• The Journal of the Petrological Society of Korea
• /
• v.9 no.1
• /
• pp.13-28
• /
• 2000

Chojeong area is mainly composed of the Ogcheon Group which consists of regionally metamorphosed, age-unknown sedimentary rocks. In the northwestern parts, the Group is intruded by the Jurassic Daebo granite and Cretaceous felsic and mafic dykes. The lowermost, Midongsan Formation which consists of milky white impure quartzite, crops out along the anticline axes with N40E trend. Ungyori quartzite Formation is intercalated with quartzite and slate. Miwon Formation is most widely exposed in the area and consists mainly of phyllitic sandy rocks with a thin crystalline limestone bed. Hwajeonri Formation is divided into two parts, pelitic lower and calcareous upper parts, composed with phyllite and slate. Changri and Hwanggangri Formations are typical members of Ogcheon Group, the former bearing coally graphite seams consists mainly of black slate and phyllite with intercalated greenish grey phyllite, the latter is pebble bearing phyllite formation of which matrix and pebbles are variable in compositions and size. Biotite granite, porphyritic granite and two mica granite belong to Jurassic so-called Dabo granite. They intruded the Ogcheon Group forming vast contact metarnophic zone. Quartz porphyry, mafic dyke and felsite intruded along the marginal zone of porphyritic granite batholith and fracture of NS trend. Main structural lineaments in Ogcheon Group shows N25-45E, NS and N30-45W trends. The N25-45E trends are mainly from general ductile deformation during regional metamorphism, showing isoclinal folding, Fl foliations and lithological erosional characters. Some of these trends are due to normal faults. The NS and N30-45W trends represent brittle deformation including faults and joints. In the area of granitic batholith, NS to N30- 45 trends are from the direction of dykes. In the soils of the area, average contents of heavy metal elements such as Cd, Cr, Cu, Pb, and Zn are 0.2, 50.6, 35.5, 27.9, and 93.4 ppm respectively, which are not higher than the average values of natural soils, under the tolerable level. Enrichment Index does not show any heavy metal pollution in the area. Average depths of weathering(5m vs. 2m), porosities(43.94 vs. 51.80), densities(l.29 vs. 1.15), and permeabilities(2.52 vs. 8.07) are comparable in granite areas and in the phyllite areas of Ogcheon Group.

• Economic and Environmental Geology
• /
• v.51 no.5
• /
• pp.401-407
• /
• 2018

For the treatment of heavy metals in the mine drainage from the closed mine area, various methods such as passive, active and semi-active treatments are considered. Among contaminated elements in the mine drainage, Mn is one of the difficult elements for the treatment because it needs high pH over 9.0 for its concentration to be reduced. In this study, the efficiency of various slag complex reactors (slag (S), slag+limestone (SL) and slag+Mn coated gravel (SG)) on Mn removal in the presence of Fe, which is a competitive element with Mn, was evaluated to investigate effective methods for the treatment of Mn in mine drainage. As a result of experiments on Mn removal without Fe during 358 days, using influent with $30{\sim}50Mn{\cdot}mg/L$ and pH 6.7 on the average, S reactor showed continuously high Mn removal efficiency with the average of 99.9% with pH 8.9~11.4. Using the same reactors, Mn removal experiments with Fe during 237 days were conducted with the influent with $40{\sim}60Mn{\cdot}mg/L$. The pH range of effluent reached to 6.1~10.0, which is slightly lower than that of effluent without Fe. S reactor showed the highest range of pH with 7.1~9.9, followed by S+L and S+G reactor. However, the efficiency of Mn removal showed S+L>S>S+G with the range of 94~100%, 68~100% and 68~100%, respectively in spite of relatively low pH range. S+L reactor showed the most resistance on Fe input, which means other mechanisms such as $MnCO_3$ formation by the carbonate prouced from the limestone or autocatalysis reaction of Mn contributed to Mn removal rather than pH related mechanisms. The evidence of reactions between carbonates and Mn, rhodochrosite ($MnCO_3$), was found from the X-ray diffraction analysis of precipitates sample from S+L reactor. From this study, the most effective reactors on Mn removal in the presence of Fe was S+L reactor. The results are expected to be applied for the Mn containing mine water treatment in the presence of Fe within the relatively low range of pH.

• Korean Journal of Soil Science and Fertilizer
• /
• v.24 no.1
• /
• pp.1-9
• /
• 1991

A study was carried out to investigate the composition of rock-forming minerals and mineralogical characteristics of the five major parent rocks in Korea. The identification was done through the analyses of chemical. X-ray diffraction, thermal(DTA, TG), infrared spectroscopic, and microscopic methods. Among these methods, X-ray diffraction was considered to be the most rapid and effective way to identify minerals in the parent rocks. The main rock-forming minerals of the parent rocks were feldspars, quartz, and micas in granite and granite-gneiss, calcite and dolomite in limestone, quartz and calcite in shale, plagioclase and augite in basalt. A small amount of sesquioxides was identified as a accessory mineral by means of DTA from the parent rocks of Weoljeong series(granite) and Cheongsan series(granite-gneiss). The abrasion pH affecting the soil formation ranged from 7.5 to 8.4 in the parent rocks containing ferromagnesian minerals and carbonates. In the granite and granite-gneiss of which the main rock-forming minerals were feldspars and quartz with low content of biotite, the abrasion pH ranged from 6.2 to 6.4. In chemical composition of the parent rocks, Si, AI, and K oxides tented to increase with higher contents of quartz, feldspars, and muscovite, while Fe and Mg oxides with higher content of biotite, chlorite, amphiboles, and augite. Higher ignition loss in limestone and shale resulted in the release of $CO_2$ from calcite and/or dolomite.

• Resources Recycling
• /
• v.31 no.6
• /
• pp.44-51
• /
• 2022

In the steelmaking process using an electric arc furnace (EAF), light-burnt dolomite, which is a flux containing MgO, is used to protect refractory materials and improve desulfurization ability. Furthermore, a recarburizing agent is added to reduce energy consumption via slag foaming and to induce the deoxidation effect. Herein, a waste MgO-C based refractory material was used to achieve the aforementioned effects economically. The waste MgO-C refractory materials contain a significant amount of MgO and graphite components; however, most of these materials are currently discarded instead of being recycled. The mass recycling of waste MgO-C refractory materials would be achievable if their applicability as a flux for steelmaking is proven. Therefore, experiments were performed using a target composition range similar to the commercial EAF slag composition. A pre-melted base slag was prepared by mixing SiO₂, Al₂O₃, and FeO in an alumina crucible and heating at 1450℃ for 1 h or more. Subsequently, a mixed flux #2 (a mixture of light-burnt dolomite, waste MgO-C based refractory material, and limestone) was added to the prepared pre-melted base slag and a melting reaction test was performed. Injecting the pre-melted base slag with the flux facilitates the formation of the target EAF slag. These results were compared with that of mixed flux #1 (a mixture of light-burnt dolomite and limestone), which is a conventional steelmaking flux, and the possibility of replacement was evaluated. To obtain a reliable evaluation, characterization techniques like X-ray diffraction (XRD) analysis and X-ray fluorescence (XRF) spectrometry were used, and slag foam height, slag basicity, and Fe recovery were calculated.

• Journal of the Korea Institute of Building Construction
• /
• v.24 no.2
• /
• pp.181-191
• /
• 2024

In the realm of cement manufacturing, concerted efforts are underway to mitigate the emission of greenhouse gases. A significant portion, approximately 60%, of these emissions during the cement clinker sintering process is attributed to the decarbonation of limestone, which serves as a fundamental ingredient in cement production. Prompted by these environmental concerns, there is an active pursuit of alternative technologies and admixtures for cement that can substitute for limestone. Concurrently, initiatives are being explored to harness technology within the cement industry for the capture of carbon dioxide from industrial emissions, facilitating its conversion into carbonate minerals via chemical processes. Parallel to these technological advances, economic growth has precipitated a surge in construction activities, culminating in a steady escalation of construction waste, notably waste concrete. This study is anchored in the innovative production of calcium silicate cement clinkers, utilizing finely powdered waste concrete, followed by a thorough analysis of their mineral phases. Through X-ray diffraction(XRD) analysis, it was observed that increasing the substitution level of waste concrete powder and the molar ratio of SiO₂ to (CaO+SiO₂) leads to a decrease in Belite and γ-Belite, whereas minerals associated with carbonation, such as wollastonite and rankinite, exhibited an upsurge. Furthermore, the formation of gehlenite in cement clinkers, especially at higher substitution levels of waste concrete powder and the aforementioned molar ratio, is attributed to a synthetic reaction with Al₂O₃ present in the waste concrete powder. Analysis of free-CaO content revealed a decrement with increasing substitution rate of waste concrete powder and the molar ratio of SiO₂/(CaO+SiO₂). The outcomes of this study substantiate the viability of fabricating calcium silicate cement clinkers employing waste concrete powder.

• Economic and Environmental Geology
• /
• v.30 no.6
• /
• pp.505-517
• /
• 1997

Lead and zinc mineralization of the Kwangsin mine was formed in quartz and carbonate veins that filled fault-related fractures in the limestone-rich Samtaesan Formation of the Chosun Supergroup and the phyllite-rich Suchangni Formation of unknown age. A K-Ar date of alteration sericite indicates that the Pb-Zn mineralization took place during Late Cretaceous (83.5 Ma), genetically in relation to the cooling of the nearby Muamsa Granite (83~87 Ma). Mineral paragenesis can be divided into three stages (I, II, III): (I) the deposition of barren massive white quartz, (II) the main Pb-Zn mineralization with deposition of white crystalline quartz and/or carbonates (rhodochrosite and dolomite), and (III) the deposition of post-ore barren calcite. Mineralogic and fluid inclusion data indicate that lead-zinc minerals in middle stage II (IIb) were deposited at temperatures between $182^{\circ}$ and $276^{\circ}C$ from fluids with salinities of 2.7 to 5.4 wt. % equiv. NaCl and with log $fs_2$ values of -15.5 to -11.8 atm. The relationship between homogenization temperature and salinity data indicates that lead-zinc deposition was a result of fluid boiling and later meteoric water mixing. Ore mineralization occurred at depths of about 600 to 700 m. Sulfur isotope compositions of sulfide minerals (${\delta}^{34}S_{CDT}=9.0{\sim}14.5$ ‰) indicate a relatively high ${\delta}^{34}S_{{\Sigma}S}$ value of ore fluids (up to 14 ‰), likely indicating an igneous source of sulfur largely mixed with an isotopically heavier sulfur source (possibly sulfates in surrounding sedimentary rocks). There is a remarkable decrease of calculated ${\delta}^{18}O$ value of water in hydrothermal fluids with increasing paragenetic time: stage I, 14.6~10.1 ‰; stage IIa, 5.8~2.2 ‰; stage IIb, 0.8~2.0 ‰; stage IIc, -6.1~-6.8 ‰, This indicates a progressive increase of meteoric water influx in the hydrothermal system at Kwangsin. Measured and calculated hydrogen and oxygen isotope values indicate that the Kwangsin hydrothermal fluids was formed from a circulating (due to intrusion of the Muamsa Granite) meteoric waters which evolved through interaction mainly with the Samtaesan Formation (${\delta}^{18}O=20.1$ to 24.9 ‰) under low water/rock ratios.

• The Journal of the Petrological Society of Korea
• /
• v.6 no.3
• /
• pp.244-244
• /
• 1997

The Janggunbong area(this study area) at the central-south part in the North Sobaegsan Massif, Korea, consists mainly of Precambrian(Wonnam and Yulri Formations)-Paleozoic [Joseon Supergroup(Jangsan Quarzite, Dueumri Formation and Janggum Limestone) and Pyeongan Group(Jaesan and Dongsugok Formations)] metasedimentary rocks and Mesozoic granitoid(Chunyang granite.) This study is to interpret geological structure of the North Sobaegsan Massif in the Jang-gunbong area by analysing rock-structure and microstructure of the constituent rocks. It indicates that its geological structure was formed at least by four phases of deformation after the formation of gneissosity(S0) in the Wonnam Formation and bedding plane(S0) in the Paleozoic metasedimentary rocks. The first phase deformation(D1) formed tight isoclinal fold(F1). Its axial plane(S1) strikes east-west and steeply dips north. Its axis (L1) subhorizontally plunges east-west. The second phase deformation(D2), which was related to ductile shear deformation, formed stretching lineation(L2) and shear foliation(S2). The sense of the shear movement indicates dextral strike-slip shearing(top-to-the east shearing). The third phase deformation(D3) formed open inclined fold(F3). Its axial plane(S3) strikes east-west and moderately or gently dips north. Its axis(L3) subhorizontally plunges east-west. The F3 fold reoriented the original north-dipping S1 foliation and D2 shear sense into south-dipping S1 foliation(top-to-the west shear sense on this foliation) at its a limb. The four phase of deformation(D4) formed asymmetric-type open inclined fold(F4) of NE-vergence with NW striking axial plane(S4) and NW-NNW plunging axis(L4). The F4 fold partly reoriented pre-D4 structural elements with east-west trend into those with north-south trend. Such reorientation is recognized mainly in the Paleozoic metasedimentary rocks.

• The Journal of the Petrological Society of Korea
• /
• v.6 no.3
• /
• pp.224-259
• /
• 1997

The Janggunbong area(this study area) at the central-south part in the North Sobaegsan Massif, Korea, consists mainly of Precambrian(Wonnam and Yulri Formations)-Paleozoic [Joseon Supergroupuangsan Quarzite, Dueumri Formation and Janggun Limestone) and Pyeongan Group (Jaesan and Dongsugok Formations)l metasedimentary rocks and Mesozoic granitoid(Chunyang granite). This study is to interpret geological structure of the North Sobaegsan Massif in the Janggunbong area by analysing rock-structure and microstructure of the constituent rocks. It indicates that its geological structure was formed at least by four phases of deformation after the formation of gneissosity(S0) in the Wonnam Formation and bedding plane(S0) in the Paleozoic metasedimentary rocks. The first phase deformation(D1) formed tight isoclinal fold(F1). Its axial plane(S1) strikes east-west and steeply dips north. Its axis(L1) subhorizontally plunges east-west. The second phase deformation(D2), which was related to ductile shear deformation, formed stretching lineation(L2) and shear foliation(S2). The sense of the shear movement indicates dextral strike-slip shearing(topto-the east shearing). The third phase deformation(D3) formed open inclined fold(F3). Its axial plane(S3) strikes east-west and moderately or gently dips north. Its axis(L3) subhorizontally plunges east-west. The F3 fold reoriented the original north-dipping S1 foliation and D2 shear sense into south-dipping S1 foliation(top-to-the west shear sense on this foliation) at its a limb. The four phase of deformation(D4) formed asymmetric-type open inclined fold(F4) of NE-vergence with NW striking axial plane(%) and NW-NNW plunging axis(L4). The F4 fold partly reoriented pre-D4 structural elements with east-west trend into those with north-south trend. Such reorientaion is recognized mainly in the Paleozoic metasedimentary rocks.

• Korean Journal of Mineralogy and Petrology
• /
• v.33 no.3
• /
• pp.215-232
• /
• 2020

The study area of Nokjeonri in Yeongwol belongs to the Taebaeksan Mineralized District. Ca and Mg skarn and related ore mineralization are developed in the Pungchon formation along the contact with the Imog granite. Ca skarn hosted in limestone mostly comprises garnet and pyroxene. Mg skarn developed in dolomite includes olivine and serpentine. Magnetite-hematite and pyrrhotite(±scheelite)-pyritegalena-sphalerite were mineralized during early and late stage, respectively. Garnet compositions are dominated by andradite series in proximal area and grossular series in distal area. Pyroxene compositions correspond to diopside series in majority. These compositional changes indicate that the fluids varied from oxidizing condition to reducing condition due to increased reaction with carbonated wall rocks as the fluids moved from the granite to a distal place. Fe₂O₃ and MgO concentrations of magnetite are higher in Mg skarn than those in Ca skarn, while FeO shows opposite trend. The Zn/Fe ratio of sphalerite increases with distance from the Imog granite. The δ³⁴S values of sulfide minerals are similar to those of the Imog granite, indicating magmatic origin in ore sulfur. Mineralization was established in the order of skarn, oxide and sulfide minerals with decreasing temperature and oxygen fugacity and increasing sulfur fugacity.

• Journal of Korean Society of Environmental Engineers
• /
• v.29 no.3
• /
• pp.297-303
• /
• 2007

Orimulsion, a bitumen-in-water emulsified fuel, has been used throughout the world as a substitute fuel for heavy oil and coal. Orimulsion has relatively high levels of sulfur, nickel, and vanadium, compared to other fuel oils and coals, and has been the subject of much debate regarding the environmental impacts. In Korea, Y power plant has operated boilers with Orimulsion as a fuel, and they has some drawbacks during the plant operation, such as plume opacity. In this study, we investigated the cause of formation mechanism and factors for the plume opacity by investigating the operation data, and measuring the particle size distribution at EP(Electrostatic Precipitator), FGD(Fuel Gas Desulfurization) and TMS(Telecommunications Management System) units. Resulting data showed the primary particles below 1 ${\mu}m$ formed were regrown by the recombination of $SO_3$ in wet-limestone FGD process, and thus the secondary particles are induced to cause the plume opacity.