• Title/Summary/Keyword: Lopez

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Effect of Gas Diffusion Layer on La0.8Sr0.2CoO3 Bifunctional Electrode for Oxygen Reduction and Evolution Reactions in an Alkaline Solution (알칼리용액에서 산소환원 및 발생반응에 대한 La0.8Sr0.2CoO3 전극의 기체확산층 영향)

  • LOPEZ, KAREEN J.;YANG, JIN-HYUN;SUN, HO-JUNG;PARK, GYUNGSE;EOM, SEUNGWOOK;RIM, HYUNG-RYUL;LEE, HONG-KI;SHIM, JOONGPYO
    • Journal of Hydrogen and New Energy
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    • v.27 no.6
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    • pp.677-684
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    • 2016
  • Various commercially available gas diffusion layers (GDLs) from different manufacturers were used to prepare an air electrode using $La_{0.8}Sr_{0.2}CoO_3$ perovskite (LSCP) as the catalyst for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in an alkaline solution. Various GDLs have different physical properties, such as porosity, conductivity, hydrophobicity, etc. The ORR and OER of the resulting cathode were electrochemically evaluated in an alkaline solution. The electrochemical properties of the resulting cathodes were slightly different when compared to the physical properties of GDLs. Pore structure and conductivity of GDLs had a prominent effect and their hydrophobicities had a minor effect on the electrochemical performances of cathodes for ORR and OER.

The genetically healthy terrestrial orchid Liparis krameri on southern Korean Peninsula

  • CHUNG, Mi Yoon;CHUNG, Jae Min;SON, Sungwon;MAO, Kangshan;LOPEZ-PUJOL, Jordi;CHUNG, Myong Gi
    • Korean Journal of Plant Taxonomy
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    • v.49 no.4
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    • pp.324-333
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    • 2019
  • Neutral genetic diversity found in plant species usually leaves an indelible footprint of historical events. Korea's main mountain range (referred to as the Baekdudaegan [BDDG]), is known to have served as a glacial refugium primarily for the boreal and temperate flora of northeastern Asia. In addition, life-history traits (life forms, geographic range, and breeding systems) influence the within- and among-population genetic diversity of seed plant species. For example, selfing species harbor significantly less within-population genetic variation than that of predominantly outcrossers. A previous study of two Liparis species (L. makinoana and L. kumokiri) emphasizes the role of the abovementioned factors shaping the levels of genetic diversity. Liparis makinoana, mainly occurring on the BDDG and self-incompatible, harbors high levels of within-population genetic diversity (expected heterozygosity, HeP = 0.319), whereas there is no allozyme variation (HeP = 0.000) in L. kumokiri, which is self-compatible and mainly occurs in lowland hilly areas. To determine if this trend is also found in other congeners, we sampled five populations of L. krameri from the southern part of the Korean Peninsula and investigated the allozyme-based genetic diversity at 15 putative loci. The somewhat intermediate levels of within-population genetic variation (HeP = 0.145) found in L. krameri are most likely due to its occurrence in mountainous areas that, despite being outside of the main ridge of the BDDG, still served as refugia, and a self-incompatible breeding system. Management strategies are suggested for L. krameri and L. makinoana based on the levels and distribution of genetic diversity and inbreeding.

A study of Koreans and Mexicans opinion's of Korean society's perception of Mexico (한국인과 멕시코인의 관점에서 한국사회가 가지는 멕시코에 대한 인식에 관한연구)

  • Coutino Lopez, Gloriana;Kim, Boyeun
    • Journal of Digital Convergence
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    • v.16 no.7
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    • pp.401-408
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    • 2018
  • In the past years, the influx of Korean tourists to international destinations has seen a significant rise, especially in non-Asian countries. However, Mexico is still far from a popular destination to the average Korean tourist. Using Keller's brand equity model, this paper researches Koreans' opinions and general brand image of Mexico in an attempt to identify both the positive and negative perceptions they have of this country. Keller's brand model analyses four different levels of engagement between the customers and the brand. We want to know the degree to which Koreans have been engaged in Mexico as a brand nation and as a tourist destination. Research findings through this study will reveal the needs and insights that offer opportunities relevant for the planning, creation, design and development of new approaches for Mexico's nation brand promotion.

Accuracy of combination rules and individual effect correlation: MDOF vs SDOF systems

  • Reyes-Salazar, Alfredo;Valenzuela-Beltran, Federico;de, Leon-Escobedo, David;Bojorquez, Eden;Lopez-Barraza, Arturo
    • Steel and Composite Structures
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    • v.12 no.4
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    • pp.353-379
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    • 2012
  • The accuracy of the 30% and SRSS rules, commonly used to estimate the combined response of structures, and some related issues, are studied. For complex systems and earthquake loading, the principal components give the maximum seismic response. Both rules underestimate the axial load by about 10% and the COV of the underestimation is about 20%. Both rules overestimate the base shear by about 10%. The uncertainty in the estimation is much larger for axial load than for base shear, and, for axial load, it is much larger for inelastic than for elastic behavior. The effect of individual components may be highly correlated, not only for normal components, but also for totally uncorrelated components. The rules are not always inaccurate for large values of correlation coefficients of the individual effects, and small values of such coefficients are not always related to an accurate estimation of the response. Only for perfectly uncorrelated harmonic excitations and elastic analysis of SDOF systems, the individual effects of the components are uncorrelated and the rules accurately estimate the combined response. In the general case, the level of underestimation or overestimation depends on the degree of correlation of the components, the type of structural system, the response parameter, the location of the structural member and the level of structural deformation. The codes should be more specific regarding the application of these rules. If the percentage rule is used for MDOF systems and earthquake loading, at least a value of 45% should be used for the combination factor.

Effect of Conductive Additives in La0.8Sr0.2MnO3 Perovskite Electrodes for Oxygen Reduction and Evolution in Alkaline Solution (알칼리용액에서 La0.8Sr0.2MnO3 페롭스카이트 촉매의 산소환원 및 발생반응에서 도전재의 영향)

  • SHIM, JOONGPYO;LOPEZ, KAREEN J.;YANG, JIN-HYUN;SUN, HO-JUNG;PARK, GYUNGSE;EOM, SEUNGWOOK;LEE, HONG-KI
    • Journal of Hydrogen and New Energy
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    • v.27 no.3
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    • pp.276-282
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    • 2016
  • The effects of conductive additives in a $La_{0.8}Sr_{0.2}MnO_3$ perovskite bifunctional electrode for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were investigated in an alkaline solution. Highly porous carbon black (CB) and Ni powder were added to the bifunctional electrodes as conductive additives. The surface morphologies of electrodes containing CB and Ni were observed by scanning electron microscopy (SEM). The current densities for both ORR and OER were changed by the addition of CB. The conductive additive changed physical properties of bifunctional electrodes such as the sheet conductance, gas permeability and contact angle. It was observed that the air permeability of electrode was most effective to enhance the currents for ORR and OER.

Removal of Organic Load from Olive Washing Water by an Aerated Submerged Biofilter and Profiling of the Bacterial Community Involved in the Process

  • Pozo, Clementina;Rodelas, Belen;Martinez-Toledo, M. Victoria;Vilchez, Ramiro;Gonzalez-Lopez, Jesus
    • Journal of Microbiology and Biotechnology
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    • v.17 no.5
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    • pp.784-791
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    • 2007
  • The present work aims to use a biofilter technology(aerated submerged filters) for the aerobic transformation at laboratory-scale of olive washing water(OWW) generated in the first steps of olive oil processing, as well as the genetic profiling and identification to the species level of the bacteria involved in the formation of the biofilm, by means of TGGE. Chemical parameters, such as biological oxygen demand at five days($BOD_5$) and chemical oxygen demand(COD), decreased markedly(up to 90 and 85%, respectively) by the biological treatment, and the efficiency of the process was significantly affected by aeration and inlet flow rates. The total polyphenol content of inlet OWW was only moderately reduced(around 50% decrease of the inlet content) after the biofilter treatment, under the conditions tested. Partial 16S rRNA genes were amplified using total DNA extracted from the biofilm and separated by TGGE. Sequences of isolated bands were mostly affiliated to the $\alpha-subclass$ of Proteobacteria, and often branched in the periphery of bacteria] genera commonly present in soil(Rhizobium, Reichenowia, Agrobacterium, and Sphingomonas). The data obtained by the experimentation at laboratory scale provided results that support the suitability of the submerged filter technology for the treatment of olive washing waters with the purpose of its reutilization.

Fuzzy Linguistic Recommender Systems for the Selective Diffusion of Information in Digital Libraries

  • Porcel, Carlos;Ching-Lopez, Alberto;Bernabe-Moreno, Juan;Tejeda-Lorente, Alvaro;Herrera-Viedma, Enrique
    • Journal of Information Processing Systems
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    • v.13 no.4
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    • pp.653-667
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    • 2017
  • The significant advances in information and communication technologies are changing the process of how information is accessed. The internet is a very important source of information and it influences the development of other media. Furthermore, the growth of digital content is a big problem for academic digital libraries, so that similar tools can be applied in this scope to provide users with access to the information. Given the importance of this, we have reviewed and analyzed several proposals that improve the processes of disseminating information in these university digital libraries and that promote access to information of interest. These proposals manage to adapt a user's access to information according to his or her needs and preferences. As seen in the literature one of the techniques with the best results, is the application of recommender systems. These are tools whose objective is to evaluate and filter the vast amount of digital information that is accessible online in order to help users in their processes of accessing information. In particular, we are focused on the analysis of the fuzzy linguistic recommender systems (i.e., recommender systems that use fuzzy linguistic modeling tools to manage the user's preferences and the uncertainty of the system in a qualitative way). Thus, in this work, we analyzed some proposals based on fuzzy linguistic recommender systems to help researchers, students, and teachers access resources of interest and thus, improve and complement the services provided by academic digital libraries.

Enantiospecific separation in biphasic Membrane Reactors

  • Giorno, Lidietta
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.15-18
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    • 1998
  • Membrane reactors are systems which combine a chemical reactor with a membrane separation process allowing to carry out simultaneously conversion and product separation. The catalyst can be immobilized on the membrane or simply compartmentalized in a reaction space by the membrane. Membrane reactors are today investigated to produce optically pure isomers and/or resolve racemic mixture of enantiomers. The interest towards these systems is due to the increasing demand of enantiomerically pure compounds to be used in the pharmaceutical, food, and agrochemical industries. In fact, enantiomers can have different biological activities, which often influence the efficacy or toxicity of the compound. On the basis of current literature there are basically two schemes on the use of membrane technology to produce enantiomers. In one case, the membrane itseft is intrinsically enantioselective: the membrane is the chiral system which selectively separates the wanted isomer on the basis of its conformation. In the other, a kinetic resolution using an enantiospecific biocatalyst is combined with a membrane separation process; the membrane separates the product from the substrate on the basis of their relative chemical properties (i.e. solubility). This kind of configuration is widely used to carry out kinetic resolutions of low water soluble substrams in biphasic membrane reactors [Giomo, 1995, 1997; Lopez, 1997]. These are systems where enzyme-loaded membranes promote reactions between two separate phases thanks to the properties of enzymes, such as lipases, to catalyse reactions at the org ic/aqueous interface; the two phases are maintained in contact and separated at the membrane level by operating at appropriate transmembrane pressure. A schematic representation of biphasic membrane reactor is shown in figure 1, while an example of enantiospecific reaction and product separation carried out with these systems is reported in figure 2.

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Combination rules and critical seismic response of steel buildings modeled as complex MDOF systems

  • Reyes-Salazar, Alfredo;Valenzuela-Beltran, Federico;de Leon-Escobedo, David;Bojorquez-Mora, Eden;Barraza, Arturo Lopez
    • Earthquakes and Structures
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    • v.10 no.1
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    • pp.211-238
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    • 2016
  • The Maximum seismic responses of steel buildings with perimeter moment resisting frames (MRF), modeled as complex MDOF systems, are estimated for several incidence angles of the horizontal components and the critical one is identified. The accuracy of the existing rules to combine the effects of the individual components is also studied. Two and three components are considered. The critical response does not occur for principal components and the corresponding incidence angle varies from one earthquake to another. The critical response can be estimated as 1.40 and 1.10 times that of the principal components, for axial load and interstory shears, respectively. The rules underestimate the axial load but reasonably overestimate the shears. The rules are not always inaccurate in the estimation of the combined response for correlated components. On the other hand, totally uncorrelated (principal) components are not always related to an accurate estimation. The correlation of the individual effects (${\rho}$) may be significant, even for principal components. The rules are not always associated to an inaccurate estimation for large values of ${\rho}$, and small values of ${\rho}$ are not always related to an accurate estimation. Only for perfectly uncorrelated harmonic excitations and elastic analysis of SDOF systems, the individual effects of the components are uncorrelated and the rules accurately estimate the combined response. The degree of correlation of the components, the type of structural system, the response parameter under consideration, the location of the structural member and the level of structural deformation must be considered while estimating the level of underestimation or overestimation.

Evaluation of 475 ℃ embrittlement in UNS S32750 super duplex stainless steel using four-point electric conductivity measurements

  • Gutierrez-Vargas, Gildardo;Ruiz, Alberto;Lopez-Morelos, Victor H.;Kim, Jin-Yeon;Gonzalez-Sanchez, Jorge;Medina-Flores, Ariosto
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2982-2989
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    • 2021
  • One of the consequences of the 475 ℃ embrittlement of duplex stainless steels is the reduction of the resistance to localized corrosion. Therefore, the detection of this type of embrittlement before the material exhibits significant loss in toughness, and corrosion resistance is important to ensure the structural integrity of critical components under corrosion threats. In this research, conductivity measurements are performed using the alternating current potential drop (ACPD) technique with using a portable four-point probe as a nondestructive evaluation (NDE) method for detecting the embrittlement in a 2507 (UNS S32750) super duplex stainless steel (SDSS) aged at 475 ℃ from as-received condition to 300 h. The electric conductivity results were compared against two electrochemical tests namely double loop electrochemical potentiokinetic reactivation (DL-EPR) and critical pitting temperature (CPT). Mechanical tests and the microstructure characterized using scanning electron microscopy (SEM) imaging are conducted to track the progress of embrittlement. It is shown that the electric conductivity correlates with the changes in impact energy, microhardness, and CPT corrosion tests result demonstrating the feasibility of the four-point probe as a possible field-deployable method for evaluating the 475 ℃ embrittlement of 2507 SDSS.