• 대한기계학회논문집
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• 제19권6호
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• pp.1518-1528
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• 1995

The deformation and departure processes of a bubble attached to the wall are studied experimentally and numerically to understand the phenomena of the nucleate boiling heat transfer enhancement under DC electric field. An air-bubble is injected in a dielectric liquid with different electric fields generated by changing three types of electrode system (Type 1,2 and 3) in the bubble generator. Experimental variables are the electric field strength and the distance and the shape of the electrodes under DC electric field. From experimental results, it is observed that the bubble under Dc electric field is elongated in the same direction as the electric field and the contact angle increases. For the parallel plate electrode which generates a uniform electric field, bubble departure volume doesn't seem to decrease within our experimental range. However, when a needle is raised a few millimeters from the lower electrode to make a nonuniform electric field around the needle, bubble departure volume decreases continuously with the increase of an applied voltage. The reduction effect of bubble departure volume is the most effective under a strong nonuniform electric field generated with Type 3. As the nonuniformity of the electric field due to the shape of a electrode increases, the terminal velocity and the acceleration of a bubble increase largely. For the comparison with visualization results, the deformation of a bubble attached to the electrode is carried out by a numerical method. Numerical results show good agreement qualitatively with experimental results.

• 대한기계학회논문집B
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• 제40권1호
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• pp.1-7
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• 2016

환원제를 이용하여 배기가스 내의 NOx를 질소로 환원시키는 요소수 SCR 시스템은 다른 후처리 장치들 중에서 가장 효율적인 장치로 알려져 있다. 차량에 적용되는 SCR 장치는 32.5wt%의 공융혼합물을 이용한다. 이러한 혼합물의 가장 큰 장점 중의 하나는 $-11.7^{\circ}C$에서 얼기 때문에 추운 환경에서 응고를 피할 수 있다는 것이다. 한편, 이러한 추운 환경에서 시동시 필요한 수용액을 충분히 공급하기 위해서는 고체상을 가열해야 한다. 따라서 본 연구에서는 Fluent 상용코드를 이용하여 3차원 비정상 전산해석을 통한 냉각수 및 전기가열 방식에 따른 고체상 요소수의 시간에 따른 액상비 및 온도분포와 같은 해동 및 열전달 특성을 고찰하였다. 본 연구를 통하여 전기히터 가열 방식이 냉각수 방식보다 효율적임을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1643-1646
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• 2012

Three Ni-based catalysts with different clay as support were prepared and tested in the hydrogenation of maleic anhydride, among which Ni/clay1 showed best activity and selectivity. Over Ni/clay1 catalyst prepared by impregnation method, 97.14% conversion of maleic anhydride and 99.55% selectivity to succinic anhydride were obtained at $180^{\circ}C$ under a pressure of 1 MPa. Catalytic activity was greatly influenced by the temperature and weighted hourly space velocity. Catalyst deactivation studies showed that this catalyst have a long life time, the yield of MA still higher than 90% even after a reaction time of 60 h. X-ray diffraction (XRD) and $H_2$ temperature programmed reduction (TPR) were use to investigate the properties of the catalyst. XRD and TPR studies showed that Ni was present as $Ni^{2+}$ on the support, which indicated that there was no elemental nickel ($Ni^0$) and $Ni_2O_3$ in the unreduced samples. The formation of Ni was strong impact on catalytic activity.

• Carbon letters
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• 제12권1호
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• pp.1-7
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• 2011

In the present study, the removal of Pb (II) ions on oxidized activated carbons (ACs) was investigated. ACs were derived from activation of indigenous cotton stalks waste with potassium hydroxide (KOH) in two-stage process. The KOH-ACs were subjected to liquid-phase oxidation with hot $HNO_3$ and one untreated sample was included for comparison. The obtained carbons were characterized by Fourier transform infrared (FTIR), slurry pH and $N_2$-adsorption at 77 K, respectively. Adsorption capacity of Pb (II) ions on the resultant carbons was determined by batch equilibrium experiments. The experimental results indicated that the oxidation with nitric acid was associated with a significant increase in mass of yield as well as a remarkable reduction in internal porosity as compared to the untreated carbon. The AC-800N revealed higher adsorption capacity than that of AC-800, although the former sample exhibited low surface area and micropore volume. It was observed that the adsorption capacity enhancement attributed to pore widening, the generation of oxygen functional groups and potassium containing compounds leading to cation-exchange on the carbon surface. These results show that the oxidized carbons represented prospective adsorbents for enhancing the removal of heavy metals from wastewater.

• 한국분말재료학회지
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• 제4권2호
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• pp.113-121
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• 1997

The densification of the compacts of Co+32%Cr+20%W+l.5%C, Co+32%Cr+20%W+3.0%C and Co+32%Cr+20%W+4.5%C sintered under $H_2$ gas or vacuum was investigated. The effect of V and B addition on the densification was also investigated. The densification of these compacts were always incomplete regardless of sintering atmosphere, temperature and time. The amounts of oxygen and carbon in compacts sintered in $H_2$ for 3.6ks at 1523K were 0.105~0.160 mass% and 0.33~0.89 mass%, respectively. And those in vacuum were 0.028~0.032% and 0.957~4.08%, respectively. Relative density(Ds) of Co+29%Cr+17%W+3.0%C compact containing 6%V and Co+32%Cr+20%W+2.97%C compact containing 0.03%B were 99 and 100%, respectively, indicating complete densification by solid phase sintering. Victors hardness of sintered compacts containing 6%V or 0.03%B were 632 and 568, showing 50~60% increase in comparison to those without V or B. These results can be explained in terms of oxidation/reduction of oxides and equilibrium pressure of CO in isolated pore, instead of presence of liquid formation and grain boundary separation from pores due to large grain growth.

• Journal of the Optical Society of Korea
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• 제19권1호
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• pp.63-68
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• 2015

A one-step fabrication of a photonic crystal (PC) with functional defects is demonstrated. Using multi-beam phase-controlled holographic lithography with a diffracting optical element, large area one dimensional (1D) and two dimensional (2D) PCs with periodic defects were fabricated. The uniform area is up to $2mm^2$, and tens of defect channels have been introduced in the 1D and 2D PC structure. This technique gives rise to substantial reduction in the fabrication complexity and significant improvement in the spatial accuracy of introducing functional defects in photonic crystals. This method can also be used to design and fabricate three dimensional (3D) PCs with periodic defects.

• 공업화학
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• 제28권3호
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• pp.272-278
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• 2017

2차원 소재인 그래핀과 이황화몰리브덴($MoS_2$)은 슈퍼커패시터 응용을 위한 많은 관심과 무한한 가능성을 보여주었다. 2차원 소재의 슈퍼커패시터 응용성을 높이기 위해서는 2차원 소재 제조를 위한 효율적이면서 친환경적인 저비용 합성법이 개발되어야 한다. 본 논문에서 우리는 최근 개발된 슈퍼커패시터용 용액기반 2차원 소재 제조 기술을 논하고자 한다. 화학적 박리-환원, 화학적 삽입, 액상 박리 기술법들을 소개하고자 한다. 또한 그래핀과 이황화몰리브덴의 전기화학적 특성들을 정리하였다. 용액기반 공정들과 함께 개선되어야 할 나노시트들의 조성, 크기 및 두께 조절 기술개발을 다룬다.

• 동력기계공학회지
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• 제9권4호
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• pp.209-213
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• 2005

The effects of density change of ambient gas on mixture formation process have been investigated in high temperature and pressure field. To analyze the mixture formation process of evaporating diesel spray is important for emissions reduction in actual engines. Ambient gas density was selected as experimental parameter. The ambient gas density was changed from $r_a=5.0kg/m^3\;to\;r_a=12.3kg/m^3$ with a high pressure injection system(ECD-U2). For visualization of the experiment phenomenon, a CVC(Constant Volume Chamber) was used in this study. The ambient temperature and injection pressure are kept as 700K and 72MPa, respectively. The images of liquid and vapor phase in the evaporating free spray were simultaneously taken by exciplex fluorescence method. As experimental results, with increasing ambient gas density, the tip penetration of the evaporating free spray decreases due to the increase in the drag force from ambient gas.

• 한국자동차공학회논문집
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• 제9권6호
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• pp.30-39
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• 2001

The direct injection into the cylinders has been regarded as a way of the reduction in fuel consumption and pollutant emissions. The spray produced by the high pressure injector is of paramount importance in DISI(Direct Injection Spark Ignition) engines in that the primary atomization process must meet the requirement of quick and complete evaporation, mixing with air and combustion especially to prohibit the excessive HC emissions. The interaction between air flow and fuel spray was investigated in a steady flow system embodied in a wind tunnel to simulate the variety of flow inside the cylinder of the DISI engine. The direct Mie scattered and shadowgraph images presented the macroscopic view of the liquid sprays and vapor fields. The velocity and particle size of fuel droplets were investigated by phase doppler anenometer(PDA) system. The processes of atomization and evaporation with a DISI injector were observed and consequently utilized to construct the data-base for the spray and fuel-air mixing mechanism as a function of the flow characteristics.

• 한국주조공학회지
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• 제15권5호
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• pp.459-468
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• 1995

For high performance aerospace structures, the properties of highest priority are low density, high strength, and high stiffness(modulus of elasticity). Addition of beryllium decrease the density of the aluminum alloy and increase the strength and the stiffness of the alloy. However it is very difficult to produce the Al-Be alloy having useful engineering properties by conventional ingot casting, because of the extremely limited solid solubility of beryllium in aluminum. So, rapid solidification processing is necessary to obtain extended solid solubility. In this study, rapidly solidified Al-6 at% Be alloy were prepared by twin roll melt spinning process and single roll melt spinning process. Twin roll melt spun ribbons were extruded at $450^{\circ}C$ with reduction in area of 25 : 1 after vacuum hot pressing at $550^{\circ}C and 375^{\circ}C$. The microstructure of melt spun ribbon exhibited a refined cellular microstructure with dispersed Be particles. As advance velocity of liquid/solid interface increase, the morphology of Be particle vary from rod-like type to spherical type and the crystal structure of Be particle from HCP to BCC. These microstructural characteristics of rapidly solidified Al-6at.%Be alloy were described on the basis of metastable phase diagram proposed by Perepezko and Boettinger. The extruded ribbon consisted of recrystallized grains dispersed with Be particles and exhibited improved tensile property compared with that of extruded ingot.