• Title/Summary/Keyword: Loss of Steel Products

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Sulphate Reducing Bacteria and Methanogenic Archaea Driving Corrosion of Steel in Deep Anoxic Ground Water

  • Rajala, P.;Raulio, M.;Carpen, L.
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.221-227
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    • 2019
  • During the operation, maintenance and decommissioning of nuclear power plant radioactive contaminated waste is produced. This waste is stored in an underground repository 60-100 meters below the surface. The metallic portion of this waste comprises mostly carbon and stainless steel. A long-term field exposure showed high corrosion rates, general corrosion up to 29 ㎛ a-1 and localized corrosion even higher. High corrosion rate is possible if microbes produce corrosive products, or alter the local microenvironment to favor corrosion. The bacterial and archaeal composition of biofilm formed on the surface of carbon steel was studied using 16S rRNA gene targeting sequencing, followed by phylogenetic analyses of the microbial community. The functional potential of the microbial communities in biofilm was studied by functional gene targeting quantitative PCR. The corrosion rate was calculated from weight loss measurements and the deposits on the surfaces were analyzed with SEM/EDS and XRD. Our results demonstrate that microbial diversity on the surface of carbon steel and their functionality is vast. Our results suggest that in these nutrient poor conditions the role of methanogenic archaea in corrosive biofilm, in addition to sulphate reducing bacteria, could be greater than previously suspected.

The Study on the Acceleration Factor of Coastal Outdoor Corrosion test, Salt Spray Test and Accelerated Corrosion Test using 0.5wt% carbon steel (0.5wt% 탄소강을 이용한 해안 야외부식시험과 염수분무시험, 가속부식시험의 가속계수에 대한 연구)

  • Cho, E.Y.;Gwon, G.B.;Cho, D.H.;Kim, J.Y.
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.209-214
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    • 2013
  • In the industry, accelerated corrosion test is used for the life time prediction. When anti-corrosion test proceeds in real environments, it is difficult that we predict and evaluate the corrosion life time because of the long test time such as 10 years or more time. Accelerated corrosion test and Salt spray test are able to test corrosion life time of products in the laboratory instead of outdoor corrosion test. Experimental procedure is selected for the corrosion standard specimen, exposure of the specimens, measurements of the mass loss and evaluating the mass loss data. As a result, the acceleration factor of the accelerated corrosion test to the outdoor corrosion test is 414.8. Therefore we can predict the corrosion life time of carbon steel during a short time period.

Strength Properies of Concrete Using Waste Slag Aggregates as the Products of Steel Industry (산업폐기물인 제강 슬래그쇄석을 이용한 콘크리트의 강도특성)

  • Lee, Bong-Hak;Kim, Tae-Kyung
    • Journal of Industrial Technology
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    • v.16
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    • pp.45-50
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    • 1996
  • An experimental study os performed to examine the feasibility of using wastes steel furnace slag construction materials and its utility as a replacement for the natural resources to prevent the economic loss was investigated. A half factorial exprements was performed with the variables of W/C ratio, S/A, Coarse aggrigate/Slag ratio and slump as a preliminary study for optimum mix design of concrete. The results show that the W/C ratio and Slump ratio are the most important factor to the concrete strength. The substitute of waste Slag up to 100% has little influence, saying that it can substitute the coarse aggregate without damaging the concrete properties.

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Crashworthiness Evaluation of Bridge Barriers Built with Hot-dip Zinc-aluminium-magnesium Alloy-coated Steel (고내식성 용융합금도금강판 적용 교량난간의 충돌성능 평가)

  • Noh, Myung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.3
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    • pp.171-176
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    • 2016
  • This paper proposes road safety facilities applying Hot-dip zinc-aluminum-magnesium alloy-coated steel sheets and coils to reduce the loss of function caused by the corrosion of steel in the service state. Vehicle crash simulations and full-scale crash tests were carried out to provide reliable information on evaluating the crash performance with the products of road safety facilities built with hot-dip zinc-aluminum-magnesium alloy-coated steel. From the results of the simulations and full-scale crash tests, the impact behaviors evaluated by the three-dimensional crash simulations considering the strain-rate dependency in a constitutive model were similar to those obtained from the full-scale crash test results. The full-scale crash test results met the crashworthiness evaluation criteria; hence, the proposed bridge barrier in this paper is ready for field applications.

A Study of Zn-coating Weight in Hotdip Galvanizing Process (응용아연(응용亞鉛) 도금공정(鍍金工程)에서 아연부착량(亞鉛附着量)에 관한 연구)

  • Kim, Wan-Chul;Kang, Sung-Kun;Nam, Seung-Eui
    • Journal of the Korean institute of surface engineering
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    • v.11 no.1
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    • pp.5-13
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    • 1978
  • This experiment intends to study Zn-coating weight through galvanixing process. A through examination has been carried out on the change of steel-composition, galvanizing-temperature, dipping-rime, Fe-loss when other factors were regular. Activation energy needed for Fe-loss was obtained and within this sample, the best condition which has influence on coating weight was found so as to reduce Fe-loss. As Fe-loss was diminidhed, the amount of product of Dross and Zn-using amount per total products could be reduced. The results of experiments are as follow. 1. Zn-coating thickness was increased by the rising Zn-bathtemperature and was the maximum at 8-minutes dipping time. 2. The coating weight was greatly influency by Si. As in other samples, the proportion of increasing was very rate after 20minutes. If the dipping time prolonged, the increasing amounts of Fe-loss are more greatly. 3. Activation Energy needed for Fe-loss was as follows Such numerical values were most equal to those of the activation energy which had influences on the growth of ${\gamma}$-phase. Sample - I = 18,500 Cal/mole Sample - III = 22,000 Cal/mole Sample - V = 42,300 Cal/mole

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Productivity Improvement by developing statistical Model

  • Shin Ill-Chul;Park Jong-Hwan
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2002.05a
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    • pp.225-231
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    • 2002
  • POSCO $\#2$ Stainless steel making plant produces more than 600 thousand ton per year with a variety of products consisting of austenite and ferrite stainless steel to meet custrmers' needs since 1996. The plant has four different major processes, that are, EAF-AOD-VOD-CC to finally produce semi-product called as slab. In this study, we importantly took AOD process into consideration due to its roles such as to check and verify the final qualities through sampling inspection. But the lead-time from sampling to its verification takes five to ten minutes causing produrtivity loss as muck as the lead-time as a result. Of all indices for quality and process control the plant has, carbon ingredient in liquid type of steel is the most important since it affects in a great way to the characteristics of steel, if any problem. customers not satisfied with quality could issue a claim; therefore there is no way hut to guarantee it before delivery. in this study, to reasonably reduce lead-time ran save a cycle time and finally improve our productivity from a state-or-art alternative just such as applying statistical model based on multi-regression analysis into the A.O.D line by analyzing the statistical and technical relationship between carbon and the relevant some vital independent variables. In consequence, the model with R-square $87\%$ allowed the plant to predict, abbreviating the process in relations to sampling to verification. approximately the value of [C] so that operators could run the process line with reliability on data automatically calculated instead of actual inspection. In the future, we are going to do the best to share this type of methodology with other processes, if possible, to apply into them.

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Monitoring Cathodic Shielding and Corrosion under Disbonded Coatings

  • Varela, F.;Tan, M. YJ;Hinton, B.;Forsyth, M.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.109-114
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    • 2017
  • Monitoring of corrosion is in most cases based on simulation of environmental conditions on a large and complex structure such as a buried pipeline using a small probe, and the measurement of thermodynamics and kinetics of corrosion processes occurring on the probe surface. This paper presents a hybrid corrosion monitoring probe designed for simulating deteriorating conditions wrought by disbonded coatings and for measuring current densities and distribution of such densities on a simulated pipeline surface. The concept of the probe was experimentally evaluated using immersion tests under cathodic protection (CP) in high resistivity aqueous solution. Underneath the disbonded area, anodic currents and cathodic currents were carefully measured. Anodic current densities were used to calculate metal loss according to Faraday's law. Calculated corrosion patterns were compared with corrosion damage observed at the surface of the probe after a series of stringent tests. The capability of the probe to measure anodic current densities under CP, without requiring interruption, was demonstrated in high resistivity aqueous solution. The pattern of calculated metal loss correlated well with corrosion products distribution observed at the array surface. Working principles of the probe are explained in terms of electrochemistry.

A Cutting Stock Problem in the Sheet Steel Cutting Production (강판 절단 생산에서의 CSP)

  • 오세호
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.18 no.35
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    • pp.47-52
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    • 1995
  • The aim of this paper is to suggest the cutting stock problems which are two-dimensional in form, but can be treated as the optimization methods for one-dimensional cutting stock problem by exploiting the length requirement of the products. The solution method consists of two stages. The first calculates the number of roll pieces of each size. Next, 1-dimensional cutting stock model is set up. One heuristic method to calculate the number of each roll is suggested. The trim loss minization criteria are used to design the objective function. This model can be solved by the conventional cutting stock procedures based on enumerating the possible cutting patterns.

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Quality Prediction Model for Manufacturing Process of Free-Machining 303-series Stainless Steel Small Rolling Wire Rods (쾌삭 303계 스테인리스강 소형 압연 선재 제조 공정의 생산품질 예측 모형)

  • Seo, Seokjun;Kim, Heungseob
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.44 no.4
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    • pp.12-22
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    • 2021
  • This article suggests the machine learning model, i.e., classifier, for predicting the production quality of free-machining 303-series stainless steel(STS303) small rolling wire rods according to the operating condition of the manufacturing process. For the development of the classifier, manufacturing data for 37 operating variables were collected from the manufacturing execution system(MES) of Company S, and the 12 types of derived variables were generated based on literature review and interviews with field experts. This research was performed with data preprocessing, exploratory data analysis, feature selection, machine learning modeling, and the evaluation of alternative models. In the preprocessing stage, missing values and outliers are removed, and oversampling using SMOTE(Synthetic oversampling technique) to resolve data imbalance. Features are selected by variable importance of LASSO(Least absolute shrinkage and selection operator) regression, extreme gradient boosting(XGBoost), and random forest models. Finally, logistic regression, support vector machine(SVM), random forest, and XGBoost are developed as a classifier to predict the adequate or defective products with new operating conditions. The optimal hyper-parameters for each model are investigated by the grid search and random search methods based on k-fold cross-validation. As a result of the experiment, XGBoost showed relatively high predictive performance compared to other models with an accuracy of 0.9929, specificity of 0.9372, F1-score of 0.9963, and logarithmic loss of 0.0209. The classifier developed in this study is expected to improve productivity by enabling effective management of the manufacturing process for the STS303 small rolling wire rods.

Correlation of Surface Chloride and Corrosion Amount for Steel Member Exposed in Marine Environment (해양환경에 노출된 강부재의 표면염분과 부식량 상관관계)

  • Min-Gyun Ha;Chang-Jae Heo;Hoon Yoo;Jin-Hee Ahn
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.4
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    • pp.45-53
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    • 2023
  • In this study, to analyze the correlation of surface chloride and corrosion amount level according to the installation location of steel members exposed to the marine environment, the surface chloride and mean corrosion depth were evaluated by member units for box girder members of the offshore steel bridge and box specimens. The surface chloride was measured monthly using the Bresle method for one year. The corrosion amount was evaluated by converting the weight loss due to corrosion products generated in the monitoring steel plate into mean corrosion depth. As a measurement result of the surface chloride and corrosion amount, relative differences in surface chloride and mean corrosion depth were appeared depending on the shape or installation location of the steel members. Moreover, even if members of the same shape were installed in the same bridge, it was confirmed that the corrosion amount was increased locally and rapidly. The tendency of corrosion amount depending on the surface chloride was evaluated to analyze the correlation between surface chloride and corrosion amount, and the relation equations that can asseses the corrosion amount depending on the surface chloride were analyzed. From the results of the correlation between surface chloride and corrosion amount, it was found that the corrosion amount of the steel member affected by the surface chloride was varied up to about 1.15 times depending on the structural detail.