• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.259-263
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• 2001

There are several steps such as slicing, lapping, chemical etching and mechanical polishing in the silicon wafer production process. The chemical etching step is necessary to remove damaged layer caused In the slicing and lapping steps. The typical etching liquor is the acid mixture comprising nitric acid, acetic acid and hydrofluoric acid. At present, the waste acid is treated by a neutralization method with a high alkali cost and balky solid residue. A solvent extraction method is applicable to separate and recover each acid. Acetic acid is first separated from the waste liquor using 2-ethlyhexyl alcohols as an extractant. Then, nitric acid is recovered using TBP(Tri-butyl phosphate) as an extractant. Finally hydrofluoric acid is separated with the TBP solvent extraction. The expected recovered acids in this process are 2㏖/l acetic acid, 6㏖/1 nitric acid and 6㏖/l hydrofluoric acid. The yields of this process are almost 100% for acetic acid and nitric acid. On the other hand, it is important to recover and reuse the metal values contained in various industrial wastes in a viewpoint of environmental preservation. Most of industrial products are made through the processes to separate impurities in raw materials, solid and liquid wastes being necessarily discharged as industrial wastes. Chemical methods such as solvent extraction, ion exchange and membrane, and physical methods such as heavy media separation, magnetic separation and electrostatic separation are considered as the methods for separation and recovery of the metal values from the wastes. Some examples of the application of solvent extraction to the treatment of wastes such as Ni-Co alloy scrap, Sm-Co alloy scrap, fly ash and flue dust, and liquid wastes such as plating solution, the rinse solution, etching solution and pickling solution are introduced.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1143-1148
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• 2010

We investigated the separation of nitrogen heterocyclic compound (NHC) contained in a model coal tar fraction comprising four kinds of NHC [indole (In), quinoline (Q), iso-quinoline (iQ), quinaldine (Qu)], three kinds of bicyclic aromatic compound (BAC) [1-methylnaphthalene (1MN), 2-methylnaphthalene (2MN), dimethylnaphthalene (DMN) mixture with ten structural isomers (DMNs; regarded as one component)], biphenyl (Bp) and phenyl ether (Pe) by liquid membrane permeation (LMP). A batch-stirred tank was used as the permeation unit. An aqueous solution of saponin and n-hexane were used as the liquid membrane and the outer oil phase, respectively. Yield and selectivity of individual NHC was much larger than that of BAC, Bp and Pe. Increasing the initial mass fraction of the saponin to the membrane solution ($C_{sap,0}$) and the initial volume fraction of O/W emulsion to total liquid in a stirred tank (${\phi}_{OW,0}$) resulted in deteriorating the yield of individual NHC, but increasing the stirring speed (N) resulted in improving the yield of each NHC. With increasing $C_{sap,0}$, the selectivity of each NHC based on DMNs increased. Increasing ${\phi}_{OW,0}$ and N resulted in decreasing the selectivity of individual NHC based on DMNs. At an experimental condition fixed, the sequence of the yield and selectivity in reference to DMNs for each NHC was Q > Qu = iQ > In. Furthermore, we compared LPM method with methanol extraction method in view of the separation efficiency (yield, selectivity) of NHC.

• Journal of the Korean Society of Food Science and Nutrition
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• v.31 no.1
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• pp.7-11
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• 2002

Hydrothermal extraction from dates was done, and then 3 groups of the date extract liquid group (A), the date puree group (B) and the jujube skin flesh group (C) were prepared. And, the omija extract liquid was added to the 3 groups at respective rates of 3:7, 5:5 and 7:3. Then, total 9 medicated diet sources were prepared by adding cinnamon, the ginger extract liquid, honey and pectin. And their physicochenmical and sensory attributes were examined. Total sugar, free sugar and pH increased in the samples of the 3 groups as the addition amount of the jujube extract increased. In chromaticity of respective samples, the "L" value did not show any difference among the 3 groups, but the "a" value was the highest in the "A"group, and "b"value was the highest in the "B"group. In the date puree group and the jujube skin flesh group, their viscosity increased as the addition amount of the jujube extract increased, but in the jujube extract liquid group, no difference was found in its viscosity. As a result of conducting the discrimination test, it was identified that the as the addition amount of the jujube extract was increased, color and sweet taste were feltto be stronger and our taste was felt to be weaker in all 3 groups. In the jujube puree group and the jujube skin flesh group, as the addition amount of the jujube extract increased, the jujube fragrance was felt to be stronger, but in the jujube extract liquid group, no difference was found in its fragrance. And, no difference was found in brightness and viscosity between samples. As a result of conducting the palatability test, no difference was showed in the appearance, but as for the overall palatability including texture, taste and fragrance, preference increased as the addition amount of the jujube extract increased.

• Analytical Science and Technology
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• v.24 no.6
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• pp.477-483
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• 2011

This work is on the synthesis of EMI-$BF_4$ (1-ethyl-3-methylimidazolium tetrafluoroborate) and purification of spectroscopic grade using aluminium oxide method, activated charcoal method, and liquid/liquid fractional extraction method in order to make supercapacitor finally. But the aluminum oxide method and the activated charcoal method were not suitable for obtaining high-purity ionic liquids. The liquid/liquid fractional distillation method turned out that as the concentration of solvent ($H_2O$) was increased, the higher purity of EMI-$BF_4$ was obtained and the electrical capacity of this compound was increased to higher value. When the solvent was changed to from methylene chloride to 1,2-dichloroethane, the higher purity of EMI-$BF_4$ was obtained.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.3
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• pp.93-97
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• 2015

To synthesis of high purity micro silver particle, we extracted the silver from the waste by liquid-liquid extraction and used the rapid firing-liquid phase precursor (RF-LPP) method. The silver micro particle was synthesized at $500^{\circ}C$ for 3 hr in air atmosphere by RF-LPP method. As a result of the research, micro silver particle is measured X-ray diffraction (XRD), the main peak is nearly corresponded to the same as JCPDS card (No.87-0719). With using the RF-LPP method, the fine Ag micro particle indicated due to the control of nucleation site and the oxygen contents was decreased by reducing treatment. We expect this research contribute to advance in field of the recycling technology.

• Journal of ILASS-Korea
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• v.12 no.1
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• pp.38-44
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• 2007

Since the Liquid Phase LPG injection (LPLI) system has Advantages in power generation and emission characteristics compared to the mixer-type fuel-supply system, a variety of studies regarding LPLi system has been conducted and its applications are made in automobile industry. However, the heat extraction due to the evaporation of liquid fuel, causes not only a post-accumulation of fuel but also an icing phenomenon which is a frost of moisture in the air around the nozzle tip. Since there exists a difficulty in the accurate control of air fuel ratio in both fuel supply systems, it can result in poor engine performance and a large amount of harmful emissions. This research examines the characteristics of icing phenomenon and develops anti-icing bushing to prevent an icing on the surface of the injection tip. It was found that n-butane, which has a relatively high boiling point ($-0.5^{\circ}C$), was a main species of post-accumulation. Also the results show that the post-accumulation problem was allevaited the utilization of a large inner to outer bore ratio and smooth surface roughness. In addition, an icing phenomenon and its formation process were found to be mainly affected by the humidity and the temperature of inlet air in an inlet duct. Also, it was observed that an icing phenomenon is lessened using aluminum bushing whose end coincides with the end of fuel injection tip in length.

• Journal of the Korea Computer Graphics Society
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• v.24 no.2
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• pp.11-20
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• 2018

We propose a new method particle-based method that explicitly preserves thin liquid sheets for animating liquids on CPU-GPU heterogeneous computing framework. Our primary contribution is a particle-based framework that splits at thin points and collapses at dense points to prevent the breakup of liquid on GPU. In contrast to existing surface tracking methods, the our method does not suffer from numerical diffusion or tangles, and robustly handles topology changes on CPU-GPU framework. The thin features are detected by examining stretches of distributions of neighboring particles by performing PCA(Principle component analysis), which is used to reconstruct thin surfaces with anisotropic kernels. The efficiency of the candidate position extraction process to calculate the position of the fluid particle was rapidly improved based on the CPU-GPU heterogeneous computing techniques. Proposed algorithm is intuitively implemented, easy to parallelize and capable of producing quickly detailed thin liquid animations.

• Bulletin of the Korean Chemical Society
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• v.25 no.1
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• pp.109-114
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• 2004

A sensitive method for quantitation of glimepiride in human plasma has been established using liquid chromatography-electrospray ionization tandem mass spectrometry (LC-ESI/MS/MS). Glipizide was used as an internal standard. Glimepiride and internal standard in plasma sample was extracted using diethyl etherethyl acetate (1 : 1). A centrifuged upper layer was then evaporated and reconstituted with the mobile phase of acetonitrile-5 mM ammonium acetate (60:40, pH 3.0). The reconstituted samples were injected into a $C_{18}$ reversed-phase column. Using MS/MS in the multiple reaction monitoring (MRM) mode, glimepiride and glipizide were detected without severe interference from human plasma matrix. Glimepiride produced a protonated precursor ion ([M+H]$^+$) at m/z 491 and a corresponding product ion at m/z 352. And the internal standard produced a protonated precursor ion ([M+H]]$^+$) at m/z 446 and a corresponding product ion at m/z 321. Detection of glimepiride in human plasma by the LC-ESI/MS/MS method was accurate and precise with a quantitation limit of 0.1 ng/mL. The validation, reproducibility, stability, and recovery of the method were evaluated. The method has been successfully applied to pharmacokinetic studies of glimepiride in human plasma.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.5
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• pp.638-648
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• 2004

In many drinking water treatment plants, chlorination process is one of the main techniques used for the disinfection of water. This disinfecting treatment leads to the formation of haloacetic acid (HAAs). In this study, headspace solid-phase microextraction (HS-SPME) was studied as a possible alternative to liquid-liquid extraction for the analysis of HAAs in drinking water. The method involves direct derivatization of the acids to their methyl esters without methyl tert-butyl ether (MTBE) extraction, followed by HS-SPME with a $2cm-50/30{\mu}m$ divinylbenzene/carboxen/polydimethylsiloxane fiber. The effects of experimental parameters such as selection of SPME fiber, the volume of sulphuric acid and methanol, derivatization temperature and time, the addition of salts, extraction temperature and time, and desorption time on the analysis were investigated. Analytical parameters such as linearity, repeatability and limit of detection were also evaluated. The $2cm-50/30{\mu}m$-divinylbenzene/carboxen/polydimethylsiloxane fiber, sulphuric acid of 1ml, methanol of 3ml, derivatization temperature of $50^{\circ}C$ derivatization time of 2hrs, sodium chloride salt of 10g, extraction time of 30 minutes, extraction temperature of $20^{\circ}C$ and desorption time of 1 minute at $260^{\circ}C$ were selected as the optimal experimental conditions for the analysis of HAAs. The linearities ($r^2$), relative standard deviations (%RSD) and limits of detection (LOD) for HAAs were 0.9978~0.9991, 1.1~9.8% and $0.05{\sim}0.2{\mu}g/l$, respectively.

• Journal of the Korean Chemical Society
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• v.41 no.9
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• pp.471-482
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• 1997

GC/MS was used to find an optimum experimental condition for the screening of organic acids in urine. Urinary organic acids were isolated through the liquid-liquid extraction method (LLE) to examine the influence of pH and the effect of including the back extraction and oximation processes respectively on the extraction. When pH was adjusted to 0.5 during the extraction without oximation process, relatively higher recovery rate and the smallest relative standard deviations (0.3-12.4%) were obtained. By removing the interference, the addition of back extraction made possible surer identification of organic acids with retention time of 15-16 minutes. Under this condition, we obtained the content distribution of urinary organic acids in healthy Korean children (n=16) by establishing the calibration curves for 51 standard organic acids.