• Progress in Superconductivity and Cryogenics
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• v.14 no.2
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• pp.28-31
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• 2012

The study on the dielectric characteristics of gaseous insulation medium is important for designing current leads of superconducting machines using a sub-cooled liquid nitrogen ($LN_2$) cooling method. In a sub-cooled $LN_2$ cooling system, the temperature of gaseous insulation medium surrounding current leads varies from the temperature of coolant to 300 K according to the displacement between the electrode system and the surface of sub-cooled $LN_2$. In this paper, AC withstand voltage experiments on gaseous nitrogen according to temperature are conducted. Also, AC withstand voltage experiments on gaseous nitrogen according to pressure, size of electrode, and gap length between two electrodes are performed. It is found that there is a functional relation between the electrical breakdown voltage and the field utilization factor (${\xi}$). As a result, the empirical formula for estimating an electrical breakdown voltage is deduced by adopting the concept of field utilization factors. It is expected that the experimental results presented in this paper are helpful to design current leads for a high voltage superconducting apparatus such as a superconducting fault current limiter (SFCL) using a sub-cooled $LN_2$ cooling system.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1498-1501
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• 1996

To evaluate insulating properties of polyimide thin film on high temperature over $100\;^{\circ}C$, polyimide film were prepared by electrophoretic deposition onto metal surface from nonaqueous emulsion. The emulsion is made by adding a solution of the resin to a precipitant, which is an organic liquid compeltely miscible with the solvent of the organic resin solution, but which does not dissolve the resin. The polyimide film obtained by annealing shows good insulation properties of 5.8 MV/cm at elevated temperature and breakdown strength of the film reveals thickness dependence.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.941-942
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• 2007

The superconducting fault current limiter (SFCL) consists of superconducting coil for limiting the fault current and cryogenic cooling system for keeping the coil in superconducting condition. The study on the insulation design for superconducting coil and cryogenic cooling system should be elaborately performed to develop a high voltage SFCL. In this paper, insulation design of solenoid coil for 13.2kV/630A SFCL is performed through the AC dielectric breakdown test and lightning impulse dielectric strength test. The dependence of dielectric characteristics on the magnitude of liquid nitrogen pressure is also investigated. Through the investigation, it is verified that dielectric characteristics of sub-cooled nitrogen are strongly enhanced by the pressurization. The electrical insulation design of 13.2kV/630A SFCL is performed by applying the experimental results. The successful insulation design for development of 13.2kV/630A SFCL is confirmed by AC dielectric breakdown tests.

• Progress in Superconductivity and Cryogenics
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• v.9 no.3
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• pp.52-56
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• 2007

A high temperature superconducting (HTS) DC cable is ideal for transmitting large blocks of electrical power over a long distance. However, it must be designed to operate reliably within the constraints of the electrical systems. Therefore, a study of the electrical insulation is important to develop a HTS DC cable because it is operated in a cryogenic high voltage environment. This paper discusses the dielectric constructions of the cable and summarizes the experimental results on the DC and impulse dielectric characteristics of the insulation material. in sheet form and mini-model cable configuration. This shows how to design such insulation to be operated reliably. These studies are essential for the insulation design of a HTS DC cable operated in cryogenic environment.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.17-18
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• 2011

Plasma in liquid phase has attracted great attention in the last few years by the wide domain of applications in material processing, decomposition of organic and inorganic chemical compounds and sterilization of water. The plasma in liquid is characterized by three main regions which interact each - other during the plasma operation: the liquid phase, which supply the plasma gas phase with various chemical compounds and ions, the plasma in the gas phase at atmospheric pressure and the interface between these two regions. The most complex region, but extremely interesting from the fundamental, chemical and physical processes which occur here, is the boundary between the liquid phase and the plasma gas phase. In our laboratory, plasma in liquid which behaves as a glow discharge type, is generated by using a bipolar pulsed power supply, with variable pulse width, in the range of 0.5~10 ${\mu}s$ and 10 to 30 kHz repetition rate. Plasma in water and other different solutions was characterized by electrical and optical measurements. Strong emissions of OH and H radicals dominate the optical spectra. Generally water with 500 ${\mu}S/cm$ conductivity has a breakdown voltage around 2 kV, depending on the pulse width and the repetition rate of the power supply. The characteristics of the plasma initiated in ultrapure water between pairs of different materials used for electrodes (W and Ta) were investigated by the time-resolved optical emission and the broad-band absorption spectroscopy. The deexcitation processes of the reactive species formed in the water plasma depend on the electrode material, but have been independent on the polarity of the applied voltage pulses. Recently, Coherent anti-Stokes Raman Spectroscopy method was employed to investigate the chemistry in the liquid phase and at the interface between the gas and the liquid phases of the solution plasma system. The use of the solution plasma allows rapid fabrication of the metal nanoparticles without being necessary the addition of different reducing agents, because plasma in the liquid phase provides a reaction field with a highly excited energy radicals. We successfully synthesized gold nanoparticles using a glow discharge in aqueous solution. Nanoparticles with an average size of less than 10 nm were obtained using chlorauric acid solutions as the metal source. Carbon/Pt hybrid nanostructures have been obtained by treating carbon balls, synthesized in a CVD chamber, with hexachloro- platinum acid in a solution plasma system. The solution plasma was successfully used to remove the template remained after the mesoporous silica synthesis. Surface functionalization of the carbon structures and the silica surface with different chemical groups and nanoparticles, was also performed by processing these materials in the liquid plasma.

• Korean Journal of Clinical Pharmacy
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• v.16 no.1
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• pp.28-33
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• 2006

The stability of cefditoren in three kinds of oral liquid preparations at 4 and $25^{\circ}C$ was studied for 90 days. Two tablets of 100 mg cefditoren pivoxil were mixed with 200 mL of each oral liquid syrup, which is Pebron syrup (oxolamine citrate 10 mg/mL), $Mucopect^{(R)}$ syrup (ambroxol hydrochloride 3 mg/mL) or $Tyrenol^{(R)}$ suspension (acetaminophen encapsulated 32 mg/mL). Three samples of each formulation were refrigerated $(4^{\circ}C)$ and three were stored at room temperature $(25^{\circ}C)$. At predetermined time, samples were assayed by stability-indicating HPLC method. The chromatographic analysis after deliberate degradation showed no evidence of any breakdown product likely to interfere with the chromatographic peak of the parent substance. The relation between cefditoren pivoxil concentration and peak area was linear from 10 to $150{\mu}g/mL\;(r^2=0.9998)$. The analysis method was precise, with coefficients of variation no greater than 3.6%. Cefditoren was stable in $Mucopect^{(R)}$ syrup up to 4 weeks regardless of the temperature; in $Tyrenol^{(R)}$ suspension and Pebron syrup, it was stable for at least 28 and 45 days, and 7 and 45 days at 25 and $4^{\circ}C$, respectively. The percentages of initial cefditoren concentration remaining after 90 days were $51.5{\pm}1.8\;and\;80.9{\pm}5.6%,\;61.7{\pm}7.8\;and\;70.2{\pm}7.3%,\;and\;39.9{\pm}3.2\;and\;81.4{\pm}5.5%$ in $Mucopect^{(R)}$ syrup, $Tyrenol^{(R)}$ suspension and $Pebron^{(R)}$ syrup at 25 and $4^{\circ}C$, respectively. The pH variations of all test solutions were minimal, which was within 0.5. The results indicated that the stability of cefditoren was significantly affected by liquid solutions mixed with cefditoren, and storage tempertature.

• Progress in Superconductivity
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• v.11 no.1
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• pp.13-18
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• 2009

Partial discharge measurements in cryogenic dielectric materials of HTS transformer are very important because partial discharge was regarded as primary source for ageing and breakdown of cryogenic materials. But, partial discharge measurement techniques and its effects in low temperature high voltage environments were not suggested and there exist only a few reports on this research fields. Therefore, in order to implement reliable HTS transformers, partial discharge diagnosis techniques for cryogenic materials of HTS transformers were investigated using partial discharge (PD) pattern analysis methods. In this works, four different types of artificial defects including turn to turn insulation, free moving particle, void and protrusion, have been fabricated since it was commonly regarded that they might cause the sudden service failures of the power apparatus. For this purpose, these defects are installed into the dielectric materials in liquid nitrogen and experimental investigations have been carried out for the diagnosis of HTS transformer. And various PD patterns caused by the amount of quench of superconductors were analyzed. Throughout this works, the different PD patterns in cryogenic dielectric materials in liquid nitrogen, and PD measuring technique could be the fundamental steps to establish diagnosis technologies of HTS transformer for power applications.

• Progress in Superconductivity and Cryogenics
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• v.13 no.1
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• pp.27-30
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• 2011

A sub-cooled liquid nitrogen cooling system is known as a most promising method to develop large scale superconducting apparatuses such as superconducting fault current limiters and superconducting cables [1]. Gaseous helium (GHe), gaseous nitrogen ($GN_2$) and sulfur hexafluoride ($SF_6$) are commonly used for designing an high voltage applied superconducting device as an injection gaseous medium [2, 3]. In this paper, the analysis on the dielectric characteristics of GHe, $GN_2$ and $SF_6$ are conducted by designing and manufacturing sphere-to-plane electrode systems. The AC withstand voltage experiments on the various gaseous insulation media are carried out and the results are analyzed by using finite element method (FEM) considering field utilization factors (${\xi}$). It is found that the electric field intensity at sparkover ($E_{MAX}$) of insulation media exponentially decreases according to ${\xi}$ increases. Also, the empirical expressions of the functional relations between $E_{MAX}$ and ${\xi}$ of insulation media are deduced by dielectric experiments and computational analyses. It is expected that the electrical insulation design of applied superconducting devices could be performed by using the deduced empirical formulae without dielectric experiments.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.240.2-240.2
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• 2014

Characteristics of pulse-discharged plasma in liquid and its biological applications to proteins are investigated by making use of high voltage Marx generator. The Marx generator has been consisted of 5 stages, where each charging capacitor is $0.5{\mu}F$ to generate a high voltage pulse with rising time of $1{\mu}s$. We have applied an input voltage of 6 kV to the each capacitor of $0.5{\mu}F$. The high voltage pulsed plasma has been generated inside a polycarbonate tube by a single-shot operation, where the breakdown voltage is measured to be 7 kV, current of 1.2 kA, and pulse width of ${\sim}1{\mu}s$ between the two electrodes of anode-cathode made of stainless steel, which are immersed into the liquids. For the investigation of the influence of pulsed plasma on biomolcules, we have focused on the amino acids, DNA, proteins, cell and cholesterol.

• Proceedings of the KIEE Conference
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• 1999.07e
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• pp.2195-2197
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• 1999

Electric breakdown in the liquid produces a spark channel. The energy input into the channel causes expansion of a vapor gas cavity. If the power of the discharge is high enough, this expansion is fast enough to produce a shock wave which propagates through the liquid to the subject of destruction. We focused our attention on the correlation between electric parameters and the characteristics of the flash caused by point to-point electrode discharge in the water. By varying firing voltage and gap length, we obtained the features of the flash : amplitude, pulse width, and so on. In this paper, We have known that there is a concrete interrelation between underwater firing voltage and photodiode output.