• Title/Summary/Keyword: Low $CO_2$ emissions

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Influence of Co incorporation on morphological, structural, and optical properties of ZnO nanorods synthesized by chemical bath deposition

  • Iwan Sugihartono;Novan Purwanto;Desy Mekarsari;Isnaeni;Markus Diantoro;Riser Fahdiran;Yoga Divayana;Anggara Budi Susila
    • Advances in materials Research
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    • v.12 no.3
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    • pp.179-192
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    • 2023
  • We have studied the structural and optical properties of the non-doped and Co 0.08 at.%, Co 0.02 at.%, and Co 0.11 at.% doped ZnO nanorods (NRs) synthesized using the simple low-temperature chemical bath deposition (CBD) method at 95℃ for 2 hours. The scanning electron microscope (SEM) images confirmed the morphology of the ZnO NRs are affected by Co incorporation. As observed, the Co 0.08 at.% doped ZnO NRs have a larger dimension with an average diameter of 153.4 nm. According to the International Centre for Diffraction Data (ICDD) number #00-036-1451, the x-ray diffraction (XRD) pattern of non-doped and Co-doped ZnO NRs with the preferred orientation of ZnO NRs in the (002) plane possess polycrystalline hexagonal wurtzite structure with the space group P63mc. Optical absorbance indicates the Co 0.08 at.% doped ZnO NRs have stronger and blueshift bandgap energy (3.104 ev). The room temperature photoluminescence (PL) spectra of ZnO NRs exhibited excitonicrelates ultraviolet (UV) and defect-related green band (GB) emissions. By calculating the UV/GB intensity, the Co 0.08 at.% is the proper atomic percentage to have fewer intrinsic defects. We predict that Co-doped ZnO NRs induce a blueshift of near band edge (NBE) emission due to the Burstein-Moss effect. Meanwhile, the redshift of NBE emission is attributed to the modification of the lattice dimensions and exchange energy.

Effect of Carbon Dioxide-reduced Cement on Properties of Lightweight-foamed Concrete (이산화탄소 저감형 시멘트 함량에 따른 경량기포 콘크리트의 물성평가)

  • Im, Donghyeok;Lee, Won-Ki
    • Journal of Environmental Science International
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    • v.29 no.6
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    • pp.605-612
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    • 2020
  • To improve the initial strength and stability of lightweight-foamed concrete, which shows suitable sound absorption and insulation characteristics, the effect of CO2-reduced cement on the properties of the concrete was investigated. Various mixing ratios were applied by substituting a certain amount of slag and Calcium Sulfo Aluminate (CSA) in CO2-reduced Ordinary Portland Cement (OPC) and the physical properties of the samples were examined using the Korean Standard. The kiln temperatures of the CSA were 100-200℃ ; these values are lower than those of OPC and can lead to energy saving. In addition, the low limestone content reduces greenhouse gas emissions by 20 %. Adding a small amount of CSA in OPC content activates Ca-Al-H2-based hydrates, and the initial compressive strength of the concrete is improved. As the CSA content increased, the thermal conductivity of the concrete decreased by up to 8% compared to plain concrete, thus indicating an improvement in its insulation. Therefore, the settlement stability was improved as the addition of CSA shortened the setting time.

Properties of Low Carbon Type Hydraulic Cement Binder Using Waste Recycle Powder (무기계 재생원료를 사용한 저탄소형 수경성 시멘트 결합재의 특성)

  • Song, Hun;Shin, Hyeon-Uk;Tae, Sung-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.22-28
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    • 2019
  • Cement is a basic material for the construction industry and it requires high temperature sintering when manufacturing cement. $CO_2$ emissions from raw materials and fuels are recognized as new environmental problems and efforts are underway to reduce them. Techniques for reducing $CO_2$ in concrete are also recommended to use blended cement such as blast furnace slag or fly ash. In addition, the construction waste generated in the dismantling of concrete structures is recognized as another environmental problem. Thus, various methods are being implemented to increase the recycling rate. The purpose of this study is to utilize the inorganic raw materials generated during the dismantling of the structure as a raw material for the low carbon type cement binder. Such as, waste concrete powder, waste cement block, waste clay brick and waste textile as raw materials for low carbon type cement binder. From the research results, low carbon type cement binder was manufactured from the raw material composition of waste concrete powder, waste cement block, waste clay brick and waste textile.

Allowable Stress Calculation of Domestic Japanese Larch Small Diameter Lumbers (국내산 낙엽송 소경각재의 허용응력 산출)

  • Kim, Yun-Hui;Shin, Il-Joong;Yang, Jung-Mo;Jang, Sang-Sik
    • Journal of the Korea Furniture Society
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    • v.23 no.2
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    • pp.214-221
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    • 2012
  • Sustainable energy consumption and increasing $CO_2$ emissions stimulate Eco-friendly industry. Wood has positive various properties as alternative energy such as solar, wind and water. Wood provide lumber, pallet, paper, pulp and fuel through production process. Even Korea republic has 63.7% of forest rates, weather condition makes low forestry production capacity. For utilization of domestic small diameter log needs study mechanical properties. In this study, various properties tested on domestic Japanese Larch small diameter lumbers and make mechanical properties table for allowable stress calculation. Result of compressive test, allowable compressive stress is 13 MPa. Allowable bending stress is 12 MPa.

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Shipboard Measurements of Air Pollutants across the Yellow Sea (황해 직선 항로상 대기오염물질의 측정)

  • 이승복;배귀남;진현철;김영성;문길주;심상규
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.1
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    • pp.33-46
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    • 2004
  • Air pollutants were measured eight times from June 1999 to June 2002 on regular ferries cruising across the Yellow Sea between Incheon in Korea and Qingdao or Tianjin in China. PM$_{10}$ and PM$_{2.5}$ were measured as particulate matters and SO$_2$, CO, and NO$_{x}$ were measured as gaseous pollutants. On each route, sampling was made, starting two hour after departure and ending two hour before arrival. Low concentrations of gaseous pollutants that were not much varied according to sampling period and location revealed that atmosphere over the sea was not directly affected by anthropogenic emissions. However, concentrations of fine particles were generally higher than those measured at Deokjeok Island, 50km west of the western seashore, at similar periods. It was believed that considerable influence of China in the form of secondary pollutants was exerted over the sea.a.a.a.

A Study on the Characteristics of Exhaust Emissions by Biodiesel Blend Waste Oil in Marine Diesel Engine (선박디젤기관에서 바이오디젤 폐혼합유의 배기배출물특성에 대한 연구)

  • Cho, Sang-Gon
    • Journal of Power System Engineering
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    • v.19 no.2
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    • pp.90-95
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    • 2015
  • Recently worldwide concern and research is being actively conducted on green energy which can reduce environmental pollution. A plant such as the natural rapeseed oil, soybean oil, palm, etc. is used as a bio source in home and industry. Biofuels is a sustainable fuel having economically benefits and decreasing environmental pollution problems caused due to fossil fuel, and it can be applied to the conventional diesel engine without changing the existing institutional structure. Waste vegetable oil contains a high cetane number and viscosity component, the low carbon and oxygen content. A lot of research is progressing about the conversion of waste vegetable oil as renewable clean energy. In this study, waste oil was prepared to waste cooking oil generated from the living environment, and applied to diesel engine to confirm the possibility and cost-effectiveness of biodiesel blend waste oil. As a result, brake specific fuel consumption and NOx was increased, carbon monoxide and soot was decreased.

Combustion Characteristics of Flameless Combustion by Reactants Injection Conditions (반응물 분사조건에 따른 무화염 연소특성 연구)

  • Hong, Seong Weon;Lee, Pil Hyong;Hwang, Sang Soon
    • Journal of the Korean Society of Combustion
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    • v.18 no.2
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    • pp.8-16
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    • 2013
  • The flameless combustion has been considered as one of the promising combustion technology for high thermal efficiency, reducing NOx and CO emissions. In this paper, the effect of air and fuel injection condition on formation of flameless combustion was analyzed using three dimensional numerical simulation. The results show that the high temperature region and the average temperature was decreased due to increase of recirculation ratio when air velocity is increased. The average temperature was also affected by entrainment length. Generally mixing effect was enhanced at low entrainment length and dilution was dominated at high entrainment length. This entrainment length was greatly affected by air and fuel injection velocity and distance between air and fuel. It is also found that the recirculation ratio and dilution effect were generally increased by entrainment length and the recirculation ratio, mixing and dilution effect are the significant factor for design of flameless combustion system.

Emissions and Combustion Dynamics with Fuel Injection Position for Low-swirl Nozzles of Gas Turbine Combustor (복합발전 가스터빈 연소기용 저선회 노즐의 연료 분사 위치에 따른 배기배출 및 연소진동 특성)

  • Jeongjae, Hwang;Won June, Lee;Min Kuk, Kim;Han Seok, Kim
    • Journal of the Korean Institute of Gas
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    • v.26 no.6
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    • pp.37-44
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    • 2022
  • In this study, two low-swirl nozzles with the same SN (Swirl Number) but different mass ratio (m) of the core part and the swirler part were designed to perform an atmospheric pressure combustion test. For each nozzle, a combustion test was conducted according to the adiabatic flame temperature, and the flame structure, emissions, and combustion instability mode were identified. Although the flame structure was significantly different, the CO emission was similar, and the NOx emission was also more related to combustion dynamics than the flame structure. Combustion dynamics and NOx emission were identified while adjusting the convection delay time by changing the position of the fuel injection nozzle. It was confirmed that when the convection delay time is in the region of (3+4n)/4T±1/4T (n=0,1,2,...), the combustion instability is strong, and in the opposite case, the combustion instability is very weak.

Estimation of Domestic Greenhouse Gas Emission of Refrigeration and Air Conditioning Sector adapting 2006 IPCC GL Tier 2b Method (국내 냉동 및 냉방부문 온실가스 배출량 산정 - 2006 IPCC GL Tier 2b 적용 -)

  • Shin, Myung-Hwan;Lyu, Young-Sook;Seo, Kyoung-Ae;Lee, Sue-Been;Lim, Cheolsoo;Lee, Sukjo
    • Journal of Climate Change Research
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    • v.3 no.2
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    • pp.117-128
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    • 2012
  • The Government of South Korea has continued its effort to fixate virtuous circle of economic growth and climate change response to cope with international demands and pressure to commitment for greenhouse gas reduction effectively. Nationally, Korean Government has established "Enforcement of the Framework Act on Low carbon, Green Growth"(2010. 4. 13) to implement national mid-term GHG mitigation goal(30% reduction by 2020 compare to BAU), which established the foundation for phased GHG mitigation by setting up the sectoral and industrial goal, adopting GHG and Energy Target Management System. Also, follow-up measures are taken such as planning and control of mid-term and short-term mitigation target by detailed analysis of potential mitigation of sector and industry, building up the infrastructure for periodic and systematic analysis of target management. Likewise, it is required to establish more accurate, reliable and detailed sectoral GHG inventory for successfully establishment and implement the frame act. In comparison to the $CO_2$ emission, Especially fluorinated greenhouse gases (HFCs, PFCs, $SF_6$) are lacking research to build the greenhouse gas inventories to identify emissions sources and collection of the applicable collection activities data. In this study, with the refrigeration and air conditioning sector being used to fluorine refrigerant(HFCs) as the center, greenhouse gas emission estimation methodology for evaluating the feasibility of using this methodology look over and mobile air conditioning, fixed air conditioning, household refrigeration equipment, commercial refrigeration equipment for the greenhouse gas emissions were calculated. First look at in terms of methodology, refrigeration and air conditioning sector GHG emissions in developing country-specific emission factors and activity data of the industrial sector the construction of the DB is not enough, it's 2006 IPCC Guidelines Tier 2a (emission factor approach) rather than the Tier 2b (mass balance approach) deems appropriate, and each detail by process, sectoral activity data more accurate, if DB is built Tier 2a (emission factor approach) can be applied will also be judged. Refrigeration and air conditioning sector in 2009 due to the use of refrigerant greenhouse gas emissions ($CO_2eq.$) assessment results, portable air conditioner 1,974,646 ton to year, fixed-mount air conditioner 1,011,754 ton to year, household refrigeration unit 4,396 ton to year, commercial refrigeration equipment 1,263 ton to year was estimated to total 2,992,037 tons.

Analysis of fuel economy characteristics depending on the fuel quality and calculation method changed (연료품질 및 연비계산 방법 변화에 따른 연비특성 분석)

  • Lee, Min-Ho;Lim, Wan-Gyu;Lim, Jae-Hyuk;Kim, Ki-Ho
    • Journal of Power System Engineering
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    • v.20 no.4
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    • pp.52-62
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    • 2016
  • Nowadays, emissions of a vehicle are been getting by testing on a chassis dynamometer and a test modes. Also, fuel efficiency is calculated by carbon-balance method that is applying the emissions(CO, THC and $CO_2$) to the fuel calculation formular. In Korea, before 2014, the formular did not include the fuel factors (density, net heat value and carbon weight fraction), but the constants were based on the fuel properties of 2000s. So, this formular did not consider a characteristic of test fuel property that was changed when progressing fuel efficiency test. The characteristics of test fuel property which was distributed in domestic have a difference of quality depending on production regions and oil-refining facilities. Because the fuel properties are variable value during refineries, crude oils and blending contents of a bio-fuel, vehicle fuel is changed for each test. Therefore, the fuel qualities need to apply for a fuel economy test. In this paper, changing patterns of a fuel properties were reviewed during history of fuel standards. Also, the appropriateness of the methods was discussed by calculating and comparing fuel economies with the fuel factors and the constants.