Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Highly Efficient and Selective Nickel/Clay Catalyst for Liquid Phase Hydrogenation of Maleic Anhydride to Succinic Anhydride

  • Tian, Weiping (The State Key Laboratory of Chemical Engineering, East China University of Science and Technology) ;
  • Guo, Shaofei (The State Key Laboratory of Chemical Engineering, East China University of Science and Technology) ;
  • Shi, Li (The State Key Laboratory of Chemical Engineering, East China University of Science and Technology)
  • Received : 2011.10.07
  • Accepted : 2012.02.15
  • Published : 2012.05.20
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Abstract

Three Ni-based catalysts with different clay as support were prepared and tested in the hydrogenation of maleic anhydride, among which Ni/clay1 showed best activity and selectivity. Over Ni/clay1 catalyst prepared by impregnation method, 97.14% conversion of maleic anhydride and 99.55% selectivity to succinic anhydride were obtained at $180^{\circ}C$ under a pressure of 1 MPa. Catalytic activity was greatly influenced by the temperature and weighted hourly space velocity. Catalyst deactivation studies showed that this catalyst have a long life time, the yield of MA still higher than 90% even after a reaction time of 60 h. X-ray diffraction (XRD) and $H_2$ temperature programmed reduction (TPR) were use to investigate the properties of the catalyst. XRD and TPR studies showed that Ni was present as $Ni^{2+}$ on the support, which indicated that there was no elemental nickel ($Ni^0$) and $Ni_2O_3$ in the unreduced samples. The formation of Ni was strong impact on catalytic activity.

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