• Title/Summary/Keyword: Limited of stability

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Improving Electrochemical Performance of Ni-rich Cathode Using Atomic Layer Deposition with Particle by Particle Coating Method

  • Kim, Dong Wook;Park, DaSom;Ko, Chang Hyun;Shin, Kwangsoo;Lee, Yun-Sung
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.237-245
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    • 2021
  • Atomic layer deposition (ALD) enhances the stability of cathode materials via surface modification. Previous studies have demonstrated that an Ni-rich cathode, such as LiNi0.8Co0.1Mn0.1O2, is a promising candidate owing to its high capacity, but is limited by poor cycle stability. In this study, to enhance the stability of the Ni-rich cathode, synthesized LiNi0.8Co0.1Mn0.1O2 was coated with Al2O3 using ALD. Thus, the surface-modified cathode exhibited enhanced stability by protecting the interface from Ni-O formation during the cycling process. The coated LiNi0.8Co0.1Mn0.1O2 exhibited a capacity of 176 mAh g-1 at 1 C and retained up to 72% of the initial capacity after 100 cycles within a range of 2.8-4.3 V (vs Li/Li+. In contrast, pristine LiNi0.8Co0.1Mn0.1O2 presented only 58% of capacity retention after 100 cycles with an initial capacity of 173 mAh g-1. Improved cyclability may be a result of the ALD coating, which physically protects the electrode by modifying the interface, and prevents degradation by resisting side reactions that result in capacity decay. The electrochemical impedance spectra and structural and morphological analysis performed using electron microscopy and X-ray techniques establish the surface enhancement resulting from the aforementioned strategy.

Coordinated Control Modeling and Simulation among the Voltage Compensation Equipments Using Python (Python을 이용한 전압보상설비의 상호 협조제어 모델링 및 시뮬레이션)

  • Lee, Sang-Deok;Baek, Young-Sik;Seo, Gyu-Seok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.1
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    • pp.1-8
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    • 2010
  • The ultrafashionable machinery that require high quality electricity power has been daily come into being. Because domestic power system has been larger and more complicated in accordance with raising power demand by power market requirement. Because of these power market situations, The FACTS (Flexible AC Transmission System) which is power transmission system for the next generation to meet flexible supply the power and reliability has been applied. If they, compensators and FACTS, are used inter-efficiently in range that does not affect the stability and a badly influence the security, they might be increase in the voltage stability of system, supply reliability and also achieve the voltage control in a suddenly changed power system. Therefore we describe and suggest on this treatise that a plan for coordination control between UPFC, Shunt elements (Sh. Capacitors & Sh. Reactors) among compensators and also describe the method to keep or control the voltage of power system in allowable ranges. The method follows that, we used characteristics of each equipment, UPFC would be also settled to keep the identified voltage range in change of load bus, Shunt elements also would be settled to supply the reactive power shortage in out of operating range of UPFC to cope actively with change of the power system. As the result of simulation, it is possible to keep the load bus voltage in limited range in spite of broad load range condition. This helps greatly for the improvements of supply reliability and voltage stability.

Nanobiocatalyst-Linked Immunosorbent Assay(NBC-LISA) (나노바이오촉매 기반 효소결합면역흡착검사)

  • Lee, Inseon;Hwang, Sang Youn;Kim, Jungbae
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.387-392
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    • 2011
  • Enzymes are being used in various fields due to their unique property of substrate specificity. Enzyme-linked immunosorbent assay(ELISA) has enabled the detection of various antigens by reporting the binding event of antigen and antibody via enzyme-catalyzed reaction. However, the sensitivity improvement of conventional ELISA has been limited because only one enzyme molecule is conjugated to one molecule of antibody. To overcome this limitation and further improve the sensitivity of ELISA, there have been efforts to increase the number ratio of enzymes to antibody. Recently, the nanobiocatalytic approaches, with their successful enzyme stabilization, improved the performance stability as well as sensitivity in a modified protocol of ELISA. The present paper introduces the basic principle of ELISA, and the recent efforts to improve sensitivity and performance stability of ELISA by using the nanobiocatalytic approaches.

A Study on the Formation of a W/O/W Multiple Emulsion by Polyglyceryl-10 Stearate (Polyglyceryl-10 Stearate를 이용한 W/O/W 다중 에멀젼의 제조에 관한 연구)

  • Yoo, Jung Min;Choi, Se Bum;Kim, Kyung Min;Kim, Seong Ho;Lee, Chung Hee;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.3
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    • pp.237-246
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    • 2014
  • Multiple emulsions, called multiphase emulsions, include water-in-oil-in-water (W/O/W) type and oil-in-water-in-oil (O/W/O) type emulsions. In cosmetic industry, they are used to stabilize active ingredients but the applicability of the multiple emulsions is limited because of low stability and difficulty of manufacturing. In this study, we investigated a two-step emulsification process for a W/O/W type emulsion. We also investigated the change of stability using different emulsifiers and oil polarity. The results suggested that polyglyceryl-10 stearate, as a main emulsifier, played an important role in the stability and the formation of the multiple emulsions.

Analysis of Determinants of Employment Retention Rate (고용유지율 결정요인 분석)

  • Lee, Sikyoon
    • Korean Journal of Labor Studies
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    • v.23 no.2
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    • pp.169-193
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    • 2017
  • This study analyzed the determinants that affect employment retention rate in order to diagnose dynamic employment stability in Korea. For this analysis, we constructed multi-level hierarchical data linking Workplace panel survey data and employment insurance job history data. And the determinants were analyzed using a multi-level analysis model suitable for these data. As result of the analysis, it is estimated that the employment stability is very low in Korea due to the widespread existence of the marginal sectors with low wage level and high level of nonstandard employment. In addition, the results of this analysis show that employment structure of Korea occupies considerable area of short-term employment where employment and unemployment are repeated, and overall employment stability is weak. This fact is likely to be a limiting factor for continued growth, as there is limited opportunity for skill development and skills formation at the corporate and individual levels. According to the results of this analysis, it is required to improve the quality of the employment structure for continuous growth and skill formation.

Thermal Stability of Surface Film Formed on a Graphite Negative Electrode in Lithium Secondary Batteries (리튬 이차전지의 흑연 음극에 형성된 표면피막의 열적 안정성)

  • Jeong, Soon-Ki;Lee, Ha-Na;Kim, Yang-Soo
    • Journal of the Korean Electrochemical Society
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    • v.14 no.3
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    • pp.157-162
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    • 2011
  • The stability at elevated temperatures of a surface film formed on a graphite electrode in lithium secondary batteries was investigated by transmission electron microscopy (TEM) and electrochemical AC impedance spectroscopy (EIS). TEM analysis revealed that the surface film partly dissolved in the electrolyte solution during storage at $60^{\circ}C$, resulting in a decrease in the thickness of the surface film and a change in its morphology to a porous structure. On the other hand, an increase in the impedance of the surface film which is attributable to a change in composition of the surface film was confirmed by EIS analysis during the storage at $60^{\circ}C$. It was also shown that the addition of vinylene carbonate or 1,3-propane sultone or etylene sulfite, even if limited, improves the stability of the surface film at elevated temperatures.

Stability Analysis for CWR on the Railway Bridges by Linearized Method (선형해석법을 이용한 교량상 장대레일의 안정성 해석 방법 연구)

  • Choi, Young-Gil;Oh, Ju-Won
    • Journal of the Korean Society for Railway
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    • v.12 no.4
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    • pp.472-480
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    • 2009
  • The stability analysis for CWR is difficult in the theory itself because both geometric and material nonlinearity should be considered. Also the analysis results are varied according to the loading history. In contrast to the complexity in the theory, the analysis results for CWR on the railway bridges are quite simple and can be predicted because of a small buckling effect and its negligible nonlinearity. In this study, refined nonlinear analysis methods for the stability analysis of CWR on the railway bridges were developed which consider only material nonlinearity beeause the effects of geometric nonlinearity are nominal. In this study, the analysis results can be found within limited number of iterations with idealized linear force-displacement relationship. From the analysis result comparisons, it was found that the stability analysis for CWR on the railway bridges can be performed effectively by this method.

Properties of Trypsin-Mediated Activation of Aspartase from Hafnia alvei

  • Lee, Min-Sub;Choi, Kyoung-Jae;Kwom, Si-Joong;Kang, In-Sug;Ha, Joo-Hun;Kim, Sung-Soo;Han, Myung-Soo;Yoon, Moon-Young
    • BMB Reports
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    • v.32 no.6
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    • pp.573-578
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    • 1999
  • Treatment of Hafnia alvei aspartase with limited tryptic digestion resulted in a marked increase in enzymatic activity. The activation required a few minutes to attain maximum level and, thereafter, the activity gradually decreased to complete inactivation. The degree of cleavage associated with the activation was extremely small as judged by SDS-PAGE. Upon activation, the optimum pH and temperature were essentially unchanged. When trypsin-activated enzyme was denatured in 4 M guanidine-HCI followed by removal of the denaturant by dilution, the restoration of activity was similar (40%) to that of the native enzyme, indicating a degree of stability. The $pK_a$ obtained on the acidic side and the $pK_b$ obtained on the basic side of trypsin-activated aspartase were 6.6 and 8.6, respectively, the same as those of the native aspartase, indicating that aspartase may exist in a stable conformation after limited tryptic digestion. These results indicate that the activation of H. alvei may be mediated by a conformational change away from the active site of individual subunits.

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Control of nonlinear production-distribution process with limited decision policy (최대구매 제한을 갖는 비선형 생산분배계의 제어)

  • 정상화;정상표;오용훈
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.3
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    • pp.156-165
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    • 1997
  • In the practical control systems, the dynamic range of actuatiors is limited(or saturated) when actuators are driven by sufficiently large signals. This gives rise to a nonlinearity as a result of actuator saturation. For example, the upper limit is imposed on productive capability by available factory space and capital equipment. Other examples of those kinds of actuator saturations are a maximum torque of the actua- ting motors and a throttle position in an aircraft speed control A saturating actuator may lead not only to a large overshoot during start-up and shut-down, but also to deterioration of the performance due to the uncertainties. That is, the speed of response is decreased and, possibly, the system output may not follow the lalrge reference inputs. The large-overshoot may be accompanied by rest wind-up(or called by integra- tor wind-up) which comes from controllers with integral action in saturation operation regions. Eventually, as the overshoot increases, the system has a limit cycle or becomes oscillatorily unstable. Due to these cir- cumstances, many studies are focused on the stability and robustness of the nonlinear systems with satu- rating actuator in the time-domain as well as in the frequency-domain.

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F2 Gel Matrix - a Novel Delivery System for Immune and Gene Vaccinations

  • Tuorkey, Muobarak J
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.7
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    • pp.3061-3063
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    • 2016
  • Exploiting the immune system to abolish cancer growth via vaccination is a promising strategy but that is limited by many clinical issues. For DNA vaccines, viral vectors as a delivery system mediate a strong immune response due to their protein structure, which could afflect the cellular uptake of the genetic vector or even induce cytotoxic immune responses against transfected cells. Recently, synthetic DNA delivery systems have been developed and recommended as much easier and simple approaches for DNA delivery compared with viral vectors. These are based on the attraction of the positively charged cationic transfection reagents to negatively charged DNA molecules, which augments the cellular DNA uptake. In fact, there are three major cellular barriers which hinder successful DNA delivery systems: low uptake across the plasma membrane; inadequate release of DNA molecules with limited stability; and lack of nuclear targeting. Recently, a polysaccharide polymer produced by microalgae has been synthesized in a form of polymeric fiber material poly-N-acetyl glucosamine (p-GlcNAc). Due its unique properties, the F2 gel matrix was suggested as an effective delivery system for immune and gene vaccinations.