• 제목/요약/키워드: Lithium Ion

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리튬이온전지의 셀균등화 방법에 관한 연구 (A Study on Cell Equalizing for Lithium ion Battery)

  • 최원석;서병설
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.182-185
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    • 2003
  • Lithium ion battery is required to balance cells in order to minimize the electric capacity difference between the batteries. This paper proposes a cell balancing method by using inductor. Simulation and experimental results are presented.

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Synthesis and Characterization of Organosilane Electrolyte Containing Silphenylene

  • Kim, Jongjun;Sohn, Honglae
    • 통합자연과학논문집
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    • 제10권4호
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    • pp.197-201
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    • 2017
  • Organosilicon compound containing silphenylene unit as an eletrolyte for the application of lithium-ion batteries was synthesized by hydrosilylation method between 1,4-bis(dimethylsilylhydro)benzene and 3-[2-(2-methoxyethoxy)ethoxy]-1-propene. As-prepared new organosilicon compounds containing spacer such as propyl group with ethylene glycol are synthesized to improve thermal stability and to promote conductivity. The products are characterized by spectroscopic analysis.

리튬 이차 전지를 위한 다공성 니켈-주석 나노 수지상 전극 (Porous Nickel-Tin Nano-Dendritic Electrode for Rechargeable Lithium Battery)

  • 정혜란;신헌철
    • 한국재료학회지
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    • 제20권11호
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    • pp.592-599
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    • 2010
  • A porous nickel-tin nano-dendritic electrode, for use as the anode in a rechargeable lithium battery, has been prepared by using an electrochemical deposition process. The adjustment of the complexing agent content in the deposition bath enabled the nickel-tin alloys to have specific stoichiometries while the amount of acid, as a dynamic template for micro-porous structure, was limited to a certain amount to prevent its undesirable side reaction with the complexing agent. The ratios of nickel to tin in the electro-deposits were nearly identical to the ratios of nickel ion to tin ion in the deposition bath; the particle changed from spherical to dendritic shape according to the tin content in the deposits. The nickel to tin ratio and the dendritic structure were quite uniform throughout the thickness of the deposits. The resulting nickel-tin alloy was reversibly lithiated and delithiated as an anode in rechargeable lithium battery. Furthermore, the resulting anode showed much more stable cycling performance up to 50 cycles, as compared to that resulting from dense electro-deposit with the same atomic composition and from tin electrodeposit with a similar porous structure. From the results, it is expected that highly-porous nickel-tin alloys presented in this work could provide a promising option for the high performance anode materials for rechargeable lithium batteries.

리튬2차전지의 수명성능평가를 위한 충방전특성 모델링 (Charging/Discharging Modeling of Lithium Secondary Battery for Estimating Cycle Characteristic)

  • 김재언;노대석
    • 한국산학기술학회논문지
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    • 제8권6호
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    • pp.1343-1354
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    • 2007
  • 카메라, 휴대전화, 노트북 등과 같이 휴대 가능한 전기전자기기들은 대부분 2차 전지로부터 전원을 공급받고 있다. 2차 전지로서는 타 전지에 비하여 고 에너지 밀도와 고 전압의 특성을 갖고 있는 리튬2차전지가 가장 많이 활용되고 있으며, 이 특성 때문에 전기자동차, 우주왕복선, 분산전원의 한 형태인 전력 저장장치에까지 그 이용이 확대되고 있다. 그러나, 시스템의 최적성능을 보장하기 위해서는 용도별 싸이클 수명성능을 고려한 충방전 설계 및 이를 위한 전기적 등가모델의 정확성이 필수적이다. 따라서, 본 논문에서는 상용 리튬이차전지의 실제 실험 데이터에 근거하여 충/방전 심도 함수를 도출하고, 리튬이차전지의 수명성능평가를 위한 충/방전 특성 모델을 제안하고, 이의 타당성을 입증하였다.

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Numerical analysis of the electromagnetic force for design optimization of a rectangular direct current electromagnetic pump

  • Lee, Geun Hyeong;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • 제50권6호
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    • pp.869-876
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    • 2018
  • The force of a direct current (DC) electromagnetic pump used to transport liquid lithium was analyzed to optimize its geometrical and electrical parameters by numerical simulation. In a heavy-ion accelerator, which is being developed in Korea, a liquid lithium film is utilized for its high charge-stripping efficiency for heavy ions of uranium. A DC electromagnetic pump with a flow rate of $6cm^3/s$ and a developed pressure of 1.5 MPa at a temperature of $200^{\circ}C$ was required to circulate the liquid lithium to form liquid lithium films. The current and magnetic flux densities in the flow gap, where a $Sm_2Co_{17}$ permanent magnet was used to generate a magnetic field, were analyzed for the electromagnetic force distribution generated in the pump. The pressure developed by the Lorentz force on the electromagnetic force was calculated by considering the electromotive force and hydraulic pressure drop in the narrow flow channel. The opposite force at the end part due to the magnetic flux density in the opposite direction depended on the pump geometrical parameters such as the pump duct length and width that defines the rectangular channels in the nonhomogeneous distributions of the current and magnetic fields.

Lipophilic Crown-4 Derivatives as Lithium Ionophores for Lithium Ion Selective Liquid Membrane Electrodes

  • Jae Sang Kim;Sung Ouk Jung;Shim Sung Lee;Si-Joong Kim
    • Bulletin of the Korean Chemical Society
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    • 제14권1호
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    • pp.123-127
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    • 1993
  • New lipophilic Crown-4 compounds of 16-membered rings containing furan (neutral carrier,I), tetrahydrofuran (neutral carrier,II) and lithium complex of the latter (neutral carrier,III) have been synthesized and tested as the active sensors for lithium ion in poly(vinyl chloride) (PVC) membrane electrode, in the presence and absence of an anion excluder, tetrakis(4-chloro-phenyl)borate (KTClPB), 2-nitrophenyl phenyl ether (NPPE), tris(2-ethylhexyl)phosphate (TEHP), o-nitrophenyl octyl ether (NPOE), dioctyl adipate (DOA), bis(2-ethylhexyl)adipate (BEHA), di-n-octylphenyl phosphonate (DOPP) were used as plasticizing solvent mediators. The electrode response function had a nearly Nernstian slope of 54-61 mV per decade (25$^{\circ}$C) within the concentration range of $10^{-1}-10^{-4}$ M LiCl and the detection limits for all electrodes were ca. $5{\times}10^{-4}$ M. The response time of the electrode was faster at the higher lithium concentration and the response of the electrode was stable for longer than 6 months. The sensor membranes exhibit improved response times and increased lifetimes as compared to the system described earlier.

리튬 폴리머 드론 배터리 방전시 이상가스에 대한 연구 (Study on-Gas-generating Property Of Lithium Polymer Drone batteries)

  • 이종헌;김재원;윤홍주;서원찬
    • 한국전자통신학회논문지
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    • 제18권1호
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    • pp.195-204
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    • 2023
  • 드론의 배터리 시스템은 리튬이온 또는 리튬폴리머 배터리를 사용하는데, 드론 사용 후 폐기 과정에서 화재 원인은 폐기되는 배터리에서 발생하는 가연성 가스인 것으로 알려졌다. 폐기공정에 들어간 배터리는 대부분 산소가 발생했지만 미량의 가연성 가스도 발생했고, 처리에 사용된 장비에서도 다량의 염소 이온과 황산염이 검출됐다. 이를 조기에 감지하는 시스템이 구성된다면 폐기 배터리로 인한 사고 위험을 줄일 수 있을 것이다.

리튬이온전지 폐기물로부터 가치 있는 리튬금속을 멤브레인 기반으로 회수 (Membrane Based Recovery of Valuable Lithium Metals from Lithium Ion Battery Waste)

  • 토잔 탕베이;라즈쿠마 파텔
    • 멤브레인
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    • 제34권3호
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    • pp.163-171
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    • 2024
  • 환경오염을 제어하기 위한 청정에너지에 대한 수요 증가는 빠르게 증가하고 있습니다. 리튬 이온 배터리와 같은 충전식 배터리는 청정에너지의 우수한 원천이지만 높은 수요와 공급 불일치로 인해 리튬 금속이 빠르게 고갈되고 있습니다. 배터리 폐기물에서 귀금속을 회수하는 것은 환경오염 제어와 함께 가능한 해결책 중 하나입니다. 멤브레인 기반 분리 방법은 폐기물에서 리튬을 회수할 수 있는 매우 성공적인 상업적 공정입니다. 이 작업은 최근에 보고된 다양한 방법을 다룰 것이며 검토 형식으로 작성될 것입니다.