• Title/Summary/Keyword: Liquid waste

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Estimation of Biomass Resources Potential (바이오매스 자원 잠재량 산정)

  • Lee, Joon-pyo;Park, Soon-chul
    • Journal of the Korean Solar Energy Society
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    • v.36 no.1
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    • pp.19-26
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    • 2016
  • Biomass has been used for energy sources from the prehistoric age. Biomass are converted into solid, liquid or gaseous fuels and are used for heating, electricity generation or for transportation recently. Solid biofuels such as bio-chips or bio-pellet are used for heating or electricity generation. Liquid biofuels such as biodiesel and bioethanol from sugars or lignocellulosics are well known renewable transportation fuels. biogas produced from organic waste are also used for heating, generation and vehicles. Biomass resources for the production of above mentioned biofuels are classified under following 4 categories, such as forest biomass, agricultural residue biomass, livestock manure and municipal organic wastes. The energy potential of those biomass resources existing in Korea are estimated. The energy potential for dry biomass (forest, agricultural, municipal waste) were estimated from their heating value contained, whereas energy potential of wet biomass (livestock manure, food waste, waste sludge) is calculated from the biological methane potential of them on annual basis. Biomass resources potential of those 4 categories in Korea are estimated to be as follows. Forest biomass 355.602 million TOE, agricultural biomass 4.019 million TOE, livestock manure biomass 1.455 million TOE, and municipal organic waste 1.074 million TOE are available for biofuels production annually.

Simulation of the Migration of 3H and 14C Radionuclides on the 2nd Phase Facility at the Wolsong LILW Disposal Center

  • Ha, Jaechul;Son, Yuhwa;Cho, Chunhyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.439-455
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    • 2020
  • Numerical model was developed that simulates radionuclide (3H and 14C) transport modeling at the 2nd phase facility at the Wolsong LILW Disposal Center. Four scenarios were simulated with different assumptions about the integrity of the components of the barrier system. For the design case, the multi-barrier system was shown to be effective in diverting infiltration water around the vaults containing radioactive waste. Nevertheless, the volatile radionuclide 14C migrates outside the containment system and through the unsaturated zone, driven by gas diffusion. 3H is largely contained within the vaults where it decays, with small amounts being flushed out in the liquid state. Various scenarios were examined in which the integrity of the cover barrier system or that of the concrete were compromised. In the absence of any engineered barriers, 3H is washed out to the water table within the first 20 years. The release of 14C by gas diffusion is suppressed if percolation fluxes through the facility are high after a cover failure. However, the high fluxes lead to advective transport of 14C dissolved in the liquid state. The concrete container is an effective barrier, with approximately the same effectiveness as the cover.

Analysis of 12 chlorophenols in waste-water using automated liquid phase microextracion (LPME) device (자동화된 Liquid Phase Microextraction(LPME)를 이용한 폐수 중 12종의 클로로페놀 분석)

  • Kim, Seok-Jung;Cho, Hyun-Woo;Myung, Seung-Woon
    • Analytical Science and Technology
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    • v.20 no.1
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    • pp.70-77
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    • 2007
  • Twelve chlorophenols (CPs) were extracted by liquid phase microextraction (LPME) from the industrial waste-water and analyzed by GC/MS. To establish the optimal conditions, species of extraction solvent, sample amount, pH of sample, salting out effect, a number of sampling and plunger movement speed were investigated. As a result, the linearities of calibaration curves ranged from 0.9913 to 0.9999, while LODs and LOQs were from 0.05 to 10.0 ng/mL except 2,3,4,5-tetrachlorophenol and pentachlorophenol. Using this method, 4-chloro-3-methylphenol confirmed from waste water at the concentration of 784 ng/mL. The method can be applicable to detect chlorophenols from industrial waste-water.

Electrochemical Behaviors of Bi3+ Ions on Inert Tungsten or on Liquid Bi Pool in the Molten LiCl-KCl Eutectic

  • Kim, Beom Kyu;Park, Byung Gi
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.1
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    • pp.33-41
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    • 2022
  • Liquid Bi pool is a candidate electrode for an electrometallurgical process in the molten LiCl-KCl eutectic to treat the spent nuclear fuels from nuclear power plants. The electrochemical behavior of Bi3+ ions and the electrode reaction on liquid Bi pool were investigated with the cyclic voltammetry in an environment with or without BiCl3 in the molten LiCl-KCl eutectic. Experimental results showed that two redox reactions of Bi3+ on inert W electrode and the shift of cathodic peak potentials of Li+ and Bi3+ on liquid Bi pool electrode in molten LiCl-KCl eutectic. It is confirmed that the redox reaction of lithium with respect to the liquid Bi pool electrode would occur in a wide range of potentials in molten LiCl-KCl eutectic. The obtained data will be used to design the electrometallurgical process for treating actinide and lanthanide from the spent nuclear fuels and to understand the electrochemical reactions of actinide and lanthanide at liquid Bi pool electrode in the molten LiCl-KCl eutectic.