• Journal of the Korean Electrochemical Society
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• v.13 no.4
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• pp.290-294
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• 2010

We performed a density functional theory study to investigate the intercalation voltage and lithium ion conduction in lithium cobalt oxide for lithium ion battery as a function of the lithium concentration. There were two methods for the intercalation of lithium ions; the intercalation of a lithium ion at a time in the individual layer and the intercalation of lithium ions in all the sites of one layer after all the sites of another layer. The average intercalation voltage was the same value, 3.48 V. However, we found the former method was more favorable than the latter method. The lattice parameter c was increased as the increase of the lithium concentration in the range of x < 0.25 while it was decreased as increase of the lithium concentration in the range of x > 0.25. The energy barrier for the conduction of lithium ion in lithium cobalt oxide was increased as the lithium concentration was increased. We demonstrated that the decrease of the intercalation voltage and increase of the energy barrier as the increase of the lithium concentration caused lower output voltage during the discharge of the lithium ion battery.

• Journal of Electrical Engineering and Technology
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• v.13 no.6
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• pp.2561-2567
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• 2018

The extension of DC battery backup time in the DC power supply system of nuclear power plants (NPPs) remains a challenge. The lead-acid battery is the most popular at present. And it is generally the most popular energy storage device. However, extension of backup time requires too much space. The lithium-ion battery has high energy density and advanced gravimetric and volumetric properties. The aim of this paper is development of the sizing formula of stationary lithium-ion batteries. The ongoing research activities and related industrial standards for stationary lithium-ion batteries are reviewed. Then, the lithium-ion battery sizing calculation formular is proposed for the establishment of industrial design standard which is essential for the design of stationary batteries of nuclear power plants. An example of calculating the lithium-ion battery capacity for a medium voltage UPS is presented.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.4
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• pp.351-359
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• 2014

This paper introduces the lithium ion battery system for LEO(Low Earth Orbit) small satellites. This study proves the reliability of lithium ion batteries applying to the space application. The specifications for lithium ion battery unit are proposed to supply power to the satellite and the overall mechanical design including structural simulation to confirm the reliability of the lithium ion BMS(Battery Management System) under the space environment and launching conditions. The results of structural simulation, functional tests, and space environmental tests show the lithium ion battery system is space qualified. Space qualification of the small satellite battery system to secure reliability of BMS and lithium ion batteries lend credibility for using lithium ion batteries in space application.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.252-256
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• 2001

The rapid development of communication equipment and information processing technology has led to a constant improvement in cordless communication. Lithium ion batteries used in cellular phones and laptop computers, in particular, have been in the forefront of the above revolution. These batteries use high value added raw materials and have a high and stable energy output and are increasingly coming into common use. The development of the material for the negative terminal has led to an improvement in the quality and efficiency of the batteries, whereas a reduction in the cost of the battery by researching new materials for the positive anode has become a research theme by itself. These long life batteries, it is being increasingly realized, can have value added to them by recycling. Research is increasingly being done on recycling the aluminum case and the load casing for the negative diode. This paper aims to introduce the current situation of recycling of lithium ion batteries. 1. Introduction 2. Various types of batteries and the situation of their recycling and the facts regarding recycling. 3. Example of cobalt recycling from waste Lithium ion secondary cell. 3-1) Flow Chart of Lithium ion battery recycling 3-2) Materials that make a lithium ion secondary cell. 3-3) Coarse grinding of Lithium ion secondary cell, and stabilization of current discharge 3-4) Burning 3-5) Grinding 3-6) Magnetic Separation 3-7) Dry sieving 3-8) Dry Classifying 3-9) Content Ratio of recycled cobalt parts 3-10) Summary of the Line used for the recovery of Cobalt from waste Lithium ion battery. 4. Conclusion.

• Safety and Health at Work
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• v.15 no.1
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• pp.114-117
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• 2024

A lithium-ion battery is a rechargeable battery that uses the reversible reduction of lithium ions to store energy and is the predominant battery type in many industrial and consumer electronics. The lithium-ion batteries are essential to ensure they operate safely. We conducted an exposure assessment five days after a fire in a battery-testing facility. We assessed some of the potentially hazardous materials after a lithium-ion battery fire.We sampled total suspended particles, hydrogen fluoride, and lithium with real-time monitoring of particulate matter (PM) 1, 2.5, and 10 micrometers (㎛). The area sampling results indicated that primary potential hazardous materials such as dust, hydrogen fluoride, and lithium were below the recommended limits suggested by the Korean Ministry of Labor and the American Conference of Governmental Industrial Hygienists Threshold Limit Values. Based on our assessment, workers were allowed to return to work.

• The Transactions of the Korean Institute of Power Electronics
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• v.26 no.6
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• pp.421-428
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• 2021

Lithium-ion secondary batteries exhibit advantageous characteristics such as high voltage, high energy density, and long life, allowing them to be widely used in both military and daily life. However, the lithium-ion secondary battery does have its limitation; for example, the output power and capacity are readily decreased due to the increased internal impedance during discharging at a lower temperature (-32℃, military requirement). Also, during charging at a lower temperature, lithium dendrite growth is accelerated at the anode, thereby decreasing the battery capacity and life as well. This paper describes a study that involves increasing the internal temperature of lithium-ion secondary battery by energy circulation operation in a low-temperature environment. The energy circulation operation allows the lithium-ion secondary battery to alternately charge and discharge, while the internal resistance of lithium-ion battery acts as a heating element to raise its own temperature. Therefore, the energy circulation operation method and device were newly designed based on the electrochemical impedance spectroscopy of the lithium-ion secondary battery to mediate the battery performance at a lower temperature. Through the energy circulation operation of lithium ion secondary battery, as a result of the heat generated from internal resistance in an extremely low-temperature environment, the temperature of the lithium-ion secondary battery increased by more than 20℃ within 10 minutes and showed a 75% discharging capacity compared with that at room temperature.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.8 no.2
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• pp.90-95
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• 2009

This paper presents a new lithium ion unit-cell and pack battery by using a new formulation ratio of material. The three types of formulation ratio for the unit-cell were used. The life cycle and basic properties of the lithium ion unit-cell$({\Psi}18{\times}65(mm))$ about one of them were acquired by the charge-discharge experiment. The nominal voltage, nominal capacity and cycle life output of the lithium ion unit-cell is respectively 3.7V, 2.4Ah, and above 500cycle. Pack type lithium ion battery has the size of $29.5{\times}73.5{\times}115(mm)$ and the weight of 300g. As the results, the weight and bulk of lithium ion battery used to a safety lamp were decreased to 1/4 and 1/7. In addition, the comparison of the new lithium ion battery and lead storge battery for confirming the effectiveness of the new lithium ion battery have been performed.

• Bulletin of the Korean Chemical Society
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• v.22 no.5
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• pp.503-506
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• 2001

Separation of lithium isotopes was investigated by chemical ion exchange with a hydrous manganese(IV) oxide ion exchanger using an elution chromatography. The capacity of manganese(IV) oxide ion exchanger was 0.5 meq/g. One molar CH3COO Na solution was used as an eluent. The heavier isotope of lithium was enriched in the solution phase, while the lighter isotope was enriched in the ion exchanger phase. The separation factor was calculated according to the method of Glueckauf from the elution curve and isotopic assays. The single stage separation factor of lithium isotope pair fractionation was 1.021.

• Journal of the Korean Ceramic Society
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• v.39 no.1
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• pp.1-11
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• 2002

A bibliographical review of inorganic lithium ion conductors is presented with a focus on those potential candidates for lithium battery application. A wide variety of inorganic lithium ion conductors, both crystalline ceramics and non-crystalline glasses, are considered.

• Journal of the Society of Naval Architects of Korea
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• v.58 no.4
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• pp.225-233
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• 2021

Conventional submarine propulsion batteries have mainly used lead acid batteries, which have proved relatively safe, but in recent years, research on mounting lithium-ion batteries to improve the underwater operation capability of submarines is underway in advanced countries such as Japan. Korea has world-class technology in the development of electric vehicles and lithium-ion batteries for energy storage, but fire safety accidents continue to occur in electric vehicles and energy storage lithium-ion batteries. In order to mount the lithium-ion battery in a submarine, it is necessary to check the safety as well as whether the performance is improved compared to the lead acid battery. Through the charge/discharge experiment of this lithium-ion battery module unit, it was possible to measure how much performance was improved compared to the lead acid battery. Safety tests were conducted on the lithium-ion battery module assuming that it was mounted on a submarine, and it was confirmed that safety was secured when applied to a submarine. Since many modules are mounted on actual submarines, it has been confirmed that it can be applied to submarine systems by simulating charge/discharge characteristics through Hardware-in-the Loop(HILS). Through the results of this study, the application of lithium-ion batteries to submarines is expected to significantly improve the sustainability of underwater operations.