• Title/Summary/Keyword: Light absorption

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Thermal Degradation of BZO Layer on the CIGS Solar Cells

  • Choi, Pyungho;Kim, Sangsub;Choi, Byoungdeog
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.458-458
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    • 2013
  • We investigated a study on the thermal degradation of boron doped zinc-oxide (BZO) layer which used as a transparent conducting layer on the Cu (In1-xGax) Se2 (CIGS) based thin film solar cells. Devices were annealed under the temperature of $100^{\circ}C$ or 100 hours and then Hall measurement was carried out to characterize the parameters of mobility (${\mu}Hall$), resistivity (${\rho}$), conductivity (${\sigma}$) and sheet resistance (Rsh). The initial values of ${\mu}Hall$, ${\rho}$, ${\sigma}$ and Rsh were $29.3cm^2$/$V{\cdot}s$, $2.1{\times}10^{-3}{\Omega}{\cdot}cm$, $476.4{\Omega}^{-1}{\cdot}cm^{-1}$ and $19.1{\Omega}$/${\Box}$ respectively. After the annealing process, the values were $4.5cm^2$/$V{\cdot}s$, $12.8{\times}10^{-3}{\Omega}{\cdot}cm$, $77.9{\Omega}^{-1}{\cdot}cm^{-1}$ and $116.6{\Omega}$/${\Box}$ respectively. We observed that ${\mu}Hall$ and ${\sigma}$ were decreased, and ${\rho}$ and Rsh were increased. In this study, BZO layer plays an important role of conducting path for electrons generated by incident light onthe CIGS absorption layer. Therefore, the degradation of BZO layer characterized by the parameters of ${\mu}Hall$, ${\rho}$, ${\sigma}$ and Rsh, affect to the cell efficiency.

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Bias-Dependent Photoluminescence Analysis on InGaN/GaN MQW Solar Cells

  • Shim, Jae-Phil;Jeong, Hoonil;Choi, Sang-Bae;Song, Young Ho;Jho, Young-Dahl;Lee, Dong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.347-348
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    • 2013
  • To obtain high conversion efficiency in InGaN-based solar cells, it is critical to grow high indium (In) composed InGaN layer for increasing sun light absorption wavelength rage. At present, most InGaN-based solar cells adopt InGaN/GaN multi-quantum-well (MQW) structure for high crystalline quality of InGaN with high In composition. In this study, we fabricated and compared the performances of two types of InGaN/GaN MQW solar cells which have the 15% (SC 15) and 25% (SC 25) of In composition at quantum well layer. Although both devices showed similar dark current density and leakage current, SC 15 showed better performance under AM 1.5G illumination as shown in Fig. 1. It is interesting to note that SC 25 showed severe current density decrease as increasing voltages. As a result, it lowered short circuit current density and fill factor of the device. However, SC 15 showed steady current density and over 75 % of fill factor. To investigate these differencesmore clearly, we analyzed their photoluminescence (PL) spectra under various applied voltages as shown in Fig. 2. At the same time, photocurrent, which was generated by PL excitation, was also measured as shown in Fig. 3. Further, we investigated the relationship between piezoelectric field and performance of InGaN based solar cell varying indium composition.

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Physicochemical Characterization of Chlorosome Isolated from Chlorobium limicola f. thiosulfatophilum NCIB 8327 (Chlorobium limicola f. thiosulfatophilum NCIB 8327에서 분리한 Chlorosomes의 물리화학적 특성)

  • Na, Jong-Uk;Yoon, Hwan;Kang, Sa-Ouk
    • Korean Journal of Microbiology
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    • v.31 no.1
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    • pp.9-16
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    • 1993
  • Physicochemical characteristics of chlorosomes isolated from Chlorobium lirnicoh f.thiosulfirtc~pl~ilut~i NClB 8327 were analyzed by means of UV-Visible spectrophotometer and CD-spectrophotometer. The density of the isolated chlorosomes were estimated to be 1.05 (g/$cm^{3}$) by Percoll self gradient ultracentrifugation. Chlorosome consist of bacteriochlorophyll d and some chlorobactene, and little amounl of bacteriochlorophyll a. Chlorosome is stable from 0 to $80^{\circ}C$and alkaline solution (above pH 7.0). but unstable in illuminated condition. From these results. it is suggested that some proteins or lipids may be essential for the stabilization of chlorosomes in vivo.

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Antimicrobial Characteristics of Yellow-Pigment Produced by Monascus anka Y7 (Monascus anka Y7이 생성하는 황색소의 항균 특성)

  • 이호재;박미연
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.2
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    • pp.338-342
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    • 2002
  • Antimicrobial activity of yellow pigment produced by Monascus anka Y7 (Y7) was studied. The crude yellow pigment of Y7 showed antimicrobial activity against some bacteria and yeasts. The diameter of inhibition zone against gram-positive bacteria was a little smaller t]fan that of gram-negative bacteria to the crude yellow pigment. Especially, E2 fraction obtained from the crude yellow pigment by TLC method showed high anti-microbial activity against E. coli.. The fraction had bright yellow pigment, showing fluorescent light and having the maximum absorption at 373 nm. Citrinin, a mycotoxin which had been characterized as an antimicrobial substance from a Monascus strain, was not detected in the E2 fraction and in the crude yellow pigment by the results of TLC and HPLC. This indicates that the antimicrobial activity of Y7 pigments did not any relationship with citrinin. Yellow degree (b/a of Hunters color value) of Y7 pigment was much higher than that of other natural colorants such as annatto, gardenia yellow and carthamus yellow. But the colors of all of the yellow pigments were similar by panels. Thus, the yellow pigment of Y7 could be used as a useful alternative colorant for food industry, having the advantage of antimicrobial activity.

Dynamic Rapid Synthesis of Bis(2,2'-bipyridine)nitrato Zinc (II) Nitrate Using a Microwave Method and its Application to Dye-Sensitized Solar Cells (DSSC)

  • Kim, Young-Mi;Kim, Su-Jung;Nahm, Kee-Pyung;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2923-2928
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    • 2010
  • This study examined the synthesis of the crystal structure of bis(2,2'-bipyridine)nitrato zinc (II) nitrate, $[Zn(bipy)_2(NO_3)]^+NO_3^-$ using a microwave treatment at 300 W and 60 Hz for the application to dye-sensitized solar cells. The simulated complex structure of the complex was optimized with the density functional theory calculations for the UV-vis spectrum of the ground state using Gaussian 03 at the B3LYP/LANL2DZ level. The structure of the acquired complex was expected a penta-coordination with four nitrogen atoms of bipyridine and the oxygen bond of the $NO_3^-$ ion. The reflectance UV-vis absorption spectra exhibited two absorptions (L-L transfers) that were assigned to the transfers from the ligand ($\sigma$, $\pi$) of $NO_3$ to the ligand ($\sigma^*$, $\pi^*$) of pyridine at around 200 - 350 nm, and from the non-bonding orbital (n) of O in $NO_3$ to the p-orbital of pyridine at around 450 - 550 nm, respectively. The photoelectric efficiency was approximately 0.397% in the dye-sensitized solar cells with the nanometer-sized $TiO_2$ at an open-circuit voltage (Voc) of 0.39 V, a short-circuit current density (Jsc) of $1.79\;mA/cm^2$, and an incident light intensity of $100\;mW/cm^2$.

Effect of salicylic acid and its analogues on stomatal closing in Commelina communis L. (닭의장풀의 기공닫힘에 미치는 살리실릭산과 그 유사물의 효과)

  • Joon-Sang Lee
    • Journal of Environmental Science International
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    • v.4 no.4
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    • pp.15-15
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    • 1995
  • ABA and SA showed different effect on stomatal closing on same condition. The addition of 1 M salicylic acid to fully opened stomata resulted in a significant reductionn of 22 % in stomatal aperture. However, 1 mM ABA reduced 73 % of stomatal aperture. The light absorption spectra of the salicylic acid solution showed that SA was degraded within 1 hour. Therefore, SA solution was resupplied % the detached epidermis every 30 min. during incubation and it was found that even at 10 $mu$M SA induced stomatal closing significantly. Its effect was also greatly pH dependent. The reduction of stomatal aperture caused by 1 mM SA was most effective at lower pH (pH 7.2, 5 %: pH 6.2, 40 %; pH 5.2, 78 %). Therefore, if SA was properly treated to the epidermal strips in the medium, the effects of SA on stomatal closing were similar with those of ABA.

Effect of salicylic acid and its analogues on stomatal closing in Commelina communis L. (닭의장풀의 기공닫힘에 미치는 살리실릭산과 그 유사물의 효과)

  • 이준상
    • Journal of Environmental Science International
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    • v.4 no.4
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    • pp.317-321
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    • 1995
  • ABA and SA showed different effect on stomatal closing on same condition. The addition of 1 M salicylic acid to fully opened stomata resulted in a significant reductionn of 22 % in stomatal aperture. However, 1 mM ABA reduced 73 % of stomatal aperture. The light absorption spectra of the salicylic acid solution showed that SA was degraded within 1 hour. Therefore, SA solution was resupplied % the detached epidermis every 30 min. during incubation and it was found that even at 10 $\mu$M SA induced stomatal closing significantly. Its effect was also greatly pH dependent. The reduction of stomatal aperture caused by 1 mM SA was most effective at lower pH (pH 7.2, 5 %: pH 6.2, 40 %; pH 5.2, 78 %). Therefore, if SA was properly treated to the epidermal strips in the medium, the effects of SA on stomatal closing were similar with those of ABA.

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Upgrade of Neutron Energy Spectrometer with Single Multilayer Bonner Sphere Using Onion-like Structure

  • Mizukoshi, Tomoaki;Watanabe, Kenichi;Yamazaki, Atsushi;Uritan, Akira;Iguchi, Tetsuo;Ogata, Tomohiro;Muramatsu, Takashi
    • Journal of Radiation Protection and Research
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    • v.41 no.3
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    • pp.185-190
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    • 2016
  • Background: In order to measure neutron energy spectra, the conventional Bonner Sphere Spectrometers (BSS) are widely used. In this spectrometer, several measurements with different size Bonner spheres are required. Operators should, therefore, place these spheres in several times to a measurement point where radiation dose might be relatively high. In order to reduce this effort, novel neutron energy spectrometer using an onion-like single Bonner sphere was proposed in our group. This Bonner sphere has multiple sensitive spherical shell layers in the single sphere. In this spectrometer, a band-shaped thermal neutron detection medium, which consists of a LiF-ZnS mixed powder scintillator sheet and a wavelength-shifting (WLS) fiber readout, was looped to each sphere at equal angular intervals. Amount of LiF neutron converter is reduced near polar region, where the band-shaped detectors are concentrated, in order to uniform the directional sensitivity. The LiF-ZnS mixed powder has an advantage of extremely high light yield. However, since it is opaque, scintillation photons cannot be collect uniformly. This type of detector shows no characteristic shape in the pulse height spectrum. Subsequently, it is difficult to set the pulse height discrimination level. This issue causes sensitivity fluctuation due to gain instability of photodetectors and/or electric modules. Materials and Methods: In order to solve this problem, we propose to replace the LiF-ZnS mixed powder into a flexible and Transparent RUbber SheeT type $LiCaAlF_6$ (TRUST LiCAF) scintillator. TRUST LiCAF scintillator can show a peak shape corresponding to neutron absorption events in the pulse height spectrum. Results and Discussion: We fabricated the prototype detector with five sensitive layers using TRUST LiCAF scintillator and conducted basic experiments to evaluate the directional uniformity of the sensitivity. Conclusion: The fabricated detector shows excellent directional uniformity of the neutron sensitivity.

Application of Ceramic Aggregate for Ultra-High Strength Concrete (초고강도 콘크리트 제조를 위한 세라믹골재 개발)

  • Kim, Song-Ho;Kang, Suk-Hwa;Song, Yong-Soon;Kim, Kang-Min
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.389-392
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    • 2008
  • Ultra-high strength concrete becomes one of the main research areas because recently concrete structure is larger. The quality of aggregate (ultra-high strength and uniformity) as well as chemical admixture and mineral additives is a key factor for ultra-high strength concrete development. However, natural aggregate including crushed aggregate is inappropriate for ultra-high strength concrete because ultra-high strength quality cannot be maintained uniformly over whole natural aggregate lot. In this study ceramic aggregate was applied for ultra-high strength concrete in order to assure uniform quality of ultra-high strength aggregate. Ultra-high strength concrete was achieved by applying coated ultra-high strength ceramic aggregate to enhance the bonding strength between aggregate and cement paste. Also for actual application light weight ceramic aggregate(density 2.2 $g/cm^3$) with zero water absorption was tested.

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The Analysis of Successional Trends by Community Types in the Natural Deciduous Forest of Mt. Jumbong (점봉산 일대 천연활엽수림의 군집 유형별 천이 경향 분석)

  • Jin, Guang Ze;Kim, Ji Hong
    • Journal of Korean Society of Forest Science
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    • v.94 no.6
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    • pp.387-396
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    • 2005
  • Having employed the transitional probability model based on Markov chain, the study was carried out to examine successional trends for community types in the natural deciduous forest of Mt. Jumbong. The species composition of oncoming generation in overstory was estimated from that of mid-story, and the species composition in mid-story was based upon that of understory. Successional trend for each community was predicted from the reorganized probability matrix of tree replacement by the square of climax index, which was evaluated by the factors of light absorption, reproduction, and wood quality. As the result of analysis, following table shows the oncoming generation of steady state and dominant species in overstory and mid-story by community types. Even though Acer pseudo-sieboldianum and Carpinus cordata could hardly reach the canopy layer due to the intrinsic growth form, these species were predicted to maintain high compositional ratio so as to play an important ecological role in the study forest ecosystem.