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Comparison of Carbon Dioxide Absorption in Aqueous MEA, DEA, TEA, and AMP Solutions

  • Kim, Young Eun;Lim, Jin Ah;Jeong, Soon Kwan;Yoon, Yeo Il;Bae, Shin Tae;Nam, Sung Chan
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.783-787
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    • 2013
  • The separation and capture process of carbon dioxide from power plants is garnering interest as a method to reduce greenhouse gas emissions. In this study, aqueous alkanolamine solutions were studied as absorbents for $CO_2$ capture. The solubility of $CO_2$ in aqueous alkanolamine solutions was investigated with a continuous stirred reactor at 313, 333 and 353 K. Also, the heat of absorption ($-{\Delta}H_{abs}$) between the absorbent and $CO_2$ molecules was measured with a differential reaction calorimeter (DRC) at 298 K. The solubility and heat of absorption were determined at slightly higher than atmospheric pressure. The enthalpies of $CO_2$ absorption in monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), and 2-amino-2-methyl-1-propanol (AMP) were 88.91, 70.44, 44.72, and 63.95, respectively. This investigation showed that the heat of absorption is directly related to the quantity of heat for absorbent regeneration, and is dependent on amine type and $CO_2$ loading.

Tensile Behavior of Fiber/Particle Hybrid Metal Matrix Composites (섬유/입자 혼합금속복합재료의 인장거동)

  • 정성욱;정창규;한경섭
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.139-142
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    • 2002
  • This study presents a mathematical model predicting the stress-strain behavior of fiber reinforced (FMMCs) and fiber/particle reinforced metal matrix composites (F/P MMCs). MMCs were fabricated by squeeze casting method using Al2O3 short fiber and particle as reinforcement, and A356 aluminum alloy as matrix. The fiber/particle ratios of F/P MMCs were 2:1, 1:1, 1:2 with the total reinforcement volume fraction of 20 vol.%, and the FMMCs were reinforced with 10 vol,%, 15 vol. %, 20 vol. % of fibers. Tensile tests were conducted and compared with predictions which were derived using laminate analogy theory and multi-failure model of reinforcements. Results show that the tensile strength of FMMCs with 10 vol.% of fiber was well matched with prediction, and as the fiber volume increases, predictions become larger than experimental results. The difference between the prediction and experiment is considered to be a result of matrix allowance of fiber damage in tensile loading. As the fiber volume fraction in FMMCs increases, the fiber damage increases and so that the tensile strength is reduced. The strength of F/P MMCs approaches more closely to the prediction than FMMCs reinforced with 20 vol.% of fibers because F/P MMCs contains small quantity of fibers and thus has a positive effect in fiber strengthening.

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The Study on the Machining Characteristics of 4 inch Wafer for the Optimal Condition (최적 가공 조건을 위한 4인치 웨이퍼의 가공 특성에 관한 연구)

  • Won, Jong-Koo;Lee, Jung-Taik;Lee, Jung-Hun;Lee, Eun-Sang
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.5
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    • pp.90-95
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    • 2007
  • Single side final polishing is a very important role to stabilize a wafer finally before the device process on the wafer is executed. In this study, the machining variables, such as pressure, machining time, and the velocity of pad table were adopted. These parameters have the major influence on the characteristics of wafer polishing. We investigated the surface roughness changing these variables to find the optimal polishing condition. Pad, slurry, slurry quantity, and oscillation distance were set to the fixed variables. In order to reduce defects and find a stable machining condition, a hall sensor was used on the polishing process. AE sensor was attached to the polishing machine to verify optimal condition. Applying data analysis of the sensor signal, experiments were performed. We can get better surface roughness from loading the quasi static force and improving wafer-holding method.

A Study on Section Properties of Partially Concrete-Filled New Type Composite Beam (부분매입형 신형상 합성보의 단면성능에 관한 연구)

  • Yoon, Myung-Ho;Lee, Yoon-Hee;Lee, Ye-Seul
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.4 no.3
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    • pp.7-12
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    • 2013
  • The demand for the structural system of reduction of story height increases because buildings are getting higher. The existing structural systems are not efficiency. Thus, it is hard to reduce the story height and existing methods cannot secure economics as expected. This study aims at developing the partially concrete-filled new type composite beam, which can efficiently resist against the end negative moment and central positive moment, also reduce deflection of beams. Through case studies on loading of concentrated load and uniformly distributed load to fixed beam, we could find the most efficient ratio of moment of inertia and the ratio ${\alpha}$(end beam length to span). The gap space between middle and end beam can be used as facilities installation, consequently the suggested Omega beam system is expected to get the effect of reduction in story height as well as reduction of quantity.

Numerical Cavitation Intensity on a Hydrofoil for 3D Homogeneous Unsteady Viscous Flows

  • Leclercq, Christophe;Archer, Antoine;Fortes-Patella, Regiane;Cerru, Fabien
    • International Journal of Fluid Machinery and Systems
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    • v.10 no.3
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    • pp.254-263
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    • 2017
  • The cavitation erosion remains an industrial issue for many applications. This paper deals with the cavitation intensity, which can be described as the fluid mechanical loading leading to cavitation damage. The estimation of this quantity is a challenging problem both in terms of modeling the cavitating flow and predicting the erosion due to cavitation. For this purpose, a numerical methodology was proposed to estimate cavitation intensity from 3D unsteady cavitating flow simulations. CFD calculations were carried out using Code_Saturne, which enables U-RANS equations resolution for a homogeneous fluid mixture using the Merkle's model, coupled to a $k-{\varepsilon}$ turbulence model with the Reboud's correction. A post-process cavitation intensity prediction model was developed based on pressure and void fraction derivatives. This model is applied on a flow around a hydrofoil using different physical (inlet velocities) and numerical (meshes and time steps) parameters. The article presents the cavitation intensity model as well as the comparison of this model with experimental results. The numerical predictions of cavitation damage are in good agreement with experimental results obtained by pitting test.

Determination of Event Mean Concentrations and Pollutant Loadings in Highway Storm Runoff (고속도로 강우 유출수내 오염물질의 EMC 및 부하량 원단위 산정)

  • Kim, Lee-Hyung;Kang, Joohyon
    • Journal of Korean Society on Water Environment
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    • v.20 no.6
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    • pp.631-640
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    • 2004
  • This research was conducted to understand the magnitude and nature of the stormwater emissions with the goal of quantifying stormwater pollutant concentrations and mass emission rates of pollutants. Eight highway sites in Southern California area were monitored for three years with collecting of grab and flow-weighted composite samples, rainfall and runoff flow. Generally the EMCs cannot be determined by simple statistical averaging of measured pollutant concentrations because of random characteristics of runoff quality and quantity. Therefore, this manuscripts will show a new EMC determination method. The EMC ranges of 95% confidence intervals are 102.78-216.37mg/L for TSS, 104.53-251.79mg/L for COD, 5.42-10.58mg/L for oil & grease and 2.42-10.18mg/L for TKN. The ranges of washed-off mass loading are determined to $0.06g/m^2-17.27g/m^2$ for TSS and $0.1-3.23g/m^2$for COD.

New Hollow RC Bridge Piers with Triangular Reinforcement Details (삼각망 철근상세를 갖는 새로운 중공 철근콘크리트 교각)

  • Kim, Tae-Hoon;Kim, Ho-Young;Lee, Jae-Hoon;Shin, Hyun-Mock
    • Journal of the Earthquake Engineering Society of Korea
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    • v.20 no.1
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    • pp.21-31
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    • 2016
  • This study investigates the seismic performance of new hollow reinforced concrete (RC) bridge piers with triangular reinforcement details. The developed triangular reinforcement details are economically feasible and rational, and facilitate shorter construction periods. We tested a model of new hollow RC bridge piers with triangular reinforcement details under a constant axial load and a quasi-static, cyclically reversed horizontal load. We used a computer program, Reinforced Concrete Analysis in Higher Evaluation System Technology (RCAHEST), for analysis of RC structures. The used numerical method gives a realistic prediction of seismic performance throughout the loading cycles for several hollow pier specimens investigated. As a result, developed triangular reinforcement details for material quantity reduction was equal to existing reinforcement details in terms of required performance.

Development of Design Method of Disconnected Piled Raft Foundation System (기초분리말뚝 공법의 설계기법 개발)

  • Choi, Jung-In;Min, Ki-Hoon;Kim, Sung-Ho;Kwon, Oh-Sung;Kim, Myoung-Mo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.691-699
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    • 2008
  • In the design of a foundation, settlement of the foundation may exceed allowable design criteria even with a competent bearing stratum. In such a case, a piled-raft foundation system may be adopted using piles as settlement reducing component. In this paper, Disconnected Piled Raft Foundation (DPRF) system, which installs disconnected piles underneath the raft and uses the piles as ground reinforcements, is studied as a cost effective design method against the classical piled-raft foundation system. To this end, large size loading tests were carried out on weathered ground changing area replacement ratio and length of piles. The results indicated that the settlement of the reinforced ground was reduced by 34~87% and the allowable bearing pressure increased by 70% on average from those of the unreinforced original ground, respectively. The correlating formula between the area replacement ratio and the load bearing ratio of piles were derived from the test results and numerical analysis. From the correlation, a design method determining the size and the quantity of the disconnected piles to enhance the bearing capacity of original ground to the desired value was proposed based on one inch settlement criteria.

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Application of Precious Slag Ball for horizontal drain material by field experimental test (현장시험을 통한 수평배수재로서의 풍쇄 슬래그의 적용성에 관한 연구)

  • Shin, Eun-Chul;Lee, Woon-Hyun;Kim, Soo-Wan;Yoo, Jeong-Hoon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.449-456
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    • 2009
  • As soft grounds have complex engineering properties that the load bearing capacity is low and high compressibility, it needs to solve this problems prior to structures are constructed by the method of improvement of soft ground. Generally, the sand mat is used to as a horizontal drain material and loading base for soft ground improvement work. However, as the natural environment can be damaged by sand pickings of large quantity and the volume which is enormous and an amount of demanded sand is increased, it is state of short in supply. This paper presents the result of field experimental test to use Precious Slag Ball to solve these issues instead of sand mat as the replacing material. This study evaluated the performance of Precious Slag Ball as a sand mat in terms of discharge capacity, settlement, and settlement through the K-Embank program.

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Adsorption of Carbon Dioxide onto Tetraethylenepentamine Impregnated PMMA Sorbents with Different Pore Structure

  • Jo, Dong Hyun;Park, Cheonggi;Jung, Hyunchul;Kim, Sung Hyun
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.382-390
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    • 2015
  • Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.