• Title/Summary/Keyword: Liquid air

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Wet Chemical Process for Improving Air Quality in Semiconductor Manufacturing Process (반도체 생산공정의 대기질 개선을 위한 복합 대기오염물의 습식화학 제거공정)

  • Jun, Chang-Sung;Kim, Hak-Ju;Park, Young-Moo;Lee, Dae-Won;Ham, Dong-Suk;Jeon, Sang-Moon;Lee, Kwan-Young
    • Clean Technology
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    • v.13 no.2
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    • pp.109-114
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    • 2007
  • In this study, we performed basic researches to develop wet purification system for improving air qualities of ventilation in semiconductor manufacturing process. Using 0.5 M aqueous solution of $KMnO_4$, 50 ppm of $NH_3$, SOx and NOx were reduced to 99% successfully. However, the removal of $O_3$ was limited to $22{\sim}30%$ for all the tested chemical solutionsincluding $KMnO_4$. Therefore, adoption of a dry ozone filter is necessary to reduce $O_3$ below a satisfactory level. For all the chemical solutions tested, NOx removal efficiency increased as NOx was mixed with $O_3$. As chemical solution was sprayed using water spraying system equipped with air atomizing type nozzle, the removal efficiencies of gaseous pollutants increased due to the increase of gas-liquid interfacial area.

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External Condensation Heat Transfer Coefficients of R22 Alternative Refrigerants and R134a According to the Saturated Vapor Temperature Change on an Enhanced Tube (열전달 촉진관에서 R22 대체냉매 및 R134a의 포화증기 온도변화에 따른 외부 응축 열전달계수에 관한 연구)

  • Yoo Gil-Sang;Hwang Ji-Hwan;Park Ki-Jung;Jung Dongsoo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.11
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    • pp.981-989
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    • 2005
  • In this study, external condensation heat transfer coefficients (HTCs) are measured on a low fin tube and Turbo-C tubes at the saturated vapor temperature of $30^{\circ}C$, $39^{\circ}C$, and $50^{\circ}C$ for R22, R410A, R407C and R134a with the wall subcooled at $3{\~}8^{\circ}C$. The HTCs of all refrigerants decreased as increasing the saturation temperature from $30^{\circ}C$ to $50^{\circ}C$. This trend is due to better thermodynamic properties of the liquid phase at low temperature Beatty and Katz's prediction yielded a $20.0\%$ deviation for the low fin tube data. The heat transfer enhancement factors for the 26 fpi low fin tube and Turbo-C tubes are 4.0${\~}$5.5 and 3.0${\~}$8.1 respectively for the refrigerants tested. Finally the performance of Turbo-C tube is better than that of the low fin tube.

Fabrication of Hierarchical Nanostructures Using Vacuum Cluster System

  • Lee, Jun-Young;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.389-390
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    • 2012
  • In this study, we fabricate a superhydrophobic surface made of hierarchical nanostructures that combine wax crystalline structure with moth-eye structure using vacuum cluster system and measure their hydrophobicity and durability. Since the lotus effect was found, much work has been done on studying self-cleaning surface for decades. The surface of lotus leaf consists of multi-level layers of micro scale papillose epidermal cells and epicuticular wax crystalloids [1]. This hierarchical structure has superhydrophobic property because the sufficiently rough surface allows air pockets to form easily below the liquid, the so-called Cassie state, so that the relatively small area of water/solid interface makes the energetic cost associated with corresponding water/air interfaces smaller than the energy gained [2]. Various nanostructures have been reported for fabricating the self-cleaning surface but in general, they have the problem of low durability. More than two nanostructures on a surface can be integrated together to increase hydrophobicity and durability of the surface as in the lotus leaf [3,5]. As one of the bio-inspired nanostructures, we introduce a hierarchical nanostructure fabricated with a high vacuum cluster system. A hierarchical nanostructure is a combination of moth-eye structure with an average pitch of 300 nm and height of 700 nm, and the wax crystalline structure with an average width and height of 200 nm. The moth-eye structure is fabricated with deep reactive ion etching (DRIE) process. $SiO_2$ layer is initially deposited on a glass substrate using PECVD in the cluster system. Then, Au seed layer is deposited for a few second using DC sputtering process to provide stochastic mask for etching the underlying $SiO_2$ layer with ICP-RIE so that moth-eye structure can be fabricated. Additionally, n-hexatriacontane paraffin wax ($C_{36}H_{74}$) is deposited on the moth-eye structure in a thermal evaporator and self-recrystallized at $40^{\circ}C$ for 4h [4]. All of steps are conducted utilizing vacuum cluster system to minimize the contamination. The water contact angles are measured by tensiometer. The morphology of the surface is characterized using SEM and AFM and the reflectance is measured by spectrophotometer.

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Measurements of Polycyclic Aromatic Hydrocarbons(PAHs) Concentration in Air of the Seoul Underground Shopping Stores (서울시 지하상가 공기중 다환방향족 탄화수소의 농도조사에 관한 연구)

  • 전준민;김윤신
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.1
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    • pp.81-92
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    • 1993
  • A purpose of this study was carried out to investigate the concentrations of four elements of PAHs(Polycyclic Aromatic Hydrocarbons) in suspended particulate matters of underground shopping stores in Seoul city. The particulate matters were collected at five underground shopping stores(Yongdungpo, Myongdong, Ulchiro, Express Terminal, Chamshil) in the Seoul area during February-October, 1992. Samples were collected using cascade impactor of low volumn air sampler and were analysed using High Performance Liquid Chromatography(HPLC) with fluorescence detector. Calibration on HPLC analyse is nearly accord with retention time between the standard solution and the samples. Analysed results obtained favorable analysing recovery rate of 97.3% and coefficient of variation of 1.60%. Mean concentrations of suspended particulate matters in five underground shopping stores wre 216.3 g/$m^3$ and observed higher at fine particles(117.2 g/$m^3$) which is respirable particulates than coarse particles(99.2 g/$m^3$). Concentrations of four species PAH were determined with anthracene of 16.8ng/$m^3$, fluoranthene of 72.3ng/$m^3$, benzo(a)pyrene of 0.54ng/$m^3$, and benzo(k)fluoranthene of 0.29ng/$m^3$, respectively. Fluoranthene levels were significantly higher than those levels in other components. PAHs concen-tration at shopping areas showed 21.3ng/$m^3$ in Yongdungpo, 35.1ng/$m^3$ in Myongdong, 23.4ng/$m^3$ in Ulchiro, 11.1ng/$m^3$ in Express Terminal, and 21.4ng/$m^3$ in Chamshil, respectively. Particularly, benzo(a)pyrene and benzo(k)-fluoranthene were detected over 83 percentage in fine particles, while fluoranthene wre highly detected in coarse particles. Also, higher concentrations of benzo(a)pyrene, benzo(k)fluoranthene were found in winter while levels of anthracene and fluoranthene were found higher in summer than other seasons.

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Study on the Atomization Characteristics of a Counter-swirling Two-phase Atomizer with Variations of Swirl angle (역선회 이류체 미립화기의 선회각 변화에 따른 미립화 특성연구)

  • Kim, N.H.;Lee, S.G.;Ha, M.H.;Rho, B.J.;Kang, S.J.
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.125-130
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    • 2001
  • Experimental and analytical researches have been conducted on the twin-fluid atomizers for better droplet breakup during the past decades. But, the studies on the disintegration mechanism still present a great challenge to understand the drop behavior and breakup structure. In an effort to describe the aerodynamic behavior of the sprays issuing from the internal mixing counter-swirling nozzle, the spatial distribution of axial (U) radial (V) and tangential (W) components of droplet velocities are investigated across the radial distance at several axial locations of Z=30, 50, 80, 120 and 170mm, respectively. Experiments were conducted for the liquid flow rates which was kept constant at 7.95 g/s and the air injection pressures were varied from 20 kPa to 140 kPa. Counter-swirling internal mixing nozzles manufactured at angles of $15^{\circ},\;30^{\circ},\;45^{\circ}$ and $60^{\circ}$ the central axis with axi-symmetric tangential-drilled holes was considered. The distributions of velocities and turbulence intensities are comparatively analyzed. PDPA is installed to specify spray flows, which have been conducted along the axial downstream distance from the nozzle exit. Ten thousand of sampling data was collected at each point with time limits of 30 second. 3-D automatic traversing system is used to control the exact measurement. It is observed that the sprays with all swirl angle have the maximum SMD for on air injection pressure of 20 kPa and 140 kPa with centerline, respectively. The nozzle with swirl angle of $60^{\circ}$ has vest performance.

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Flow Condensation Heat Transfer Coefficients of R22, R410A and Propane in Aluminum Multi-Channel Tube (알루미늄 다채널 평판관내 R22, R410A, Propane의 흐름 응축 열전달 성능 비교)

  • Park Ki-Jung;Lee Ki-Young;Jung Dongsoo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.7
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    • pp.649-658
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    • 2005
  • Flow condensation heat transfer coefficients (HTCs) of R22, R410, Propane (R290) were measured inside a horizontal 9 hole aluminum multi-channel flat tube. The main test section in the refrigerant loop was made of a 0.53m long multi-channel flat tube of hydraulic diameter of 1.4 mm. Refrigerant was cooled by passing cold water through an annulus surrounding the test section. Data were obtained in qualities of $0.1\~0.9$ at mass flux of $200\~400kg/m^2s$ and heat flux of $7.3\~7.7kW/m^2$ at the saturation temperature of $40^{\circ}C$. All popular heat transfer correlations in single-phase subcooled liquid flow and flow condensation originally developed for large single tubes predicted the present data of the multi channel flat tube within $25\%$ deviation when effective heat transfer area was used in determining experimental data. This suggests that there is little change in flow characteristics and patterns when the tube diameter is reduced down to 1.4 mm diameter range. Hence, a modified correlation based on the present data was proposed which could be applied to small diameter tubes with effective heat transfer area. The correlation showed a mean deviation of less than $20\%$ for all data.

Induction of Hariy Root and Bioreactor Culture of Lycium chinense (구기자나무 (Lycium chinense)의 모상근 유도 및 생물반응기 배양)

  • Bae, Ki-Hwa;Kim, Yun-Soo;Jeong, Jae-Hun;Kim, Young-Seon;Choi, Yong-Eui;Yoon, Eui-Soo
    • Journal of Plant Biotechnology
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    • v.31 no.4
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    • pp.295-300
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    • 2004
  • This article was conducted to induce the transgenic hairy roots and determine the effect of culture conditions on optimum growth of hairy roots by Agrobacterium rhizogenes strain, 15834 in Lycium chinense Miller. Hairy roots of L. chinense Miller. were induced from leaf segments by co-cultivation with A. rhizogenes. When the hairy roots were cultured in various MS medium strength and sucrose concentrations, the highest growth of hairy roots was observed in half-strength MS media supplemented with 3% sucrose, respectively. In air lift bioreactor cultures, the liquid medium contained with 1/2 MS and 3% sucrose was also the best for optimum growth of hairy roots.

Distribution of Radon Concentration at Subway Station in Seoul (서울시 지하철역사의 라돈농도분포 조사)

  • Lee Cheol-Min;Kim Yoon-Shin;Kim Jong-Cheol;Jeon Hyung-Jin
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.469-480
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    • 2004
  • The radon concentrations were measured to survey distribution of radon concentrations in Seoul subway stations. The radon concentrations in air and water were measured at seventeen subway stations(Mapo, Chungjongno, Sodaemun, Kwanghwamun, Chongno3ga, Ulchiro4ga, Tangdaemun, Sangildong on Line 5;Nowon, Chunggye, Hagye, Kongnung, Taenung, Mokkol, Chunghwa, Sangbong, Myomok on Line 7) using the $RAdtrak^{TM}$ radon gas detector, Pylon AB-5 continuous passive radon detector and liquid scintillation counting method from January to May 1999. The major results obtained from this study were as follows: The long-term mean concentrations of radon were $61.8\;Bq/m^3$ in office, $78.9\;Bq/m^3$ in platform, $38.2\;Bq/m^3$ in concourse and $20.1\;Bq/m^3$ in outdoor, respectively. These levels were less than the action level ($148\;Bq/m^3$) of the U.S. EPA. The highest level of short-term mean concentrations was $116.55\;Bq/m^3$ at Chongno3ga station on the 5th line subway stations, while the lowest mean concentration was $19.55\;Bq/m^3$ at Mokkol station on the 7th line subway stations. The highest concentration of radon in the road water and storing underground water in the subway stations was $234.7\;KBq/m^3\;and\;155.5\;KBq/m^3$ in Sodaemun subway station, respectively. The results suggest that radon concentration in subway stations seems to be affected by ventilation and radon concentratin in underground water in the subway stations.

Injectable Gel Type Formulation of Hydrated Egg Phosphatidylcholine and Hyaluronate for Local Drug Delivery

  • Kim, Sang-Gyun;Chung, Hesson;Lee, In-Hyun;Kang, Seung-Back;Kwon, Ick-Chan;Sung, Ha-Chin;Jeong, Seo-Young
    • Journal of Pharmaceutical Investigation
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    • v.32 no.3
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    • pp.165-172
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    • 2002
  • Injectable gel composed of egg phosphatidylcholine (egg PC), hyaluronate (HA) and water was formulated for local drug delivery. The lamellar liquid crystalline structure of the egg PC/water system did not change by adding HA in the formulation. However, egg PC/HA/water gel was more resistant to erosion than the egg PC/water gel. The egg PC/HA/water and egg PC/water gels containing model drugs, tetracycline and sudan IV were prepared to perform in vitro and in vivo drug release experiments. In vitro release of tetracycline was sustained in the gel type formulations. The release rate of hydrophobic sudan IV was extremely slow. More than 99% of sudan IV remained inside the gel after 5 days. In vivo release of drugs from the air pouch model in Balb/c mice shows that lipophilic sudan IV remained for more than 10 days whereas tetracycline remained for 1 day in the pouch. The compatibility of the gels was also examined by histopathology. The gels did not cause any adverse inflammatory effect in the air pouch.

Development and Performance Tests of the Waste Water Diffusers using Acoustic Resonance and Oscillatory Pulsation (음향공진과 맥진동 현상을 이용한 폐수처리용 산기관 개발 및 성능시험)

  • Hong, Suk-Yoon;Moon, Jong-Duck
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.6
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    • pp.52-58
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    • 1996
  • Using the acoustic resonances and oscillatory pulsations considered as the branch of wave technologies, the concept of the acoustic resonance diffusers for waste water treatment which maximize the oxygen transfer efficiency in gas-liquid two phase medium have been proposed, and studies for the principles and performance tests were accomplished. Besides, the design concepts for the low pressure Helmholtz resonator, cylinder and annular type reflection resonator and combined type resonance system have been implemented. The acoustic resonance energy which can speed up the mass transfer process increase the oxygen transfer efficiency, and periodic pulsations generated from the instability of air jet from nozzle make very small air bubbles. Then, the annular type jet resonator(AJR) applying these two principles successfully was evalulated as the most promising device and also the efficiency showing $20{\sim}30%$ better than conventional diffusers has been verified experimentally.

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