• Title/Summary/Keyword: Local corrosion

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A REVIEW OF CANDU FEEDER WALL THINNING

  • Chung, Han-Sub
    • Nuclear Engineering and Technology
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    • v.42 no.5
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    • pp.568-575
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    • 2010
  • Flow Accelerated Corrosion is an active degradation mechanism of CANDU feeder. The tight bend downstream to Gray loc weld connection, close to reactor face, suffers significant wall thinning by FAC. Extensive in-service inspection of feeder wall thinning is very difficult because of the intense radiation field, complex geometry, and space restrictions. Development of a knowledge-based inspection program is important in order to guarantee that adequate wall thickness is maintained throughout the whole life of feeder. Research results and plant experiences are reviewed, and the plant inspection databases from Wolsong Units One to Four are analyzed in order to support developing such a knowledge-based inspection program. The initial thickness before wall thinning is highly non-uniform because of bending during manufacturing stage, and the thinning rate is non-uniform because of the mass transfer coefficient distributed non-uniformly depending on local hydraulics. It is obvious that the knowledge-based feeder inspection program should focus on both fastest thinning locations and thinnest locations. The feeder wall thinning rate is found to be correlated proportionately with QV of each channel. A statistical model is proposed to assess the remaining life of each feeder using the QV correlation and the measured thicknesses. W-1 feeder suffered significant thinning so that the shortest remaining life barely exceeded one year at the end of operation before replacement. W-2 feeder showed far slower thinning than W-1 feeder despite the faster coolant flow. It is believed that slower thinning in W-2 is because of higher chromium content in the carbon steel feeder material. The average Cr content of W-2 feeder is 0.051%, while that value is 0.02% for W-1 feeder. It is to be noted that FAC is reduced substantially even though the Cr content of W-2 feeder is still very low.

Fundamentals and Applications of Multi-functional NSOM Technology to Characterization of Nano Structured Materials (다기능 NSOM (mf-NSOM) 을 이용한 나노 구조 재료 분석에 관한 원리와 응용)

  • Lee Woo-Jin;Pyun Su-Il;Smyrl W. H.
    • Journal of the Korean Electrochemical Society
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    • v.7 no.2
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    • pp.108-123
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    • 2004
  • Imaging of surfaces and structures by near-field scanning optical microscopy (NSOM) has matured and is routinely used for studies ranging from biology to materials science. Of interest in this review paper is a versatility of modified or multi-functional NSOM (mf-NSOM) to enable high resolution imaging in several modes: (1) Concurrent fluorescence and Topographical Imaging (gases) (2) Microspectroscopy (gases) (3) Concurrent Scanning Electrochemical and Topographical Imaging (SECM) (liquids) (4) Concurrent Photoelectrochemical and Topographical Imaging (PEM) (liquids) The present study will summarize some of the recent advances in mf-NSOM work confirmed and supported by the results from several other imaging techniques of optical, fluorescence, electron and electrochemical microscopy. The studies are directed at providing local information on pitting precursor sites and vulnerable areas on metal and semiconductor surfaces, and at reactive sites on heterogeneous, catalytic substrates, especially on Al 2024 alloy and polycrystalline Ti. In addition, we will introduce some results related to the laser-induced nanometal (Ag) synthesis using mf-NSOM.

Effectiveness study of a cement mortar coating based on dune sand on the carbonation of concrete

  • Korichi, Youssef;Merah, Ahmed;Khenfer, Med Mouldi;Krobba, Benharzallah
    • Advances in concrete construction
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    • v.13 no.4
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    • pp.315-325
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    • 2022
  • Reinforced concrete structures are exposed throughout their lifetime to the phenomenon of carbonation, which considerably influences their durability by causing corrosion of the reinforcements. The fight against this phenomenon is usually ensured by anti-carbonation coatings which have the possibility of limiting the permeability to carbon dioxide or with coatings which absorb the CO2 present in the air. A coating with good crack-bridging (sealing) capacity will prevent water from entering through existing cracks in concrete. Despite the beneficial effect of these coatings, their durability decreases considerably over time with temperature and humidity. In order to use coatings made from local materials, not presenting any danger, available in abundance in our country, very economical and easy to operate is the main objective of this work. This paper aim is to contribute to the formulation of a corrected dune sand-based mortar as an anti-carbonation coating for concrete. The results obtained show that the cement mortar based on dune sand formulated has a very satisfactory compressive strength, a very low water porosity compared to ordinary cement mortar and that this mortar allows an improvement in the protection of the concrete against the carbonation of 60% compared to ordinary cement mortar based on alluvial sand. Moreover, the formulated cement mortars based on dune sand have good adhesion to the concrete support, their adhesion strengths are greater than 1.5MPa recommended by the standards.

Technical Application and Analysis for Reduction of Water Loss in Water Distribution Systems (상수도 관망의 유수율 제고 기술의 적용 및 분석)

  • Kim, Ju-Hwan;Lee, Doo-Jin;Bae, Cheol-Ho;Woo, Hyung-Min
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.260-266
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    • 2009
  • Non-revenue water reduction(NRW) technologies are implemented to evaluate and manage leakages scientifically in water distribution systems under local governments. A development of quantitative leakage indicator by measuring minimum night flow, pressure control policy by installation of PRV(pressure reducing valve) and the establishment of leakage prevention schemes by residual life modeling of deteriorated water pipes are reviewed and studied. Estimation models of allowable leakage are developed by measuring and analyzing minimum night flow at residential and commercial area in Nonsan city, which is suggested from UK water industry and can improve an existing leakage indicator for the evaluation of non-revenue water. Also, pressure control method is applied and analyzed to Uti distribution area in Sacheon city in the operation aspect. As results, $466\;m^3/day$ of leakage can be reduced and it is expected that 113million won of annual cost can be saved. In the part of corrosion velocity and residual life assessment, non-linear prediction models of residual thickness are proposed by assessment of corrosion velocity based on exposure years, soil and water quality etc., since the deteriorated water pipe play a major role to increase leakage. It is expected that collection data and analyzing results can be applied effectively and positively to reduce non-revenue water by accumulating surveying data and verifying the results in the business field of water distribution systems under local governments.

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An Analytical Study on the Buckling of Orthotropic Plates and Local Buckling of Compression Members (직교이방성 판의 좌굴 및 압축재의 국부좌굴에 대한 해석적 연구)

  • Choi, Jin-Woo;Lee, Kang-Yeon;Park, Jung-Hwan;Yoon, Soon-Jong
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.3 no.1
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    • pp.21-28
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    • 2012
  • In this paper, we present the analytical study results pertaining to the buckling of the orthotropic plates and local buckling of structural compression members composed of orthotropic plate components. Fiber reinforced polymeric plastic (FRP) materials, have many advantages over conventional structural materials such as steel and concrete. The advantages of the FRP materials are high specific strength and stiffness, high corrosion resistance, right weight, etc. Among the various manufacturing methods, pultrusion process is one of the best choices for the mass production of structural plastic members. Since the major reinforcing fibers are placed along the axial direction of the member, this material is usually considered as an orthotropic (tranversely isotropic, more specifically) material. However, pultruded fiber reinforced plastic structural members have low modulus of elasticity and are composed of orthotropic thin plate components the members are prone to buckle. Therefore, stability is an important issue in the design of the pultruded FRP structural members. In this paper, the buckling of orthotropic plates and the local buckling of pultruded FRP structural members are investigated by following the previous research results and the local buckling strength of the member produced in the domestic manufacturer is found.

A Study on Chloride Threshold Level of Polymer Inhibitive Coating Containing Calcium Hydroxide (수산화칼슘을 혼입한 폴리머 방청 코팅의 부식 임계치 향상에 대한 연구)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.713-719
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    • 2008
  • Various types of coatings have been developed for use as reinforcement in concrete and to resist chloride environment. The most commonly used coatings are inhibited and sealed cement slurry coating, cement polymer compositing coating and epoxy coating. Cement slurry offers passive protection, epoxy coating offers barrier protection whereas polymer coating offers both passive protection and barrier protection. Moreover, damage during handling of the steel may result in disbondment of the epoxy coating, which would increase the risk of localized corrosion. In the present study, inhibiting technique was used to increase the calcium hydroxide content at the interface up to 20%. Calcium hydroxide provides a high buffering capacity that resists a local fall in pH and thus maintains the alkaline environment necessary to prevent chloride corrosion. This study examines the use of a calcium hydroxide coating on the steel surface to enhance the pH buffering capacity of steel-concrete interface. Finally, the chloride threshold level (CTL) of polymer inhibitive coating calcium hydroxide is evaluated.

An Application of Solenoid Eddy Current Sensor for Nondestructively Inspecting Deterioration of Overhead Transmission Lines due to Forest Fires (산불에 의한 가공송전선의 열화특성을 비파괴적으로 검출하기 위한 솔레노이드 와류센서의 응용)

  • Kim, Sung-Duck;Kim, Young-Dal;Jeong, Dong-Hwa
    • Journal of Sensor Science and Technology
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    • v.9 no.6
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    • pp.404-415
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    • 2000
  • This paper describes several performances and nondestructive inspection for deterioration due to forest fires in overhead transmission lines. After discussing corrosion mechanism such as atmospheric and galvanic corrosion for aged ACSR conductors and its detection for them are presented. Through impedance analysis of a solenoid coil, it is shown that the eddy current sensor may be available to inspect severe fault or local corrosion. As the solenoid coil changes its impedance when the test conductor is inserted into the coil, it can be possible to measure deterioration degree caused by forest fires. Tensile strength, extension rate and sensor impedance are tested for some samples degraded by artificial fire. As increasing blazed period to some extent, the strength of aluminum strand begins to be reduced remarkably, while galvanized steel strand holds the similar strength to the initial value, despite of appearing a little loss of zinc layer. In general, it is shown that the sensor impedance would be increased while the tension load of conductor is reduced and the extension rate is contrarily increased. Therefore, the sensor output could exhibit the changes of mechanical performances, and would be used to detect such deterioration caused by forest fire in ACSR conductors built on the ridge of mountains. Finally, it was verified that the solenoid coil could be applicable to obtain any crucial inform for serious deterioration due to forest fires.

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Analysis of Failure Behavior of FRP Rebar Reinforced Concrete Slab based on FRP Reinforced Ratio (FRP 보강근비에 따른 FRP 보강 콘크리트 슬래브의 파괴거동 분석)

  • Jang, Nag-Seop;Kim, Young-Hwan;Oh, Hong-Seob
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.173-181
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    • 2021
  • Reinforced concrete structures are exposed to various environments, resulting in reinforcement corrosion due to moisture and ions penetration. Reinforced concrete corrosion causes a decrease in the durability performance of reinforced concrete structures. One solution to mitigate such issues is using FRP rebars, which offer several advantages such as high tensile strength, corrosion resistance, and light-weight than conventional rebars, in reinforced concrete instead of conventional steel rebars. The FRP rebar used should be examined at the limit state because FRP reinforced concrete has linear behavior until its fracture and can generate excessive deflection due to the low elastic modulus. It should be considered while designing FRP reinforced concrete for flexure. In the ultimate limit state, the flexural strength of FRP reinforced concrete as per ACI 440.1R is significantly lower than the flexural strength by applying both the environmental reduction and strength reduction factors accounting for the material uncertainty of FRP rebar. Therefore, in this study, the experimental results were compared with the deflection of the proposed effective moment of inertia referring to the local and international standards. The experimental results of GFRP and BFRP reinforced concrete were compared with the flexural strength as determined by ACI 440.1R and Fib bulletin 40. The flexural strength obtained by the experimental results was more similar to that obtained by Fib bulletin 40 than ACI 440.1R. The flexural strength of ACI 440.1R was conservatively evaluated in the tension-controlled section.

A study on the condition assessment of large diameter water valves using non-destructive technologies (비파괴 기술을 이용한 대구경 수도용 밸브의 상태평가에 관한 연구)

  • Ho-Min Lee;Hyun-yong Choi;Suwan Park;Tae-min Oh;Chae-Min Kim;Cheol-Ho Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.37 no.4
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    • pp.215-229
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    • 2023
  • In this study, non-destructive technologies that can be applied to evaluate the integrity of valve materials, safety against internal pressure caused by corrosion, and the blocking function of large-diameter water valves during operation without requiring specimen collection or manpower entering the inside of the valve were tested to assess the reliability of the technologies and their suitability for field application. The results showed that the condition of the graphite structure inside the valve body can be evaluated directly through the optical microscope in the field without specimen collection for large-diameter water butterfly valves, and the depth of corrosion inside the valve body can be determined by array ultrasound and the tensile strength can be measured by instrumented indentation test. The reliability of each of these non-destructive techniques is high, and they can be widely used to evaluate the condition of steel or cast iron pipes that are significantly smaller in thickness than valves. Evaluation of blocking function of the valves with mixed gas showed that it can be detected even when a very low flow rate of mixed gas passes through the disk along with the water flow. Finally, as a result of evaluating the field applicability of non-destructive technologies for three old butterfly valves installed in the US industrial water pipeline, it was found that it is possible to check the material and determine the suitability of large-diameter water valves without taking samples, and to determine the corrosion state and mechanical strength. In addition, it was possible to evaluate safety through the measurement results, and it is judged that the evaluation of the blocking function using mixed gas will help strengthen preventive response in the event of an accident.

Local Bond Stress-Slip Model of GFRP Rebars (GFRP 보강근의 부착응력-미끄럼 모델)

  • Cheong, Yeon-Geol;Yi, Chong-Ku;Lee, Jung-Yoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.133-136
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    • 2008
  • The cost of repairing the deterioration of concrete structures due to corrosion of the reinforcement steel has been the prominent figure in the maintenacne of the reinforced-concrete infrastructures. As an alternative material to steel reinforcement, the use of Glass Fiber Reinforced Polymer (GFRP) bar in concrete is being actively studied for the high resistance of chemical environment and high strength to weight ratio properties of GFRP. However, there remain various aspects of GFRP properties that still need to be studied before the standard design criteria can be established. One of the imminent issues is the bond between GFRP and concrete. In this study, the bond-behavior of GFRP bars in concrete is investigated via the pullout test with varying parameters: surface condition of GFRP bars and concrete compression strength. And the local bond-stress model of GFRP rabars with applying monotonc load was also derived from the present test.

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