• 전기화학회지
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• 제13권4호
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• pp.290-294
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• 2010

본 연구는 밀도 범함수 이론을 이용하여 Li이온전지에 사용되는 Li코발트 산화물에서의 Li이온 삽입 전압과 전도에 관한 것이다. Li이온은 Li코발트 산화물 원자구조의 각 층을 1개씩 채우거나 한 층을 다 채우고 다음 층을 채울 수 있다. 평균 삽입 전압은 3.48V로 동일하나, 전자가 후자보다 더 유리하였다. 격자상수 c는 Li농도가 0.25보다 작을 때는 증가하였으나, 0.25보다 클 때는 감소하였다. Li농도가 증가하면, Li코발트 산화물에서의 Li이온 전도를 위한 에너지 장벽은 증가하였다. Li이온전지가 방전 중 출력 전압이 낮아지는 현상은 Li농도 증가에 따른 삽입 전압의 감소와 전도 에너지 장벽의 증가로 설명할 수 있었다.

• Journal of Electrical Engineering and Technology
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• 제13권6호
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• pp.2561-2567
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• 2018

The extension of DC battery backup time in the DC power supply system of nuclear power plants (NPPs) remains a challenge. The lead-acid battery is the most popular at present. And it is generally the most popular energy storage device. However, extension of backup time requires too much space. The lithium-ion battery has high energy density and advanced gravimetric and volumetric properties. The aim of this paper is development of the sizing formula of stationary lithium-ion batteries. The ongoing research activities and related industrial standards for stationary lithium-ion batteries are reviewed. Then, the lithium-ion battery sizing calculation formular is proposed for the establishment of industrial design standard which is essential for the design of stationary batteries of nuclear power plants. An example of calculating the lithium-ion battery capacity for a medium voltage UPS is presented.

• 한국항공우주학회지
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• 제42권4호
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• pp.351-359
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• 2014

본 논문에서는 저궤도 소형인공위성에서 위성의 각 부에 전원을 공급하기 위한 리튬이온 배터리 시스템의 신뢰성 확보를 위해 수행한 우주인증시험들의 결과를 나타내었다. 리튬이온 배터리 시스템의 신뢰성을 검증하기 위하여 구조해적, 성능시험, 우주 및 발사환경에서의 환경시험 등을 수행하였다. 모든 해석 및 시험 결과가 요구조건에 만족함을 보임으로써 리튬이온 배터리를 적용한 소형인공위성의 신뢰성을 검증하고 제고할 수 있었다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.252-256
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• 2001

The rapid development of communication equipment and information processing technology has led to a constant improvement in cordless communication. Lithium ion batteries used in cellular phones and laptop computers, in particular, have been in the forefront of the above revolution. These batteries use high value added raw materials and have a high and stable energy output and are increasingly coming into common use. The development of the material for the negative terminal has led to an improvement in the quality and efficiency of the batteries, whereas a reduction in the cost of the battery by researching new materials for the positive anode has become a research theme by itself. These long life batteries, it is being increasingly realized, can have value added to them by recycling. Research is increasingly being done on recycling the aluminum case and the load casing for the negative diode. This paper aims to introduce the current situation of recycling of lithium ion batteries. 1. Introduction 2. Various types of batteries and the situation of their recycling and the facts regarding recycling. 3. Example of cobalt recycling from waste Lithium ion secondary cell. 3-1) Flow Chart of Lithium ion battery recycling 3-2) Materials that make a lithium ion secondary cell. 3-3) Coarse grinding of Lithium ion secondary cell, and stabilization of current discharge 3-4) Burning 3-5) Grinding 3-6) Magnetic Separation 3-7) Dry sieving 3-8) Dry Classifying 3-9) Content Ratio of recycled cobalt parts 3-10) Summary of the Line used for the recovery of Cobalt from waste Lithium ion battery. 4. Conclusion.

• Safety and Health at Work
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• 제15권1호
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• pp.114-117
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• 2024

A lithium-ion battery is a rechargeable battery that uses the reversible reduction of lithium ions to store energy and is the predominant battery type in many industrial and consumer electronics. The lithium-ion batteries are essential to ensure they operate safely. We conducted an exposure assessment five days after a fire in a battery-testing facility. We assessed some of the potentially hazardous materials after a lithium-ion battery fire.We sampled total suspended particles, hydrogen fluoride, and lithium with real-time monitoring of particulate matter (PM) 1, 2.5, and 10 micrometers (㎛). The area sampling results indicated that primary potential hazardous materials such as dust, hydrogen fluoride, and lithium were below the recommended limits suggested by the Korean Ministry of Labor and the American Conference of Governmental Industrial Hygienists Threshold Limit Values. Based on our assessment, workers were allowed to return to work.

• 전력전자학회논문지
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• 제26권6호
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• pp.421-428
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• 2021

Lithium-ion secondary batteries exhibit advantageous characteristics such as high voltage, high energy density, and long life, allowing them to be widely used in both military and daily life. However, the lithium-ion secondary battery does have its limitation; for example, the output power and capacity are readily decreased due to the increased internal impedance during discharging at a lower temperature (-32℃, military requirement). Also, during charging at a lower temperature, lithium dendrite growth is accelerated at the anode, thereby decreasing the battery capacity and life as well. This paper describes a study that involves increasing the internal temperature of lithium-ion secondary battery by energy circulation operation in a low-temperature environment. The energy circulation operation allows the lithium-ion secondary battery to alternately charge and discharge, while the internal resistance of lithium-ion battery acts as a heating element to raise its own temperature. Therefore, the energy circulation operation method and device were newly designed based on the electrochemical impedance spectroscopy of the lithium-ion secondary battery to mediate the battery performance at a lower temperature. Through the energy circulation operation of lithium ion secondary battery, as a result of the heat generated from internal resistance in an extremely low-temperature environment, the temperature of the lithium-ion secondary battery increased by more than 20℃ within 10 minutes and showed a 75% discharging capacity compared with that at room temperature.

• 한국기계가공학회지
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• 제8권2호
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• pp.90-95
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• 2009

This paper presents a new lithium ion unit-cell and pack battery by using a new formulation ratio of material. The three types of formulation ratio for the unit-cell were used. The life cycle and basic properties of the lithium ion unit-cell$({\Psi}18{\times}65(mm))$ about one of them were acquired by the charge-discharge experiment. The nominal voltage, nominal capacity and cycle life output of the lithium ion unit-cell is respectively 3.7V, 2.4Ah, and above 500cycle. Pack type lithium ion battery has the size of $29.5{\times}73.5{\times}115(mm)$ and the weight of 300g. As the results, the weight and bulk of lithium ion battery used to a safety lamp were decreased to 1/4 and 1/7. In addition, the comparison of the new lithium ion battery and lead storge battery for confirming the effectiveness of the new lithium ion battery have been performed.

• Bulletin of the Korean Chemical Society
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• 제22권5호
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• pp.503-506
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• 2001

Separation of lithium isotopes was investigated by chemical ion exchange with a hydrous manganese(IV) oxide ion exchanger using an elution chromatography. The capacity of manganese(IV) oxide ion exchanger was 0.5 meq/g. One molar CH3COO Na solution was used as an eluent. The heavier isotope of lithium was enriched in the solution phase, while the lighter isotope was enriched in the ion exchanger phase. The separation factor was calculated according to the method of Glueckauf from the elution curve and isotopic assays. The single stage separation factor of lithium isotope pair fractionation was 1.021.

• 한국세라믹학회지
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• 제39권1호
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• pp.1-11
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• 2002

A bibliographical review of inorganic lithium ion conductors is presented with a focus on those potential candidates for lithium battery application. A wide variety of inorganic lithium ion conductors, both crystalline ceramics and non-crystalline glasses, are considered.

• 대한조선학회논문집
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• 제58권4호
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• pp.225-233
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• 2021

Conventional submarine propulsion batteries have mainly used lead acid batteries, which have proved relatively safe, but in recent years, research on mounting lithium-ion batteries to improve the underwater operation capability of submarines is underway in advanced countries such as Japan. Korea has world-class technology in the development of electric vehicles and lithium-ion batteries for energy storage, but fire safety accidents continue to occur in electric vehicles and energy storage lithium-ion batteries. In order to mount the lithium-ion battery in a submarine, it is necessary to check the safety as well as whether the performance is improved compared to the lead acid battery. Through the charge/discharge experiment of this lithium-ion battery module unit, it was possible to measure how much performance was improved compared to the lead acid battery. Safety tests were conducted on the lithium-ion battery module assuming that it was mounted on a submarine, and it was confirmed that safety was secured when applied to a submarine. Since many modules are mounted on actual submarines, it has been confirmed that it can be applied to submarine systems by simulating charge/discharge characteristics through Hardware-in-the Loop(HILS). Through the results of this study, the application of lithium-ion batteries to submarines is expected to significantly improve the sustainability of underwater operations.