• Title/Summary/Keyword: Light dependent

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Equivalent-Circuit Analysis of Organic Light-Emitting Diodes using Frequency-dependent Response of $ITO/Alq_3/Al$ Device ($ITO/Alq_3/Al$ 소자의 주파수 의존 응답을 이용한 유기 발광소자의 등가회 로 분석)

  • Ahn, Joon-Ho;Chung, Dong-Hoe;Hur, Sung-Woo;Lee, Joon-Ung;Song, Min-Jong;Lee, Won-Jae;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04a
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    • pp.5-8
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    • 2004
  • We have investigated equivalent-circuit analysis of organic light-emitting diodes using frequency-dependent response of $ITO/Alq_3(60nm)/Al$ device at two different bias voltages. Complex impedance Z of the device was measured in the frequency range of 40Hz~1MHz. A Cole-Cole plot shows that there are two dielectric relaxations at the bias below turn-on voltage, and one relaxation at the bias above turn-on voltage. We are able to interpret the frequency-dependent response in terms of equivalent-circuit model of contact resistance $R_s$ in series with parallel combination of resistance $R_p$ and capacitance $C_p$. We have obtained contact resistance $R_s$ around $90{\Omega}$, mainly from the ITO anode.

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Phosphorylation, 14-3-3 protein and photoreceptor in blue light response of stomatal guard cells

  • Toshinori Kinoshita;Takashi Emi;Michio Doi;Shimazaki, Ken-ichiro
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.335-337
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    • 2002
  • Blue light (BL) induces stomatal opening through activation of H$^{+}$ pump, which creates electrical gradient across the plasma membrane for $K^{+}$ uptake into guard cells. The pump is the plasma membrane H$^{+}$ -ATPase and is activated via phosphorylation of the C-terminus with concomitant binding of the 14-3-3 protein. The opening is initiated by the perception of BL through phototropin (phot), which are recently identified as BL receptors in stomatal guard cells. In this study, we provide the biochemical evidence for phots as BL receptors in stomatal guard cells. vfphot was phosphorylated reversibly by BL, and phosphorylation levels of vfphot increased earlier than those of the plasma membrane W-ATPase. BL-dependent phosphorylations of vfphot and H$^{+}$-ATPase showed similar fluence dependency. Staurosporin, an inhibitor of serine/threonine protein kinase, and diphenyleneiodonium chloride (DPI), an inhibitor of flavoprotein, inhibited BL-dependent phosphorylations of vfphot and H$^{+}$ -ATPase. These results indicate that vfphot acts as a BL-receptor mediating stomatal opening.l opening.

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Photoperiodic modulation of insect circadian rhythms

  • Tomioka, Kenji;Uwozumi, Kouzo;Koga, Mika
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.9-12
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    • 2002
  • Circadian rhythms can be seen in a variety of physiological functions in insects. Light is a powerful zeitgeber not only synchronizing but also modulating the rhythm to adjust insect's temporal structure to seasonal changes in the environmental cycle. There are two general effects of the length of light phase within 24 hr light cycles on the circadian rhythms, i.e., the modulation of free-running period and the waveform. Since the photoperiodic modulation of the free-running period is induced even in the clock mutant flies, per$\^$s/, the free-running period is not fully determined genetically. In crickets, the ratio of activity (a) and rest phase (p) under the constant darkness (DD) is clearly dependent on the photoperiod under which they have been kept. When experienced the longer photoperiod it becomes smaller. The magnitude of change in a/p-ratio is dependent on the number of cycles they experienced. The neuronal activity of the optic lobe in DD shows the a/p-ratio changing with the preceding photoperiod. These data suggest that a single circadian pacemaker stores and maintains the photoperiodic information and that there is a system that accumulates the effects of single photoperiod to cause greater effects.

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Organic-layer and reflectivity of transparent electrode dependent, microcavity effect of top-emission organic light-eitting diodes (TE-OLED의 유기물층과 반투명 음전극의 반사도에 따른 마이크로 캐비티 특성)

  • An, Hui-Chul;Na, Su-Hwan;Joo, Hyun-Woo;Mok, Rang-Kyun;Jung, Kyung-Seo;Chio, Seong-Jea;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.299-300
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    • 2009
  • We have studied an organic layer and semitransparent Al cathode thickness dependent optical properties for top-emission organic light-emitting diodes. Device structure is ITO(170nm)/TPD(xnm)/$Alq_3$(ynm)/LiF(0.5nm)/Al(100nm) and Al(100nm)/TPD(xnm)/$Alq_3$(ynm)/LiF(0.5nm)/Al(25nm). While a thickness of total, organic layer was varied from 85nm to 165nm, a ratio of those two layers was kept to be about 2:3. Then it was compared with that of bottom devices. And a thickness of semitransparent Al cathode was varied from 20nm to 30nm for the device with an organic layer thickness of 140nm. We were able to control the emission spectra from the top-emission organic light-emitting diodes.

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Effects of Hole-Injection Buffer Layer in Organic Light-Emitting Diodes (유기 발광 소자에서 정공 주입 버퍼층의 효과)

  • 정동희;김상걸;오현석;홍진웅;이준웅;김영식;김태완
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.816-825
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    • 2003
  • Current-voltage-luminance characteristics of organic light-emitting diodes (OLEDs) were measured in the temperature range of 10 K~300 K. Indium-tin-oxide (ITO) was used as an anode and aluminum as a cathode in the device. Organic of N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) was used for a hole transporting material, and tris (8-hydroxyquinolinato) aluminum (Alq$_3$) for an electron transporting material and emissive material. And copper phthalocyanine (CuPc), poly(3,4-ethylenedi oxythiophene);poly(styrenesulfonate) (PEDOT:PSS), and poly(N-vinylcarbazole) (PVK) were used for hole-injection buffer layers. From tile analysis of electroluminescence (EL) and photoluminesccnce (PL) spectra of the Alq$_3$, the EL spectrum is more greenish then that of PL. And the temperature-dependent current-voltage characteristics were analyzed in the double and multilayer structure of OLEDS. Electrical conduction mechanism was explained in the region of high-electric and low-electric field. Temperature-dependent luminous efficiency and operating voltage were analyzed from the current-voltage- luminance characteristics of the OLEDS.

Dose-dependent UV Stabilization of p53 in Cultured Human Cells Undergoing Apoptosis Is Mediated by Poly(ADP-ribosyl)ation

  • Won, Jungyeon;Chung, So Young;Kim, Seung Beom;Byun, Boo Hyeong;Yoon, Yoo Sik;Joe, Cheol O.
    • Molecules and Cells
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    • v.21 no.2
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    • pp.218-223
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    • 2006
  • The effect of poly(ADP-ribosyl)ation on the stability of p53 in SK-HEP1 cells treated with UV light was examined. Intracellular levels of p53 increased in cells treated with a low dose of UV light ($20J/m^2$), whereas they increased but then declined after a higher dose of UV ($100J/m^2$). Intracellular levels of p53 in the UV treated SK-HEP1 cells were dependent on the UV dose. Use of proteasome inhibitors revealed that p53 is degraded by proteasomal proteolysis after high doses of UV light. We present evidence that, at low doses, poly(ADP-ribose)polymerase (PARP) poly(ADP-ribosyl) ates p53 and protects it from proteasomal degradation before caspase-3 is activated, whereas at high doses the cells undergo UV induced apoptosis and PARP is cleaved by caspase-3 before it can protect p53 from degradation. Destabilization of p53 by cleavage of PARP may be important in cell fate decision favoring apoptosis.

Organic-layer thickness dependent optical properties of top emission organic light-eitting diodes (전면 유기 발광 소자의 유기물층 두께 변화에 따른 광학적 특성)

  • An, Hui-Chul;Joo, Hyun-Woo;Na, Su-Hwan;Kim, Tae-Wan;Hong, Jin-Woong;Oh, Yong-Cheul;Song, Min-Joung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.413-414
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    • 2008
  • We have studied an organic layer thickness dependent optical properties and microcavity effects for top-emission organic light-emitting diodes. Manufactured top emission device, structure is Al(100nm)ITPD(xnm)/$Alq_3$(ynm)/LiF(0.5nm)/Al(23nm). While a thickness of hole-transport layer of TPD was varied from 35 to 65nm, an emissive layer thickness of $Alq_3$ was varied from 50 to 100nm for two devices. A ratio of those two layers was kept to about 2:3. Variation of the layer thickness changes a traverse time of injected carriers across the organic layer, so that it may affect on the chance of probability of exciton formation. View-angle dependent emission spectra were measured for the optical measurements. Top-emission devices show that the emission peak wavelength shifts to longer wavelength as the organic layer thickness increases. For instance, it shifts from 490 to 555nm in the thickness range that we used. View-angle dependent emission spectra show that the emission intensity decreases as the view-angle increases. The organic layer thickness-dependent emission spectra show that the full width at half maximum decreases as the organic layer thickness increases. Top emission devices show that the full width at half maximum changes from 90 to 35nm as the organic layer thickness increases. In top-emission device, the microcavity effect is more vivid as the organic layer thickness increases.

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INITIATION OF LIPID PEROXIDATION AS A RESULT OF THE COMBINED ACTION OF FERRIC IRON AND LIGHT ON MEMBRANES

  • Park, Zee-Yong;Kim, Chang-Sook;Jung, Jin
    • Journal of Photoscience
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    • v.1 no.2
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    • pp.83-88
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    • 1994
  • The synergic effect of iron plus blue light on the peroxidation of membrane lipid was investigated, using liposomes made of phospholipid. While strong irradiation did not affect Fe$^{+2}$-promoted lipid peroxidation that turned out to be O$_2$-dependent, ferric iron in bright light exerted a pronounced effect on the initiation of lipid peroxidation: this combined action of light and Fe$^{+3}$ on liposomal membranes was apparently independent of O$_2$. When liposomal samples containing Fe$^{+3}$ were subjected to irradiation, some portions of Fe$^{+3}$ were converted into Fe$^{+2}$. The extent of the Fe$^{+3}$-Fe$^{+2}$ conversion increased with increasing time of irradiation, which resembled the dependence of Fe$^{+3}$-promoted lipid peroxidation on irradiation. Further, it was observed that the effect of irradiation in liposomal samples containing Fe$^{+2}$ was strikingly mimicked by that of Fe$^{+2}$ addition to the same samples. The obligatory requirement of a suitable Fe$^{+3}$/Fe$^{+2}$ ratio for the genesis of iron-dependent lipid peroxidation, a controversial proposition, was also confirmed by the observation that lipid peroxidation was substantially enhanced by the addition of a mixture of Fe$^{+3}$ and Fe$^{+2}$, as compared to the addition of Fe$^{+3}$ or Fe$^{+2}$ alone. The results obtained in this study not only suggest that light acts as an effector for initiating lipid peroxidation, when Fe$^{+3}$ is present in membrane systems, but also imply that any chemical or physical factor that influences the redox states of iron in membranes can play a role in lipid peroxidation reactions.

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High-light avoidance response of chloroplasts and reorganization of actin filaments are induced only in the exposed area to blue light in the epidermal cell of Vallisneria gigantea

  • Sakurai, Nami;Domoto, Kikuko;Takagi, Shingo
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.326-328
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    • 2002
  • In many plant cells, the positions of chloroplasts change in response to changes in light conditions. In the epidermal cells of the aquatic angiosperm Vallisneria gigantea, the avoidance response of chloroplasts is induced specifically by irradiation with blue light of high intensity. Possible roles of actin cytoskeleton in the blue-light-induced avoidance response of chloroplasts were investigated by partial irradiation and phalloidin staining. We showed that the blue-light-dependent redistribution of chloroplasts was induced only in the limited area, where exposed to blue light, even in individual cells. In addition. in the exposed area, the configuration of actin filaments strikingly changed compared with that before the irradiation. Short and thick bundles of actin filaments surrounding the chloroplasts changed to much longer and thinner bundles with a more stretched array. In contrast, in the unexposed area, neither the distribution of chloroplasts nor the configuration of actin filaments exhibited any changes. Cytochalasin D and latrunculin B inhibited the avoidance response of chloroplasts concomitantly with the fragmentation of actin filaments. These results indicate that the reorganization of actin filaments plays a crucial role in the induction of avoidance response of chloroplasts.

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Organic-layer and semitransparent electrode thickness dependent optical properties of top-emission organic light-emitting diodes (전면 유기 발광 소자의 유기물층과 반투명 전극의 두께 변화에 따른 광학적 특성)

  • An, Hui-Chul;Joo, Hyun-Woo;Na, Su-Hwan;Han, Wone-Keun;Kim, Tae-Wan;Lee, Won-Jea;Chung, Dong-Hoe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.57-58
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    • 2008
  • We have studied an organic layer and semitransparent Al electrode thickness dependent optical properties and microcavity effects for top-emission organic light-emitting diodes. Manufactured top-emission device structure is Al(100nm)/TPD(xnm)/Alq(ynm)/LiF(0.5nm)/Al(25nm). While a thickness of total organic layer was varied from 85nm to 165n, a ratio of those two layers was kept to be about 2:3. Semitransparent Al cathode was varied from 20nm to 30nm for the device with an organic layer total thickness of 140nm. As the thickness of total organic layer increases, the emission spectra show a shift of peak wavelength from 490nm to 580nm, and the full width at half maxima from 90nm to 35nm. The emission spectra show a blue shift as the view angle increases. Emission spectra depending on a transmittance of semitransparent cathode show a shift of peak wavelength from 515nm to 593nm. At this time, the full width at half maximum was about to be a constant of 50nm. With this kind of microcavity effect, we were able to control the emission spectra from the top-emission organic light-emitting diodes.

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