O$ desorption at the substrate temperature as low as 100 K/70 K. Interestingly, $N_2O$, however, does not dissociate into $N_2$ and $O_{BBO}$ over the oxygen vacancy on the $TiO_2$(110) surface. Successive reduction of NO and $NO_2$ into $N_2O$ and NO, respectively, leaves oxygen atoms on the $TiO_2$(110) surface in a form of $O_{ad}$, which can induce additional reductive channels of NO and $NO_2$ at higher temperatures up to 400 K. During the repeated TPD cycles of $NO_x$, our x-ray photoelectron spectroscopy (XPS) analysis indicates that no N atom accumulates on the $TiO_2$ surface.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.1
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• pp.39-46
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• 2011

NO oxidation is an important prerequisite step to assist the selective catalytic reduction (SCR) at low temperatures ($<200^{\circ}C$). Therefore, we conducted the lab- and bench-scales experiments appling the sodium chlorite powder ($NaClO_2(s)$) for the oxidation of NO to $NO_2$ and the carbon-based catalyst for the reduction of $NO_x$ and $SO_2$; the lab- and bench-scales experiments were conducted in laboratory and iron-ore sintering plant, respectively. In the lab-scale experiment, known concentrations of $NO_x$ (200 ppm), $SO_2$ (75 ppm), $H_2O$ (10%) and $NH_3$ (400 ppm) in 2.6 L/min were introduced into a packed-bed reactor containing $NaClO_2(s)$, then gases produced by the reaction with $NaClO_2(s)$ were fed into the carbon-based catalyst (space velocity = $2,000hr^{-1}$) at $130^{\circ}C$. In the bench-scale experiment, flue gases of $50Nm^3/hr$ containing 120 ppm NO and 150 ppm $SO_2$ were taken out from the duct of iron-ore sintering plant, then introduced into the flow reactor; $NaClO_2(s)$ were injected into the flow reactor using a screw feeder. Gases produced by the reaction with $NaClO_2(s)$ were introduced into the carbon-based catalyst (space velocity = $1,000hr^{-1}$). Results have shown that, in both lab- and bench-scales experiments, NO was oxidized to $NO_2$ by $NaClO_2(s)$. In addition, above 90% of $NO_x$ and $SO_2$ removal were obtained at the carbon-based catalyst. These results lead us to suggest that the combination of $NaClO_2(s)$ with the carbon-based catalyst has the potential to achieve the simultaneous removal of $NO_x$ and $SO_2$ at low temperature ($<200^{\circ}C$).

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.1-3
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• 2013

The premixed combustion system applying exhaust gas recirculation was investigated to achieve the low pollutant emission and the high thermal efficiency. In this study, it was studied the effects of EGR on the thermal efficiency, $NO_x$ and CO emissions with various EGR ratios and equivalence ratios. As results, when equivalence ratio was increased, thermal efficiency increased and $NO_x$ and CO concentration increased. When EGR was applied, $NO_x$ and CO concentration decreased and thermal efficiency increased. Especially, in the case of 15% of EGR ratio at 0.85 of equivalence ratio, $NO_x$ and CO concentration will be a smaller than these of a current operating condition of the boiler and thermal efficiency was about 1.7% higher.

• Korean Journal of Environmental Agriculture
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• v.26 no.1
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• pp.1-6
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• 2007

In view of energy supply, biogas can be seen as alternative fuel by substituting considerable amount of fossil fuel and may be utilized for heat and power production or for transport fuel production ($CH_4-enriched$ biogas). The aim of this research is to analyse the emission of $NO_x$ and CO from biogas fired combustion engine for electric power production. The result indicate a significant effect of biogas composition ($CH_4-CO_2$ ratio) and biogas flow rate on the air pollutants emission. The emission factors from this study were compared with those of U.S. EPA. Low $CH_4-CO_2$ ratio condition typically shows the lower $NO_x$ and CO emission than higher $CH_4-CO_2$ ratio condition. At normal $CH_4-CO_2$ ratio (7:3) emission factors of $NO_x$ and CO were 1.29 and 30.43 g/MMBtu, respectively. At low $CH_4-CO_2$, ratio (6:4) emission factors of $NO_x$ and CO were 0.646 and 60.86 g/MMBtu, respectively, It should be emphasized that the actual emission may vary considerably from these results due to operating conditions including torque load and engine speed.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2874-2879
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• 2008

The Selective catalytic reduction(SCR) system is a highly-effective device of $NO_x$ reduction for diesel engines. Generally, the ammonia($NH_3$) generated from a liquid urea-water solution is used for the reductant. The ideal ratio of $NH_3$ molecules to $NO_x$ molecules is 1:1 based on $NH_3$ consumption and having $NH_3$ available for reaction of all of the exhaust $NO_x$. However, under the too low and too high temperature condition, the $NO_x$ reduction efficiency becomes lower, due to temperature window. And space velocity also affects to $NO_x$ conversion efficiency. This paper reviews a laboratory study to evaluate the effects of $NO_x$ and $NH_3$ concentrations, gas temperature and space velocity on the $NO_x$ conversion efficiency of the SCR system. The maximum conversion efficiency of $NO_x$ was indicated when the $NH_3$ to $NO_x$ ratio was 1.2 and the space velocity was $60,000\;h^{-1}$. The results of this paper contribute to improve overall $NO_x$ reduction efficiency and $NH_3$ slip.

• Journal of Environmental Science International
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• v.15 no.4
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• pp.333-340
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• 2006

A (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ catalyst were prepared by co-precipitation method and used for low-temperature selective catalytic reduction (SCR) of $NO_x$ with ammonia in the presence of oxygen. The properties of the catalysts were studied by X-ray diffraction (XRD), temperature programmed reduction (TPR) and scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS). The experimental results showed that (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ catalyst yielded 81% NO conversion at temperature as low as $150^{\circ}C$ and a space velocity of $2,400\;h^{-1}$. Crystalline phase of $Mn_{2}O_3$ was present at ${\ge}\;15%$ Mn on $V_{2}O_{5}/TiO_{2}$. XRD confirmed the presence of manganese oxide ($Mn_{2}O_{3}$) at $2{\theta}=32.978^{\circ}(222)$. The XRD patterns presented of (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ did not show intense or sharp peaks for manganese oxides and vanadia oxides. The TPR profiles of (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ catalyst showed main reduction peat of a maximum at $595^{\circ}C$.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.4
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• pp.415-425
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• 2003

A single particle analysis, called low-Z electron probe X-ray microanalysis was applied to characterize the atmospheric aerosols collected during Asian Dust storm events in the year of 2000 and 2001. Most frequently encountered chemical species were the soil-originated species such as aluminosilicates, silicon dioxide, and calcium carbonate. Also various species such as carbon -rich, organics, sea salts, and some reacted calcium carbonate were identified. The observation of internally mixed particles oi calcium carbonate, calcium nitrate and/or calcium sulfate shows the occurrence of the heterogeneous reaction between Asian Dust particles and NO$_{x}$ and/or SO$_{x}$ species in the atmosphere.ere.

• Journal of the Korean Wood Science and Technology
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• v.46 no.5
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• pp.597-609
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• 2018

Korea Forest Service has supplied 76 industrial wood pellet boilers from 2011 to 2015 through subsidy programs. Since carbon monoxide (CO) and nitrogen oxides ($NO_x$) generated during boiler combustion are substances that lead to death in the case of acute poisoning, it is very important to reduce emissions. Therefore, the CO and $NO_x$ emission values of 63 boilers excluding the hot air blower and some boilers initially supplied were analyzed. The emission factor was also calculated from the measured exhaust gas concentration (based on exhaust gas $O_2$ concentration of 12%). The average value of CO emitted from industrial wood pellet boilers was 49 ppm and it was confirmed that the CO concentration was decreasing as the years passed. The emission factor of CO was 0.73 g/kg. The average value of $NO_x$ emitted from industrial wood pellet boilers was 67 ppm and the emission factor of $NO_x$ was 1.63 g/kg. Unlike CO, there was no tendency to decrease according to the installation year. Both CO and $NO_x$ measurements met the limits of the Ministry of Environment. These $NO_x$ emission factors were compared with the $NO_x$ emission factors produced by certified low $NO_x$ burners. The $NO_x$ emission factor of industrial wood pellet boilers was about 1.9 times that of certified low $NO_x$ LNG combustors and about 0.92 times that of coal combustion.