• Title/Summary/Keyword: Liquid Liquid Extraction

Search Result 1,075, Processing Time 0.03 seconds

Effect of Experimental Factors on Reduction of Nitrogen Compounds Contained in Crude Methylnaphthalene Oil by Formamide Extraction (포름아미드 추출에 의한 조제 메틸나프탈렌유에 함유된 질소화합물의 저감에 관한 실험인자의 영향)

  • Su Jin Kim
    • Applied Chemistry for Engineering
    • /
    • v.34 no.6
    • /
    • pp.665-669
    • /
    • 2023
  • The crude methylnaphthalene oil (CMNO) contains nitrogen compounds (NCs) such as quinoline (QU), isoquinoline (IQU), and indole (IN). These NCs in the CMNO are treated as impurities contained in the CMNO due to contamination of the atmospheric environment and unpleasant odors. In order to improve the quality of CMNO, this study examined the effect of extraction experimental factors on the reduction of NCs contained in CMNO using CMNO as a raw material and an aqueous formamide solution as a solvent, respectively. The increase in the volume ratio of solvent to feed in initial (S/F)0 in initial increased the distribution coefficient of NCs and the selectivity of NCs in reference to 2-methylnaphthalene (2MNA). Additionally, an increase in operating temperature (T) increased the distribution coefficient of NCs but conversely decreased selectivity. The compositions of QU, IQU, and IN in the raffinate oil recovered through equilibrium extraction under a constant condition (volume fraction of water to solvent in initial (yw,0) = 0.1, (S/F)0 = 9, T = 303 K, liquid-liquid contacting time = 72 h) were reduced by about 58.5 wt%, 61.9 wt%, and 73.4 wt%, respectively, compared to those of CMNO. The formamide extraction method in this study was expected to be an effective reduction method for NCs contained in CMNO.

Determination of Ursodeoxycholic Acid in Crude Drug Formulations by HPLC and SPE Using Selective Pre-column Derivatization with 2-Bromoacetyl-6-methoxynaphthalene (2-Bromoacetyl-6-methoxynaphthalene을 형광유도체화제로 HPLC와 SPE를 이용한 생약제제 중 Ursodeoxycholic acid의 정량)

  • 진창화;임수희;이기진;심형섭;조의환;염정록
    • YAKHAK HOEJI
    • /
    • v.46 no.6
    • /
    • pp.392-397
    • /
    • 2002
  • A simple and sensitive high performance liquid chromatographic method to quantitate ursodeoxycholic acid in crude drug pharmaceuticals was investigated. Ursodeoxycholic acid react with 2-bromoacetyl-6-methoxynaphthalene (Br-AMN) in the presence of triethylamine to form highly fluorescent derivative. The derivatization procedure was performed at 7$0^{\circ}C$ and completed within 30 min. The optimal wavelength of the fluorescence detector are λ$_{ex}$=300 nm and λ$_{em}$ = 460 nm. The LOD of the ursodeoxycholic acid was 25 ng/mι based on the S/N =3, and the LOQ was 80 ng/mι based on S/N = 10. Crude drug pharmaceuticals pretreated by solid phase extraction (Sep-pak $C_{18}$ cartridge) which were shown very good separation and recovery values for the compound.d.

A Study on the Relief of Shell Wall Thinning of Low Pressure Type Feedwater Heater Around the Extraction Nozzle Identified (저압형 급수가열기 추기노즐에서 동체 감육 완화에 관한 연구)

  • Kim, Kyung-Hoon;Hwang, Kyeong-Mo;Seo, Hyuk-Ki
    • Journal of ILASS-Korea
    • /
    • v.13 no.4
    • /
    • pp.173-179
    • /
    • 2008
  • The current machinery and tools of secondary channel of the nuclear power plants were produced in the carbon-steel and low-alloy steel. What produced with the carbon-steel occurs wall thinning effect from flow accelerated corrosion by the fluid flow at high temperature, high pressure. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed. Wall thinning by flow accelerated corrosion occurs piping system, the heat exchanger, steam condenser and feedwater heaters etc,. Feedwater heaters of many nuclear power plants have recently experienced sever wall thinning damage, which will increase as operating time progress. This study describes the comparisons between the numerical results using the FLUENT code and experimental data of down scale model.

  • PDF

Evaluation of Remediation of Contaminated Soil Using PVDs (연직배수재를 이용한 오염도턍복원 특성 평가)

  • Shin, Eun-Chul;Park, Jeong-Jun;Roh, Jeong-Min
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2005.03a
    • /
    • pp.1400-1407
    • /
    • 2005
  • There are a number of approaches to in situ remediation that are used at contaminated sites for removing contaminants from the contaminated zone without excavating the soil. These include soil flushing, dual phase extraction, and soil vapor extraction. Of these techniques, soil flushing is the focus of the investigation in this paper. The concept of using prefabricated vertical drains(PVDs) for remediation of contaminated sites with fine-grained soils is examined. The PVD system is used to shorten the drainage path or the groundwater flow and promote subsurface liquid movement expediting the soil flushing process. The use of PVDs in the current state of practice has been limited to soil improvement. The use of PVDs under vacuum conditions is investigated using sample soil consisting of silty sand.

  • PDF

Effect of Extraction Temperature and Ethanol Concentration on Nitrogeneous Constituents of Red Ginseng Extract (추출조건이 홍삼엑기스의 질소화합물 조성에 미치는 영향)

  • Seong, Hyeong-Sun;Kim, U-Jeong;Yang, Cha-Beom
    • Journal of Ginseng Research
    • /
    • v.9 no.1
    • /
    • pp.95-103
    • /
    • 1985
  • The concentrated red ginseng extract (RG-EXT) was prepared by extracting the ginseng tails with 0-90% ethanol solution at 70-100$^{\circ}C$ and analyzed for amino acids composition and other nitrogeneous fractions. The results showed that nonprotein fraction was more than 90% of the total N-compounds and 17 free amino acids were identified by High Performance Liquid Chromatography. Maximum and minimum N-compounds or total free amino acids were recovered in RG-EXT with 50% and 90% ethanol, respectively. An increase in ethanol concentration resulted a significant change in free amino acid composition while extraction temperature caused a little gradual decrease in water soluble nonprotein and total nitrogen fractions.

  • PDF

Overview on Ionic Liquid Application Technologies for Back-end Fuel Cycle Processes (핵주기 공정에서의 이온성 액체 활용 기술 개요)

  • Kim, Ki-Sub;Park, Byung Heung
    • Journal of Institute of Convergence Technology
    • /
    • v.3 no.2
    • /
    • pp.1-6
    • /
    • 2013
  • The ionic liquids are known to potential alternative solvents capable of replacing the commercial solvents in various processes including those in nuclear fuel cycle. As to the material, a number of studies have already reviewed the interesting results and addressed the spectroscopic as well as electrochemical behaviors of metal elements included in spent nuclear fuels. It has found that the important properties of metal ions in TBP dissolved ILs have led the development of alternative technologies to traditional solvent extraction processes. On the other hand, the electrochemical deposition of metal ions in ILs have been investigated for the application of the solvents to aqueous as well as to non-aqueous processes. In this work, a review on the application of ILs in nuclear fuel cycle is briefly presented to understand the notable researches on ILs focusing on aqueous processes.

  • PDF

Development of New Edible Pigments using Monascus spp.

  • Cho, Gyu-Seong;Kim, Kwangwook;Park, Won-Jong
    • The Korean Journal of Food And Nutrition
    • /
    • v.32 no.1
    • /
    • pp.41-49
    • /
    • 2019
  • Carotene, xanthophyll, carotenoid anthocyan, phycopyrine, chlorophyll, and monascus pigments are used as natural coloring agents since they are more stable to human body than synthetic coloring agents. Among them, monascus pigments are a natural red pigment produced by the Monascus purpureus. For the development of edible paint using natural pigment, Monascus purpureus strain was cultured at a temperature of $35^{\circ}C$ for 15 days on a PDYA plate and liquid medium to produce a red pigment. In addition, a large amount of the red pigment was extracted from Hongkuk Koji in parallel with water extraction and ultrasonic wave extraction. At this time, the yield of ultrasonic extract was 2~4 times higher. Thus, Monascus purpureus strains, etc. were prepared by freeze-drying powder. In conclusion, natural paints made with red pigments have enabled the development of been edible paints that can be used as eco-friendly materials with good viscosity, enhanced spread ability and coloration.

Additional power conservation in 200W power plant with the application of high thermal profiled cooling liquid & improved deep learning based maximum power point tracking algorithm

  • Raj G. Chauhan;Saurabh K. Rajput;Himmat Singh
    • Advances in Energy Research
    • /
    • v.8 no.3
    • /
    • pp.185-202
    • /
    • 2022
  • This research work focuses to design and simulate a 200W solar power system with electrical power conservation scheme as well as thermal power conservation modeling to improve power extraction from solar power plant. Many researchers have been already designed and developed different methods to extract maximum power while there were very researches are available on improving solar power thermally and mechanically. Thermal parameters are also important while discussing about maximizing power extraction of any power plant. A specific type of coolant which have very high boiling point is proposed to be use at the bottom surface of solar panel to reduce the temperature of panel in summer. A comparison between different maximum power point tracking (MPPT) technique and proposed MPPT technique is performed. Using this proposed Thermo-electrical MPPT (TE-MPPT) with Deep Learning Algorithm model 40% power is conserved as compared to traditional solar power system models.

Extraction of Caffeic Acid and Rosmarinic Acid from Zostera marina Based on Ionic Liquids and Deep Eutectic Solvent (이온성액체와 Deep Eutectic Solvent를 사용한 잘피에서 카페인산과 로즈마리산의 추출)

  • Lee, Yu Ri;Lee, Yu Jin;Row, Kyung Ho
    • Korean Chemical Engineering Research
    • /
    • v.52 no.4
    • /
    • pp.481-485
    • /
    • 2014
  • The applicability of the dipping, ultrasonic-assisted, heating methods to the extraction of useful components from Zostera marina was investigated. For the increase of the extraction yield of caffeic acid and rosmarinic acid from Zostera marina, ionic liquids and DES were used as additives in the extraction solvent. The optimum extraction conditions were found: dipping extraction, methanol as extraction solvent, 0.005 g of freeze-dried material powder, 5 mL methanol, 30 min and 0.5 g of DES-3 ($Et_4NCl$ and phenol) as additive. As a result, 0.19 mg/g of caffeic acid and 8.48 mg/g of rosmarinic acid were obtained. This method is simple and sensitive, and has been applied successfully to determine the component of caffeic acid and rosmarinic acid in Zostera marina and these results indicate that DES were used as additives is more suitable than traditional extraction for the extraction of useful components from Zostera marina.

Comparison of Liquefying Efficiency of Mixed Organic Fertilizer as Affected by Aeration Time and the Ratio of Organic Fertilizer to Water (폭기시간과 유기질비료 농도에 따른 혼합유기질비료의 액비화 특성비교)

  • Lee, Jong-Tae;Ha, In-Jong;Moon, Jin-Seong;Song, Won-Doo
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.40 no.2
    • /
    • pp.156-163
    • /
    • 2007
  • This study was conducted to evaluate the liquefying efficiency of mixed organic fertilizer in different conditions. The organic fertilizer was composed of sesame oil cake, rice bran, fish meal, ground bone meal etc, and made by fermenting process. It included $23g\;kg^{-1}$, $17.0g\;kg^{-1}$, $23.9g\;kg^{-1}$, $290g\;kg^{-1}$ of N, $P_2O_5$, $K_2O$, organic matter, respectively. In one test, the mixed organic fertilizer was added in the proportion of 10% to water 90% and aerated continuously, for 2, 8 hours per day, and not aerated as control. In the other test, ratios of organic fertilizer to water were 5%, 10%, 20% and aerated for 2 hours a day. With the increase of liquefying time, pH, EC and $NH_4-N$ increased without relation to aeration time. After 10 days, liquid organic fertilizer aerated for 2 hours a day contained $634mg\;N\;kg^{-1}$, $68.1mg\;P_2O_5\;kg^{-1}$, $453mg\;K_2O\;kg^{-1}$, which was not significantly different from 8 hours a day or continuous aeration. Then extraction ratios of inorganic contents were 27.6%, 4.0% and 18.9%, respectively. Continuous aeration resulted in increasing the viable number of aerobic bacteria, spore forming bacteria and fungi in liquefied solution. Higher ratio of organic fertilizer to water increased EC, $NH_4-N$ and other inorganic matter contents, but decreased extraction ratio of nutrients in liquid fertilizer. The liquid organic fertilizer of 20% contained $1,140mg\;N\;kg^{-1}$, $35.4mg\;P_2O_5\;kg^{-1}$, $544mg\;K_2O\;kg^{-1}$ after 10 days. Then extraction ratios were 24.8%, 2.4% and 13.6%, respectively. The ratio of organic fertilizer to water was positively correlated with only spore forming bacteria, Pseudomonas spp. among microorganisms.