• Journal of Energy Engineering
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• v.20 no.1
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• pp.1-7
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• 2011

The performance and life-cycle costs of electric vehicle(EV) and hybrid electric vehicle(HEV) depend inherently on battery packs. Temperature uniformity in a pack is an important factor for obtaining optimum performance for an EV or HEV battery pack, because uneven temperature distribution in a pack leads to electrically unbalanced battery cells and reduced pack performance. In this work, a three-dimensional modeling was carried out to investigate the effects of operating conditions on the thermal behavior of a lithium-ion battery pack for an EV or HEV application. Thermal conductivities of various compartments of the battery were estimated based on the equivalent network of parallel/series thermal resistances of battery components. Heat generation rate in a cell was calculated using the modeling results of the potential and current density distributions of a battery cell.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.2
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• pp.186-193
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• 2018

Generally, it is difficult to operate moveable-weir due to the expensive cost of the facility management and manpower consumption. Also, when it is installed in a remote area, there is a problem that the cost of connection for power system increases as well as the operating cost. Therefore, this paper proposes an optimal design algorithm to replace an existing power system with an Eco-friendly power supply system for movable-weir using PCS, PV module and lithium-ion battery. Also, this paper proposes a modeling method of environment-friendly power supply system for a movable-weir based on the PSCAD/EMTDC S/W and implements 5[kW] prototype environment-friendly power supply system. As a result of the performance test using the S/W modeling and the prototype system, it is confirmed that the proposed system has stable characteristics in the independent operation mode and the interconnection mode.

• Fire Science and Engineering
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• v.34 no.1
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• pp.66-71
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• 2020

The process of discharging batteries using salt water, when used for the disposal of a lithium-ion (Li-ion) batteries, is likely to cause a fire. However, there is a dearth of studies in the literature on the risk of fire while discharging mobile phone batteries in salt water. In order to investigate the possibility of fire by elucidating the discharge characteristics and the generation of heat, we conducted experiments by varying the concentration of the salt water, number of overlapping batteries, and type of the mobile phone batteries used as experimental specimen. The discharging voltage and the temperature of the batteries were measured, and the fire risk was predicted by analyzing the data. The results of the experiment showed that the higher the salt water concentration, the greater the discharge value of the mobile phone battery and the higher the exothermic temperature. Moreover, the exothermic temperatures of the overlapping batteries were higher than that of the single battery submerged in salt water. The highest exothermic temperature points of the battery occurred at the positive and negative poles.

• Korean Journal of Microbiology
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• v.22 no.1
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• pp.57-66
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• 1984

Cells of Stigmatella aurantiace developed in the light on the medium containing calcium, barium, or lithium ion formed fruiting bodies without stalk. Fruiting body with stalk was formed on the medium containing calcium ion and GMP (GMP-medium) even under the dark condition. On the medium containing calcium and pheromone (pheromone-medium), most cells were developed only into the stalk in the light and into the sporangium in the dark. The number of aggregate formed on the medium containing calcium ion (Ca-medium) was more than that formed on the medium containing calcium, potassium, and sodium ions (CPS-medium). The number of aggregate formed on the GMP or pheromone-medium was less than that formed on the Ca-medium. Both pheromone and GMP reduced the time required for aggregate formation when cells were developed in the dark. Light stimulated cells to form more aggregates in short time when it was introduced into the Ca-, CPS-, GMP-, or pheromone-medium.

• Journal of Electrochemical Science and Technology
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• v.2 no.1
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• pp.45-50
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• 2011

A series of expanded graphites is prepared from graphite oxide by changing the heat-treatment temperature, and their lithiation/de-lithiation mechanism and rate performance are examined. A featureless sloping profile is observed in their charge-discharge voltage and dilatometry profiles, which is contrasted by the stepwise plateau-like profiles observed with the pristine graphite. With an increase in the heat-treatment temperature from $250^{\circ}C$ to $850^{\circ}C$, the interlayer distance becomes smaller whereas the electric conductivity becomes larger, both of which are resulted from a removal of foreign atoms (mainly oxygen) from the interlayer gaps. The expanded graphite that is prepared by a heat-treatment at $450^{\circ}C$ delivers the best rate performance, which seems to be a trade-off between the $Li^+$ ion diffusivity that is affected by the interlayer distance and electrical conductivity.

• Fire Science and Engineering
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• v.32 no.6
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• pp.91-99
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• 2018

Recently, the spread of ESS in Korea has increased and a fire accident has also occurred. By July 2018, there were a total of 7 cases. All 7 cases were ESS systems consisting of lithium-ion batteries and were burned down. Both the automatic fire extinguisher and the fire department were not able to digest. In this paper, the characteristics of ESS fire are analyzed based on recent ESS fire situation and field investigation, and the cause of fire is divided into environmental, electrical and thermal factors. As a result, it was found that the ESS fire was correlated with the installation environment of the system. In the domestic and overseas lithium ion battery test standard and ESS facility standard survey, the trends and differences of domestic and overseas facilities standards were identified. Based on the fire status and field investigationy, and domestic and overseas facility standard survey, measures were suggested to prevent and prevent the spread of fire in ESS fire.

• Journal of Powder Materials
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• v.28 no.5
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• pp.423-428
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• 2021

Here, we report the development of a new and low-cost core-shell structure for lithium-ion battery anodes using silicon waste sludge and the Ti-ion complex. X-ray diffraction (XRD) confirmed the raw waste silicon sludge powder to be pure silicon without other metal impurities and the particle size distribution is measured to be from 200 nm to 3 ㎛ by dynamic light scattering (DLS). As a result of pulverization by a planetary mill, the size of the single crystal according to the Scherrer formula is calculated to be 12.1 nm, but the average particle size of the agglomerate is measured to be 123.6 nm. A Si/TiO₂ core-shell structure is formed using simple Ti complex ions, and the ratio of TiO₂ peaks increased with an increase in the amount of Ti ions. Transmission electron microscopy (TEM) observations revealed that TiO₂ coating on Si nanoparticles results in a Si-TiO₂ core-shell structure. This result is expected to improve the stability and cycle of lithium-ion batteries as anodes.

• Journal of the Korean Electrochemical Society
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• v.22 no.3
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• pp.112-121
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• 2019

In this study, silicon / carbon nanotube / carbon composite particles with high capacity were fabricated by using micro-sized silicon particles and carbon nanotubes as an anode material for lithium ion batteries. The silicon / carbon nanotube / carbon composite particles were prepared by spray drying method to prepare spherical composite particles. The composite particles have the network structure of the carbon nanotubes around the silicon particles, in which the silicon particles and the carbon nanotubes are bonded by amorphous carbon. It appears that the volume expansion of silicon is effectively buffered and the electrical contact is maintained in the network structure of the composite particles during charge-discharge cycles.

• Journal of Powder Materials
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• v.28 no.6
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• pp.462-469
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• 2021

Tin/graphite composites are prepared as anode materials for Li-ion batteries using a dry ball-milling process. The main experimental variables in this work are the ball milling time (0-8 h) and composition ratio (tin:graphite=5:95, 15:85, and 30:70 w/w) of graphite and tin powder. For comparison, a tin/graphite composite is prepared using wet ball milling. The morphology and structure of the different tin/graphite composites are investigated using X-ray diffraction, Raman spectroscopy, energy-dispersive X-ray spectroscopy, and scanning and transmission electron microscopy. The electrochemical properties of the samples are also examined. The optimal dry ball milling time for the uniform mixing of graphite and tin is 6 h in a graphite-30wt.%Sn sample. The electrode prepared from the composite that is dry-ball-milled for 6 h exhibits the best cycle performance (discharge capacity after 50^th cycle: 308 mAh/g and capacity retention: 46%). The discharge capacity after the 50^th cycle is approximately 112 mAh/g, higher than that when the electrode is composed of only graphite (196 mAh/g after 50^th cycle). This result indicates that it is possible to manufacture a tin/graphite composite anode material that can effectively buffer the volume change that occurs during cycling, even using a simple dry ball-milling process.

• Korean Journal of Materials Research
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• v.31 no.11
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• pp.614-618
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• 2021

As the size of market for electric vehicles and energy storage systems grows, the demand for lithium-ion batteries (LIBs) is increasing. Currently, commercial LIBs are fabricated with liquid electrolytes, which have some safety issues such as low chemical stability, which can cause ignition of fire. As a substitute for liquid electrolytes, solid electrolytes are now being extensively studied. However, solid electrolytes have disadvantages of low ionic conductivity and high resistance at interface between electrode and electrolyte. In this study, Li₇La₃Zr₂O₁₂ (LLZO), one of the best ion conducting materials among oxide based solid electrolytes, is fabricated through RF-sputtering and various electrochemical properties are analyzed. Moreover, the electrochemical properties of LLZO are found to significantly improve with co-sputtered Li₂O. An all-solid thin film battery is fabricated by introducing a thin film solid electrolyte and an Li₄Ti₅O₁₂ (LTO) cathode; resulting electrochemical properties are also analyzed. The LLZO/Li₂O (60W) sample shows a very good performance in ionic conductivity of 7.3×10^-8 S/cm, with improvement in c-rate and stable cycle performance.