• Title/Summary/Keyword: Lithium rechargeable batteries

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Charge/discharge Properties of Flyash as a Anode for Lithium Polymer Battery (리튬 폴리머 전지용 Flyash 부극의 충방전 특성)

  • Song, Hee-Woong;Kim, Jong-Uk;Park, Gye-Choon;Gu, Hal-Bon
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.968-970
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    • 1999
  • The trend of increasing of portable electric devices and demand for global environmental conservation have demands the development of high energy density rechargeable batteries. Lithium polymer battery has excellent theoretical energy density and energy conversion efficiency. Lithium polymer battery, included solid polymer electrolyte(SPE), can be viewed as a system suitable for wide applications from thin film batteries for microelectronics to electric vehicle batteries. The purpose of this paper is to research and development of flyash anode for lithium polymer battery. We investigated AC impedance response and charge/discharge characteristics of flyash/SPE/Li cells. The radius of semicircle associated with the interfacial resistance of flyash/SPE/Li cell increased very slowly during discharge process from 3.11V to 0.478V. And then the cell resistance was decreased at discharge process from 10% SOC to 0% SOC. Also, The radius of semicircle associated with the interfacial resistance of flyash/SPE/Li cell decreasing very slowly during charge process. And then the cell resistance was increased after 20th discharge precess. The discharge capacity based on flyash of 1st and 20th cycles was 276mAh/g and 143mAh/g.

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CC-CV Charging Time Characteristics of Lead-Acid Batteries Based on Compact Estimation Model (간결한 예측 모형에 기반한 납축전지의 정전류-정전압 충전시간 특성화)

  • Han, Jeong-gyeon;Shin, Donghwa
    • IEMEK Journal of Embedded Systems and Applications
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    • v.11 no.5
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    • pp.305-312
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    • 2016
  • Modern embedded systems are typically operated by the rechargeable batteries in our daily life. Since charge of batteries is considered as an time consuming task, there have been extensive efforts to manage the charge time from the perspective of materials, circuits, and systems. Estimation of battery charge time is one of the essential information to design the charge circuitry. A compact macro model for the constant-current and constant-voltage charge protocol was recently introduced, which gives us a quick estimation of charge time with similar shape to the famous Peukert's law for discharge time estimation. The CC-CV charging protocol is widely used for Lithium-based batteries and Lead-acid batteries. In this paper, we characterize the lead-acid battery by measurement to extract the model coefficients, which was not covered by the previous studies. By our proposed model, the key coefficient Kcc results in 1.18-1.31, which is little bit higher than that of Lithium batteries. The accuracy of our model is within the range of ${\pm}10%$ error, which is compatible with the other studies such as Peukert's law.

Built-in protection circuit module by using VO2 temperature sensors (VO2 온도센서를 이용한 전원차단 PCM 구성)

  • Song, K.H.;Choi, J.B.;Son, M.W.;Yoo, K.S.
    • Journal of Sensor Science and Technology
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    • v.18 no.1
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    • pp.28-32
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    • 2009
  • Most portable mobile devices employ rechargeable lithium-ion batteries. This lithium-ion battery usually suffers from the possibility of explosion due to heat generation from surrounding atmosphere or internal deficiency during charging or at overuse. To solve these problems, most rechargeable batteries have a built-in protection circuit module (PCM). The resistance of a properly processed $VO_2$ critical temperature sensor (CTS) is changed dramatically at a critical temperature of around $68^{\circ}C$, which can replace some bi-metal, NTC, or PTC sensors embedded in PCM. Such $VO_2$ CTS consumes a very small current at the level of natural discharge. Experimental results showed that this CTS could be applied to a PCM as the PCM could protect the battery while keeping its power consumption at minimum.

Effects of Fe layer on Li insertion/extraction Reactions of Fe/Si Multilayer thin Film Anodes for Lithium Rechargeable Batteries

  • Kim, Tae-Yeon;Kim, Jae-Bum;Ahn, Hyo-Jun;Lee, Sung-Man
    • Journal of Electrochemical Science and Technology
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    • v.2 no.4
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    • pp.193-197
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    • 2011
  • The influences of the thickness and microstructure of Fe layer on the electrochemical performances of Fe/Si multilayer thin film anodes were investigated. The Fe/Si multilayer films were prepared by electron beam evaporation, in which Fe layer was deposited with/without simultaneous bombardment of Ar ion. The kinetics of Li insertion/extraction reactions in the early stage are slowed down with increasing the thickness of Fe layer, but such a slowdown seems to be negligible for thin Fe layers less than about $500{\AA}$. When the Fe layer was deposited with ion bombardment, even the $300{\AA}$ thick Fe layer significantly suppress Li diffusion through the Fe layer. This is attributed to the dense microstructure of Fe layer, induced by ion beam assisted deposition (IBAD). It appears that the Fe/Si multilayer films prepared with IBAD show good cyclability compared to the film deposited without IBAD.

Effective Approaches to Preventing Dendrite Growth in Lithium Metal Anodes: A Review

  • Jaeyun Ha;Jinhee Lee;Yong-Tae Kim;Jinsub Choi
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.365-382
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    • 2023
  • A lithium metal anode with high energy density has the potential to revolutionize the field of energy storage systems (ESS) and electric vehicles (EVs) that utilize rechargeable lithium-based batteries. However, the formation of lithium dendrites during cycling reduces the performance of the battery while posing a significant safety risk. In this review, we discuss various strategies for achieving dendrite-free lithium metal anodes, including electrode surface modification, the use of electrolyte additives, and the implementation of protective layers. We analyze the advantages and limitations of each strategy, and provide a critical evaluation of the current state of the art. We also highlight the challenges and opportunities for further research and development in this field. This review aims to provide a comprehensive overview of the different approaches to achieving dendrite-free lithium metal anodes, and to guide future research toward the development of safer and more efficient lithium metal anodes.

Exposure Assessment Study on Lithium-Ion Battery Fire in Explosion Test Room in Battery Testing Facility

  • Mi Sung Jo;Hoi Pin Kim;Boo Wook Kim;Richard C. Pleus;Elaine M. Faustman;Il Je Yu
    • Safety and Health at Work
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    • v.15 no.1
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    • pp.114-117
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    • 2024
  • A lithium-ion battery is a rechargeable battery that uses the reversible reduction of lithium ions to store energy and is the predominant battery type in many industrial and consumer electronics. The lithium-ion batteries are essential to ensure they operate safely. We conducted an exposure assessment five days after a fire in a battery-testing facility. We assessed some of the potentially hazardous materials after a lithium-ion battery fire.We sampled total suspended particles, hydrogen fluoride, and lithium with real-time monitoring of particulate matter (PM) 1, 2.5, and 10 micrometers (㎛). The area sampling results indicated that primary potential hazardous materials such as dust, hydrogen fluoride, and lithium were below the recommended limits suggested by the Korean Ministry of Labor and the American Conference of Governmental Industrial Hygienists Threshold Limit Values. Based on our assessment, workers were allowed to return to work.

Characteristic Analysis of Lithium-ion Battery and Lead-acid Battery using Battery Simulator (배터리 시뮬레이터를 이용한 리튬이온 배터리와 납축전지 특성분석)

  • Yongho Yoon
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.2
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    • pp.127-132
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    • 2024
  • Recently, secondary batteries, commonly known as rechargeable batteries, find widespread applications across various industries. Particularly valued for their compact and lightweight characteristics, they play a crucial role in diverse portable electronic devices such as smartphones, laptops, and tablets, offering high energy density and efficient charge-discharge capabilities. Moreover, they serve as vital components in electric vehicles and contribute significantly to the field of renewable energy as part of Energy Storage Systems(ESS). However, despite advancements in this technology, issues such as reduced lifespan, cracking, damage, and even the risk of fire can arise due to excessive charging and discharging of secondary batteries. To address these challenges, Battery Management System(BMS) are employed to protect against overcharging and improve overall performance. Nevertheless, understanding the protective range settings of BMS using lithium-ion batteries, the most commonly used secondary batteries, and lead-acid batteries can be challenging. Therefore, this paper aims to utilize a battery charge-discharge tester and simulator to investigate the charging and discharging characteristics of lithium-ion batteries and lead-acid batteries, addressing the associated challenges of reduced lifespan, cracking, damage, and fire hazards in secondary batteries.

A Mini-Review on Non-Aqueous Lithium-Oxygen Batteries - Electrochemistry and Cathode Materials

  • Riaz, Ahmer;Jung, Kyu-Nam;Lee, Jong-Won
    • Journal of Electrochemical Science and Technology
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    • v.6 no.2
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    • pp.50-58
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    • 2015
  • There is a great deal of current interest in the development of rechargeable batteries with high energy storage capability due to an increasing demand for electric vehicles (EVs) with driving ranges comparable to those of gasoline-powered vehicles. Among various types of batteries under development, a Li-O2 battery delivers the highest theoretical energy density; thus, it is considered a promising energy storage technology for EV applications. Despite the fact that extensive research efforts have been made in the field of Li-O2 batteries in recent years, there are still many technical challenges to be addressed, such as low round-trip efficiency, poor reversibility, and poor power capability. In this article, we provide a short review on the fundamental electrochemistry of Li-O2 batteries with non-aqueous electrolytes and on electrode materials that have been employed in cathodes (oxygen electrodes). The major aim of this mini-review is to highlight the physical and electrochemical origins of scientific challenges facing Li-O2 battery technology and to overview the strategies proposed to overcome them.