• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.653-660
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• 2022

In liquid hydrogen storage tanks, tank damage or leakage in the surrounding pipes possess a major risk. Since these tanks store huge amounts of the fluid among all the liquid hydrogen process facilities, there is a high risk of leakage-related accidents. Therefore, in this study, we conducted a risk assessment of liquid hydrogen leakage for a grid-type liquid hydrogen storage tank (lattice-type pressure vessel (LPV): 18 m³) that overcame the low space efficiency of the existing pressure vessel shape. Through a commercially developed three-dimensional computational fluid dynamics program, the geometry of the site, where the liquid hydrogen storage tank will be installed, was obtained and simulations of the leakage scenarios for each situation were performed. From the computational flow analysis results, the pool formation behavior in the event of liquid hydrogen leakage was identified, and the resulting damage range was predicted.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.6
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• pp.565-572
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• 2021

Hydrogen is currently produced from natural gas reforming or industrial process of by-product over than 90%. Additionally, there are green hydrogens based on renewable energy generation, but the import of green hydrogen from other countries is being considered due to the output variability depending on the weather and climate. Due to low density of hydrogen, it is difficult to storage and import hydrogen of large capacity. For improving low density issue of hydrogen, the gaseous hydrogen is liquefied and stored in cryogenic tank. Density of hydrogen increase from 0.081 kg/m³ to 71 kg/m3 when gaseous hydrogen transfer to liquid hydrogen. Density of liquid hydrogen is higher about 800 times than gaseous. However, since density and boiling point of liquid hydrogen is too lower than liquefied natural gas approximately 1/6 and 90 K, to store liquid hydrogen for long-term is very difficult too. To overcome this weakness, this paper introduces storage method of hydrogen based on liquid/solid (slush) and facilities for producing slush hydrogen to improve low density issue of hydrogen. Slush hydrogen is higher density and heat capacity than liquid hydrogen, can be expected to improve these issues.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.2
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• pp.47-59
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• 2022

Liquid hydrogen/liquid oxygen rocket engines with highest specific impulse have been developed since the 1950s and used until now to maximize the capability of space launch vehicles. Domestic liquid hydrogen infrastructures for the production, transportation and distribution are being expanded at world-class level with the rise of hydrogen economy, which is a great opportunity for the performance enhancement for indigenous space launch vehicles. In this paper, feasibility of applying liquid hydrogen as a propellant is investigated in various aspects. The status of domestic liquid hydrogen infrastructure, the technologies required for liquid hydrogen engines, and operational aspects for safe handling of hydrogen are reviewed. In addition, test facilities for developing hydrogen engines are introduced briefly.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.4
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• pp.293-300
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• 2022

The Changwon city which announced 2040 hydrogen policy vision is planning to establish the new hydrogen-centered city. The building of plant which is available to produce the 5 ton/day of liquid hydrogen is promoted as one of the projects in order to achieve the vision. However, the analysis in terms of local economic and environmental aspects is insufficient because this liquid hydrogen plant is the first in Korea. Therefore, in this study, the financial feasibility of the liquid hydrogen plant project was analyzed by reviewing the benefits of liquid hydrogen supply and environmental improvement, and the feasibility of this project has been investigated which is being built based on the hydrogen industrial plan of Changwon city.

• Transactions of the Korean hydrogen and new energy society
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• v.35 no.1
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• pp.34-39
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• 2024

Korea government is trying to supply liquid hydrogen from another country to domestic The research for liquid hydrogen transportation and liquefaction plant of hydrogen underway for several years, and empirical research is also planned in the future. Along with the development of liquid hydrogen transport ship/liquefaction plant technology, the development of liquid hydrogen reception base technology must be carried out. In this study, a concept level liquid hydrogen receiving terminal is constructed based on the process of the LNG receiving terminal. Based on this, a study is conducted on the development of analysis technology for the amount of BOG (pipe, tank) generated during cooldown and unloading in the liquid hydrogen unloading line (loading arm to storage tank). The research results are intended to be used as basic data for the design and liquid hydrogen receiving terminal in the future.

• Journal of Information Display
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• v.2 no.3
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• pp.18-31
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• 2001

We utilize Fourier transform infrared (IR) spectroscopy to probe intramolecular hydrogen bonding in $smectic-C^{\ast}$ liquid crystal phases. Infrared spectra of aligned smectic liquid crystal materials vs. temperature and of isotropic liquid crystal mixtures vs. concentration were measured in homologs, both with and without hydrogen bonding. Hydrogen bonding significantly changes the direction and magnitude of the vibrational dipole transition moments, causing marked changes in the IR dichroic absorbance profiles of hydrogen bonded molecular subfragments. A GAUSSIAN94 computation of the directions, magnitudes, and frequencies of the vibrational dipole moments of molecular subfragments shows good agreement with the experimental data. The results show that IR dichroism can be an effective probe of hydrogen bonding in liquid crystal phases.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.607-615
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• 2022

In this study, economic analysis program was developed for economic evaluation of hydrogen production, storage/delivery, and utilization technologies as well as overseas import of hydrogen. Economic analysis program can be used for the estimation of the levelized cost of hydrogen for hydrogen supply chain technologies. This program include five hydrogen production technology on steam methane reforming and water electrolysis, two hydrogen storage technologies (high compressed gas and liquid hydrogen storage), three hydrogen delivery technologies (compressed gas delivery using tube trailer, liquid hydrogen, and pipeline transportation) and six hydrogen utilization technologies on hydrogen refueling station and stationary fuel cell system. In the case of overseas import hydrogen, it was considered to be imported from five countries (Austraila, Chile, India, Morocco, and UAE), and the transportation methods was based on liquid hydrogen, ammonia, and liquid organic hydrogen carrier. Economic analysis program that was developed in this study can be expected to utilize for planning a detailed implementation methods and hydrogen supply strategies for the hydrogen economy road map of government.

• Journal of Aerospace System Engineering
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• v.18 no.3
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• pp.8-16
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• 2024

Because hydrogen has very low density, a different storage method is required to store the same amount of energy as fossil fuel. One way to increase the density of hydrogen is through liquefaction. However, since the liquefied temperature of hydrogen is extremely low at -252 ℃, it is easily vaporized by external heat input. When liquid hydrogen is vaporized, a self-pressurizing phenomenon occurs in which the pressure inside the hydrogen tank increases, so when designing the tank, this rising pressure must be carefully predicted. Therefore, in this paper, the internal pressure of a cryogenic liquid fuel tank was predicted according to the liquid hydrogen filling ratio. A one-dimensional thermodynamic model was applied to predict the pressure rise inside the tank. The thermodynamic model considered heat transfer, vaporization of liquid hydrogen, and fuel discharging. Finally, it was confirmed that there was a significant difference in pressure behavior and maximum rise pressure depending on the filling ratio of liquid hydrogen in the fuel tank.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.3
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• pp.234-240
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• 2015

In the face of the world's growing energy storage needs, liquid hydrogen offers a high energy density solution for the storage and transport of energy throughout society. A 5 L liquid hydrogen storage tank has been designed, fabricated and tested to investigate boil-off rate of liquid hydrogen. As the insulation plays a key role on the cryogenic vessels, various insulation methods have been employed. To reduce heat conduction loss, the epoxy resin-based insulation supports G-10 were used. To minimize radiation heat loss, vapor cooled radiation shield, multi-layer insulation, and high vacuum were adopted. Mass flow meter was used to measure boil-off rate of the 5 L cryogenic vessel. A series of performance tests were done for liquid nitrogen and liquid hydrogen to compare with design parameters, resulting in the boil-off rate of 1.7%/day for liquid nitrogen and 16.8%/day for liquid hydrogen at maximum.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.6
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• pp.490-498
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• 2019

The intermittent electric power supply of renewable energy can have extremely negative effect on power grid, so long-term and large-scale storage for energy released from renewable energy source is required for ensuring a stable supply of electric power. Power to gas which can convert and store the surplus electric power as hydrogen through water electrolysis is being actively studied in response to increasing supply of renewable energy. In this paper, we proposed the novel concept of hydrogen liquefaction process combined with pre-cooling process using the liquid air. It is that hydrogen converted from surplus electric power of renewable energy was liquefied through the hydrogen liquefaction process and vaporization heat of liquid hydrogen was conversely recovered to liquid air from ambient air. Moreover, Comparisons of specific energy consumption (kWh/kg) saved for using the liquid air pre-cooling was quantitatively conducted through the performance analysis. Consequently, about 12% of specific energy consumption of hydrogen liquefaction process was reduced with introducing liquid air for pre-cooling and optimal design point of helium Brayton cycle was identified by sensitivity analysis on change of compression/expansion ratio.