• Resources Recycling
• /
• v.7 no.5
• /
• pp.33-40
• /
• 1998

The formation reation of anhydrite (CaSO$_{4}$) depends upon the amount and velocity of the SO$_{3}$(g) and CaO(s) produced in the process of the thermal decomposition of alunite[K$_{2}SO_{4}{\cdot}Al_{2}(SO_{4})_{3}{\cdot}4Al(OH)_{3}$] and limestone (CaCO$_{3}$) respectively. Therefore, this study had carried out to investigate the amount and velocity of SO$_{3}$(g) produced by roasting alunite and pyrolytic materials. In air, alunite was transfouned into KAl(SO$_{4})_{2}$ and Al$_{2}O_{3}$ by dehydration at 500~580$^{\circ}C$. The dehydration velocity of alunite was found to be kt=(1-(1-${\alpha})^{1/3})^{2}$, the activation energy, 73.01 kcal/mol. SO$_{3}$(g) ware slowly produced by the thermal decomposition of KAl(SO$_{2})_{2}$, at 580~700$^{\circ}C$, rapidly, at 700~780$^{\circ}C$, The pyrolysis velocity of KAl(SO$_{4})_{2}$ was found to be kt=1-(1-${\alpha})^{1/1}$; activation energy, 66.84kcal/mol. The SiO$_{2}$ and kaolinite in alunite ore scarcely affected the temperature and velocity in which SO$_{3}$(g) were produced.

• Economic and Environmental Geology
• /
• v.45 no.1
• /
• pp.1-8
• /
• 2012

Copper-zinc-bearing skarns of the Kasihan area developed at limestone layers in the sedimentary facies of the Late Oligocene Arjosari Formation. The skarns consist mainly of fine-grained, massive clinopyroxene-garnet, garnet, garnet-epidote, and epidote skarns. Most copper and zinc(-lead) ore mineralization occur in the clinopyroxene-garnet and garnetepidote skarn, respectively. Clinopyroxene occurs as a continuous solid solution of diopside and hedenbergite (from nearly pure diopside up to ${\approx}34$ mole percent hedenbergite), with a maximum 28.2 mole percent johannsenite component. The early and late pyroxenes of Kasihan skarns are diopsidic and salitic, respectively. They fall in the fields typical Cu- and Zn-dominated skarns, respectively. Garnet displays a relatively wide range of solid solution between grossular and andradite with up to ${\approx}2.0$ weight percent MnO. Garnet in early pyroxene-garnet skarn ranges from 49.1 to 91.5 mole percent grossular (mainly ${\geq}78$ mole % grossular). Garnets in late garnet and garnet-epidote skarns range from 2.8 to 91.4 mole percent grossular (mainly ${\geq}70$ mole % for garnet skarn). Epidote compositions indicate solid solutions of clinozoisite and pistacite varying from 65.8 to 76.2 mole percent clinozoisite. Phase equilibria indicate that skarn evolution was the result of interaction of water-rich fluids ($X_{CO_2}{\leq}0.1$) with original lithologies at ${\approx}0.5$ kb with declining temperature (early clinopyroxene-garnet and garnet skarn, ${\approx}450$ to $370^{\circ}C$; late garnet-epidote and epidote skarn, ${\approx}370$ to $300^{\circ}C$).

• Journal of the Korean Ceramic Society
• /
• v.40 no.8
• /
• pp.804-810
• /
• 2003

The fine powder produced by heating and grinding of the waste concrete in the waste construction was investigated whether utilize as substitution raw material of SiO$_2$, CaO, and Al$_2$O$_3$ source for OPC clinker manufacture is possible or not. In order to synthesize OPC clinker, limestone, shale, converter slag and fly ash were used as main raw materials, and modulus was fixed LSF 91.0, SM 2.60, IM 1.60. The synthesized clinkers were characterized. The Main products of synthesized clinker were C$_3$S, ${\beta}$-C$_2$S, C$_3$A, C$_4$AF as OPC clinker at 1,43$^{\circ}C$. As a result of TG-DTA and burnability index(B.U) analysis of each raw mixtures, the formation temperature of clinker phases was similar and B.I was showed easy burning as 48.6∼51.4.

• The Journal of Engineering Geology
• /
• v.30 no.1
• /
• pp.71-84
• /
• 2020

Various geological structures are found on the slope of Bangnim district in Pyeongchang, Gangwon-do, based on the Paleozoic Joseon Supergroup Limestone. The recumbent fold observed on the slope is a very rare geological structure that has not been found in Korea, and has important academic value in exploring the formation process of the Paleozoic geological structures in the Gangwon region. In this study, discussed the geological value of the geological structure observed on the slope of the road, and studied the management method of rockfall problem slopes. The state of development of recumbent folds has conservation value in geological scarcity and specificity. Preservation management measures should be prepared through the protection of slopes and measures to reduce of rockfall risks as geoheritage with an important value in geology science and education. Furthermore, it is expected to be preserved and utilized as a geopark.

• Journal of the Mineralogical Society of Korea
• /
• v.20 no.1 s.51
• /
• pp.35-46
• /
• 2007

Shinyemi skarn deposits occur as Fe-Mo skarn type and Pb-Zn-Cu hydrothermal replacement type along the contact between Cretaceous Shinyemi granitoids and Cambro-Ordovician mixed limestone and dolostone sequence of the Choseon Supergroup. In the lower part of Western Shinyemi ore body two stages of skarn formation have been observed: the early, stage I (magnesian) skarn with Fe mineralization and the late, stage II(calcic) skarn with Mo mineralization. The stage I skarn spatially is overprinted by stage II skarn. The stage I skarn is predominantly composed of olivine, magnetite and diopside whereas, the stage II skarn is dominated by hedenbergite and garnet. The skarnification process occurred in two stages, both prograde and retrograde for stage I and stage II skarns. In stage I, the prograde skarns, mainly composed of anhydrous silicate minerals, were formed at relatively higher temperatures (about $400\;to\;550^{\circ}C$) under low $CO_{2}$ fugacity ($X_{CO2}<0.1$) conditions. On the other hand, the retrograde skarns that consisted of hydrous minerals were formed at lower temperatures (about $300\;to\;400^{\circ}C$).

• Economic and Environmental Geology
• /
• v.50 no.1
• /
• pp.73-83
• /
• 2017

The surveyed mines are located in a polymetallic vein, replacement, and skarn mineral district in the central Andes of Peru. Iscaycruz, which includes underground and open pit mines that produce zinc and lead concentrates, was the largest mineral deposit of an important group of base metal deposits in the Andes of central Peru. The deposits are sub-vertical seams of polymetallic ores(Zn, Cu, and Pb). These seams are hosted by Jurassic and Cretaceous sedimentary rock formation. The intrusion of igneous rocks in these formations originated metallic deposits of metasomatic and skarn types. The Raura mine is composed of polymetallic deposit of veins and replacement orebodies. The main sedimentary unit in the area is Cretaceous Machay Limestone. The Raura depression contains several orebodies each with different mineralization: predominantly Pb-Zn bearing Catuvo orebody; Ag-rich galena-bearing Lake Ninacocha orebody; Cu-Ag bearing Esperanza and Restauradora orebody. Huaron is a hydrothermal polymetallic deposit of silver, lead, zinc, and copper mineralization hosted within structures likely related to the intrusion of monzonite dikes, principally located within the Huaron anticline. Mineralization is encountered in veins parallel to the main fault systems, in replacement bodies known as "mantos" associated with the calcareous sections of the conglomerates and other favourable stratigraphic horizons, and as dissemination in the monzonitic intrusions at vein intersections.

• Journal of the Korean GEO-environmental Society
• /
• v.16 no.9
• /
• pp.23-32
• /
• 2015

This study examined blast testing measurement data which had been obtained from 97 field sites in Korea to investigate the comprehensive characteristics of rock blasting-induced vibration focusing on the effect of excavation types (tunnel, bench) and rock types. The measurement data was from the testing sites mostly in Kangwon province and Kyungsang province and rock types were granite, gneiss, limestone, sand stone, and shale in the order of number of data. The study indicated that the blasting-induced vibration velocity was affected by the excavation types (tunnel, bench) and bench blasting induced higher velocity than tunnel blasting. In addition, the vibration velocity was also highly affected by the rock types and therefore, it can be concluded that rock types should be considered in the future to estimate a blasting-induced vibration velocity. Furthermore, the pre-existing criteria was compared with the results of this study and the comparison indicated that there was a discernable difference except for tunnel blasting results based on the square root scaling and therefore, further studies and interests, which include the effects of rock strength, joint characteristics, geological formation, excavation type, power type, measurement equipment and method, might be necessarily in relation to the estimation of blasting-induced vibration velocity in rock mass.

• Journal of the Mineralogical Society of Korea
• /
• v.31 no.3
• /
• pp.193-213
• /
• 2018

Soil geochemical exploration to check anomalies related to mineralization was carried out targeting around Quy Hop area within Nghe An province, Northern Vietnam. The interval of sampling are horizontal 250 m with 13 line and longitudinal 300 m with 25 line, resulting in 325 soil samples. Based on the result of soil geochemical exploration, the pitting survey was carried out targeting the grid point with high TREO content, resulting in 73 soil samples within 8 pits. The geology of the survey area are consisted of Ban Chieng biotite granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. By ICP-MS result of soil samples, total REE oxide content of background amount is about 1.4 times of crustal abundance, depleting the light rare earth (about 0.2 times) and enriching the heavy rare earth (about 1.5 times). By ICP-MS result of pit soil samples, we identified TREO more than 1,000 ppm in 6 pits. It may be considered that REE ore bodies may develop in NE-SW direction, compared with the geochemical results of Quy Chau area.

• Journal of The Geomorphological Association of Korea
• /
• v.19 no.2
• /
• pp.81-98
• /
• 2012

This research aims 1) to analyse the spatial occurrence of red soils, in Korea 2) to predict their spatial distribution using terrain analyses, and 3) to interpret results from the perspective of pedogeomorphological processes. Red soils (often called red-yellow soils) in Korea are frequently found on welldrained plains and gently sloping areas. These soils are widely believed paleo-soils that were formed under hot and humid climatic conditions in the past. The spatial distribution of red soils was derived from the soil map of Korea, and a DEM based soil prediction was developed, based on a continuity equation to depict water and material flows over the landscape. About 64.5% of the red soil occurrence can be explained by the prediction. Close examinations between surveyed and predicted red soil maps show few distinctive spatial features. Granitic erosional plains at the inland of Korea show comparatively low occurrence of red soils, which might indicate active geomorphological processes within the basins. The occurrence of red soils at limestone areas is more abundant than that of the predicted, indicating the influence of parent materials on the formation of red soils. At and around lava plateau at Cheulwon and Youncheon, the occurrence of red soils is underestimated, which might partly be explained by the existence of loess-like surface deposits. There are also distinctive difference of prediction results between northern and southern parts of Korea (divided by a line between Seosan and Pohang). The results of this research calls for more detailed field-based investigations to understand forming processes of red soils, focusing on the spatial heterogeneity of pedological processes, the influence of parent materials, and difference in uplift patterns of the Korean peninsula.

• Geomechanics and Engineering
• /
• v.17 no.4
• /
• pp.343-354
• /
• 2019

The present study demonstrates the application of seismic petrophysics and amplitude versus angle (AVA) forward modeling to identify the reservoir fluids, discriminate their saturation levels and natural gas composition. Two case studies of the Lumshiwal Formation (mainly sandstone) of the Lower Cretaceous age have been studied from the Kohat Sub-basin and the Middle Indus Basin of Pakistan. The conventional angle-dependent reflection amplitudes such as P converted P ($R_{PP}$) and S ($R_{PS}$), S converted S ($R_{SS}$) and P ($R_{SP}$) and newly developed AVA attributes (${\Delta}R_{PP}$, ${\Delta}R_{PS}$, ${\Delta}R_{SS}$ and ${\Delta}R_{SP}$) are analyzed at different gas saturation levels in the reservoir rock. These attributes are generated by taking the differences between the water wet reflection coefficient and the reflection coefficient at unknown gas saturation. Intercept (A) and gradient (B) attributes are also computed and cross-plotted at different gas compositions and gas/water scenarios to define the AVO class of reservoir sands. The numerical simulation reveals that ${\Delta}R_{PP}$, ${\Delta}R_{PS}$, ${\Delta}R_{SS}$ and ${\Delta}R_{SP}$ are good indicators and able to distinguish low and high gas saturation with a high level of confidence as compared to conventional reflection amplitudes such as P-P, P-S, S-S and S-P. In A-B cross-plots, the gas lines move towards the fluid (wet) lines as the proportion of heavier gases increase in the Lumshiwal Sands. Because of the upper contacts with different sedimentary rocks (Shale/Limestone) in both wells, the same reservoir sand exhibits different response similar to AVO classes like class I and class IV. This study will help to analyze gas sands by using amplitude based attributes as direct gas indicators in further gas drilling wells in clastic successions.