• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.19 no.12
• /
• pp.883-888
• /
• 2007

As a starting point of investigating what molecular dynamic simulations can reveal about the nature of atomic level of heating and cooling process, argon described by the LJ potential is considered. Stepwise heating and cooling of constant rates are simulated in the NPT (constant number, pressure and temperature) ensemble. Hysteresis is found due to the superheating and supercooling. Drastic change of volume and energy is involved with phase change, but the melting point can not be obtained by simply observing the changes of these quantities. Since liquid and solid phases can co-exist at the same temperature, Gibbs free energy should be calculated to find the temperature where the Gibbs free energy of liquid is equal to that of the solid since the equilibrium state is the state of minimum Gibbs free energy. The obtained melting temperature, $T^*=0.685$, is close to that of the experiment with only 2% error.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2009.10a
• /
• pp.1130-1132
• /
• 2009

We propose a novel way for enhancement of efficiency on a quasi solid-state dye-sensitized solar cell (DSSC). It contained gel type electrolyte mixing the liquid crystal (LC) of specific concentration and applied voltage for alignment of the LC. Aligned LC is supported charge transfer inside electrolyte and efficiency is increased in DSSC. We made a quasi solid-state DSSC which applied DC voltage or not and have measured the power conversion efficiency (PCE) and the fill factor. From measurement, we obtain high performances in case of cell applied voltage compare to reference cell.

• Journal of the Korea Institute of Building Construction
• /
• v.12 no.5
• /
• pp.548-557
• /
• 2012

In this study the thermal performance of G-PCM replaced for find aggregate in mortar specimens was evaluated using TG-DTA. As a result, it was found that when solid changed into liquid, it absorbed heat, and when liquid changed into solid, it radiated heat. In addition, the fluidity and the compressive strength of mortar with G-PCM can be applied to the floor mortar and a wall finish material. Also the higher the replacement ratio, the larger the latent heat capacity. It was found that the mortar with G-PCM slowed the increase and decrease of temperature. Thus, the duration of pleasant indoor temperature is extended by the floor and wall mortar with G-PCM. In conclusion, G-PCM is expected to reduce the heating energy consumption.

• Bulletin of the Korean Chemical Society
• /
• v.26 no.6
• /
• pp.943-946
• /
• 2005

An effective spectrophotometric determination of palladium with 4-(2-pyridylazo)-resorcinol (PAR) using molten naphthalene as a diluent has been studied. A red complex of palladium with PAR is formed at 90 ${^{\circ}C}$. In the range of pH 9.0-11.0, the complex is quantitatively extracted into molten naphthalene. The organic phase is anhydrously dissolved in $CHCl_3$ to be determined spectrophotometrically at 520 nm against the reagent blank. Beer’s law is obeyed over the concentration range of 0.1-2 ${\mu}g{\cdot}mL^{-1}$. The molar absorptivity and Sandell’s sensitivity are 8.0 ${\times}\;10^5\;L{\cdot}mol^{-1}{\cdot}cm^{-}1\;and\;0.49\;{\mu}g{\cdot}cm^{-2}$ respectively. From the results of tolerance limits, it was found that there was no interferences were observed for most of the ions examined and those somewhat high interferences by Co(II), Fe(II) and Bi(III) could be effectively masked by EDTA.

• Journal of the Korean Chemical Society
• /
• v.55 no.6
• /
• pp.983-987
• /
• 2011

Surveys on the process of extracting acid from dried rinds of Garcinia oblongifolia Champ. ex Benth (G. oblongifolia) using microwave in terms of time, machine power and solid/liquid rate, have resulted in such findings as: the best time allocation for extracting is 25 minutes; machine power works best at level 2 (microwave power is 400 W); suitable rate of solid/liquid is 0.071 (approximately 150 mL solvent per 10 g of sample). The total amounts acid and (-)-hydroxycitric acid extracted from 100 g dried rinds of G. oblongifolia are 18.592 g and 10.137g respectively. This is the first finding on extraction of (-)-HCA from dried rinds of G. oblongifolia using microwave.

• Journal of computational fluids engineering
• /
• v.12 no.4
• /
• pp.14-19
• /
• 2007

We present a direct numerical simulation technique and some preliminary results of the capillary spreading of a droplet containing particles on the solid substrate. We used the level-set method with the continuous surface stress for description of droplet spreading with interfacial tension and employed the discontinuous Galerkin method for the stabilization of the interface advection equation. The distributed Lagrangian-multipliers method has been combined for the implicit treatment of rigid particles. We investigated the droplet spreading by the capillary force and discussed effects of the presence of particles on the spreading behavior. It has been observed that a particulate drop spreads less than the pure liquid drop. The amount of spread of a particulate drop has been found smaller than that of the liquid with effectively the same viscosity as the particulate drop.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.10 no.3
• /
• pp.260-270
• /
• 1998

The viscous plane stagnation-flow solidification problem is theoretically investigated. An analytic solution at the beginning of solidification is obtained by expanding the temperature and thickness of solidified layer in powers of time. An exact expression for the steady-state thickness of solidified layer is also obtained. The .fluid flow toward the cold substrate inhibits the solidification process. As Stefan number becomes larger, or Prandtl number becomes smaller, the solidification is more strongly inhibited by the fluid flow. The transient heat flux at the liquid side of solid-liquid interface is increased, as Stefan number or Prandtl number is increased.

• Journal of the Semiconductor & Display Technology
• /
• v.7 no.2
• /
• pp.1-5
• /
• 2008

Silicide formation process and the formation sequence were investigated in this study. It was postulated that the formation of the second silicide phase involves glass formation between the first silicide phase and Si given that a thin metal film is deposited on a Si substrate. The concentration of glass was assumed to be located where the free energy of the liquid alloy with respect to the first nucleated compound and solid Si (${\Delta}$G') is most negative. It was also mentioned that the glass concentration is close to the composition of the second phase in order to achieve the maximum energy degradation. It was shown that the minimum ${\Delta}$G' concentration can be estimated by interpolating the portion of the liquidus where the liquid alloy is in equilibrium with the two solid constituents, namely the first compound phase and Si, thereby forming a hypothetical eutectic.

• Nuclear Engineering and Technology
• /
• v.50 no.7
• /
• pp.1184-1189
• /
• 2018

Pyroprocessing uses various molten salts during electrochemical unit processes. Reaction products after the electrochemical processes must contain a significant amount of residual salts to be separated. Vacuum distillation is a common method to separate the residual salts; however, its high operation temperature may cause side reactions. In this study, a simple rotation technique using centrifugal force was suggested to separate the residual salts from the reaction products at relatively low temperature compared to the distillation technique. When a reaction product container with porous wall rotates inside a vessel heated above the melting point of the residual salt, the residual salt in the liquid phase is separated through centrifugal force. It was shown that the $LiNO_3-Al_2O_3$ mixture can be separated by this technique to leave solid $Al_2O_3$ inside the container, with a separation efficiency of 99.4%.

• Proceedings of the PSK Conference
• /
• 2003.10b
• /
• pp.224.1-224.1
• /
• 2003

A sensitive and selective liquid chromatographic method coupled with tandem mass spectrometry (LC-MS/MS) was developed for the determination of beraprost in human plasma. Plasma samples were transferred into 96-well OASIS HLB extraction plate using an automated sample handling system and the drugs were eluted with methanol. The eluents were then evaporated and reconstituted with water. All sample transfer and solid-phase extraction (SPE) was automated through the application of both the PerkinElmer MultiPROBE II HT and TOMTEC Quadra 96 workstation. (omitted)