• Korean Chemical Engineering Research
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• v.49 no.3
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• pp.271-276
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• 2011

We investigated the possibility of introducing functional groups without damaging surface polymeric chains through the treatment of a polypropylene(PP) film immersed in liquid phase using an atmospheric pressure plasma with large area. The ionic liquid of 1-butyl-3-methylimidazolium tetrafluoroborate: $[BMIM]^{+}[BF_{4}]^{-}$- was successfully applied for generating stable plasmas in the plasma-solution system. We successfully treated the film surface using the plasma-solution system and confirmed various oxygen-containing functional groups formed on the surface of PP film. The surface free energy of PP film was increased with increasing plasma treatment time and power. It also showed a maximum value at the PP sample treated in the ionic liquid solution of 1.5 M. ATR-FTIR analyses revealed the increase of various carbonyl groups(1,726 $cm^{-1}$, 1,643 $cm^{-1}$) and OH groups$(3,100{\sim}3,500\;cm^{-1})$ after plasma treatment of PP film, and XPS also supported the ATR-FTIR result.

• Coupled systems mechanics
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• v.8 no.1
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• pp.19-38
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• 2019

The influence of torsional rigidity of hinged flexible appendage on the linear dynamics of flexible spacecrafts with liquid on board was analyzed by considering the spacecraft's main body as a rigid tank, its flexible appendages as two elastically supported elastic beams, and the onboard liquid as an ideal liquid. The meniscus of the liquid free surface due to surface tension was considered. Using the Lagrangian of the spacecraft's main body (rigid tank), onboard liquid, and two beams (flexible appendages) in addition to assuming the system moved symmetrically, the coupled system frequency equations were obtained by applying the Rayleigh-Ritz method. The influence of the torsional rigidity of the flexible appendages on the spacecraft's coupled vibration characteristics was primary focus of investigation. It was found that coupled vibration modes especially that of appendage considerably changed with torsion spring parameter ${\kappa}_t$ of the flexible appendage. In addition, variation of the main body displacement with system parameters was investigated.

• 한국전산유체공학회:학술대회논문집
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• 2003.10a
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• pp.160-161
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• 2003

Thermocapillary convection is a surface tension driven flow due to a temperature gradient along an interface. It occurs during a crystal-growth process and therefore understanding the convection is important to material processing in microgravity. Although modelling of the float-zone crystal-growth process has been of interest for a few decades, most studies of liquid bridges assumed non-deformable flat surfaces. In reality, the surface profile, g(t,z), is unknown and should be obtained as a solution to the coupled transport equations along with the surface force balance. Here we report on a numerical study of axisymmetric thermocapillary convection in liquid bridges with deformable surfaces. The interface is determined as part of the complete solution. The influence of the capillary number (Ca), Reynolds number (Re), Prandtl number (Pr) and aspect ratio(Ar) on the dynamics is explored.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.7
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• pp.1014-1021
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• 2002

Analysis of two-dimensional secondary flows given by an oscillatory motion of a liquid with a free surface in a rectangular container subject to a linear reciprocating force is performed by numerical and experimental methods. FVM is used for the numerical computation of the two-dimensional flows. We considered the effects of the free-surface properties such as the surface tension and the dilatational viscosity. The boundary-layer analysis as well as an experiment is used in establishing the free surface properties. The secondary flow patterns are visualized by a laser sheet. It is shown that the secondary flow patterns predicted by the numerical methods are in good agreement with the experimental results.

• Proceedings of the PSK Conference
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• 2003.10b
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• pp.236.1-236.1
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• 2003

Evaluation of solid surface properties is very important for formulation of solid dosage form, specially insoluble drugs. The contact angle of insoluble drugs was measured by the penetration rate into powder bed using Washburn equation and wicking method. From the measured contact angle data, the surface free energy value of pharmaceutical powders ${\gamma}$s was divided and analysized into the polar component, ${\gamma}$s$\^$p/ and the dispersion component, ${\gamma}$s$\^$d/. Furthermore, the data was interpreted for acid part, ${\gamma}$s$\^$+/ and base part, ${\gamma}$s$\^$$\square$/ of surface free energy. (omitted)

• Clean Technology
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• v.22 no.3
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• pp.203-207
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• 2016

Here, we report a novel fabrication technique for patchable organic lasing sheet based on non-volatile liquid organic semiconductors and freestanding polymeric film with high flexibility and patchability. For this work, we have fabricated the second-order DFB grating structure, which leads to surface emission, embedded in the freestanding polymeric film. Using an ultra-violet (UV) curable polyurethaneacrylate (PUA) mixture, the periodic DFB grating structure can be easily prepared on the freestanding polymeric film via a simple UV curing process. Due to unsaturated acrylate remained in the PUA mixture after UV curing, the freestanding PUA film provides adhesive properties, which enable mounting of the patchable organic lasing sheet onto non-flat surfaces with conformal contact. To achieve laser actions in the freestanding resonator structure, a composite material of liquid 9-(2-ethylhexyl)carbazole (EHCz) and organic laser dyes was used as the laser medium. Since the degraded active materials can be easily refreshed by a simple injection of the liquid composite, such a non-volatile liquid organic semiconducting medium has degradation-free and recyclable characteristics in addition to other strong advantages including tunable optoelectronic responses, solvent-free processing, and ultimate mechanical flexibility and uniformity. Lasing properties of the patchable organic lasing sheet were also investigated after mounting onto non-flat surfaces, showing a mechanical tunability of laser emission under variable surface curvature. It is anticipated that these results will be applied to the development of various patchable optoelectronic applications for light-emitting displays, sensors and data communications.

• Journal of the Society of Naval Architects of Korea
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• v.47 no.4
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• pp.508-516
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• 2010

This study aims at investigating the effect of the chamfer on the liquid sloshing in the three-dimensional (3D) rectangular tank. In order to simulate the 3D incompressible viscous two-phase flow in the 3D tank with partially filled liquid, the present study has adopted the volume of fluid (VOF) method based on the finitevolume method which has been well verified by comparing with the results of the relevant previous researches. The effects of the chamfering top corners of the tank on the liquid sloshing characteristics have been investigated. The angle of the chamfering top corners (${\theta}$) has been changed in the range of $0^{\circ}{\leq}{\theta}{\leq}60^{\circ}$(${\Delta}{\theta}=15^{\circ}$) to observe the free surface behavior, and the effect on wall impact load. Generally, as the angle of the chamfering top corners increases, the impact pressure on the upper knuckle point decreases. However it seemed that a critical angle of the chamfering top corners exists to reveal the lowest impact pressure on the wall.

• Journal of Powder Materials
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• v.18 no.2
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• pp.112-121
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• 2011

This study investigated the effect of solvent on the fabrication of Ni-free Fe-based alloy nano powders by employing the PWE (pulsed wire evaporation) in liquid and compared the alloy particles fabricated by three different methods (PWE in liquid, PWE in Ar, plasma arc discharge), for high temperature oxidation-resistant metallic porous body for high temperature soot filter system. Three different solvents (ethanol, acetone, distilled water) of liquid were adapted in PWE in liquid process, while X-ray diffraction (XRD), field emission scanning microscope (FE-SEM), and transmission electron microscope (TEM) were used to investigate the characteristics of the Fe-Cr-Al nano powders. The alloy powder synthesized by PWE in ethanol has good particle size and no surface oxidation compared to that of distilled water. Since the Fe-based alloy powders, which were fabricated by PWE in Ar and PAD process, showed surface oxidation by TEM analysis, the PWE in ethanol is the best way to fabricate Fe-based alloy nano powder.

• Journal of Pharmaceutical Investigation
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• v.15 no.2
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• pp.45-52
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• 1985

For the model tablets using mannitol and Avicel PH 101 as excipients, the patterns of disintegration and dissolution from the differences of physical properties were investigated. It was found that the patterns in the dissolution and binding forces in the interaction of materials by estimates of solid-solid or liquid surface free energy due to cohesive or adhesive properties of materials, and solid surface free energy in binding forces of tablet should be considered as an important factor in dissolution processes.

• Korean Journal of Materials Research
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• v.19 no.2
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• pp.111-114
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• 2009

For the fabrication of core-shell structure bimetallic lead-free solder balls, both the critical temperature ($T_{cr}$) for the phase separation of two immiscible liquid phases and the temperature coefficient of the interfacial tension between the two separated liquid phases are required. In order to obtain this information, the temperature dependence of the surface tension of 60%Bi-24%Cu-16%Sn(-REM) alloys was measured using the constrained drop method. The slope of the temperature dependence of the surface tension changed clearly at a critical temperature for the separation of two immiscible liquid phases. The critical temperature of the 60%Bi-24%Cu-16%Sn alloy was estimated to be 1097K. An addition of 0.05% Ce decreased the critical temperature to 1085K, whereas that of 0.05% La increased it to 1117K. It was found that the surface tension and its temperature coefficient of the 60%Bi-24%Cu-16%Sn alloy were slightly increased by the addition of 0.05% Ce and 0.05% La. In addition, additions of Ce and La increased the temperature coefficient of the interfacial tension.