• Title/Summary/Keyword: Li-ferrite

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Enhanced Piezoelectric Properties of (1-x)[0.675BiFeO3-0.325BaTiO3]-xLiTaO3 Ternary System by Air-Quenching

  • Akram, Fazli;Malik, Rizwan Ahmed;Lee, Soonil;Pasha, Riffat Asim;Kim, Myong Ho
    • Korean Journal of Materials Research
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    • v.28 no.9
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    • pp.489-494
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    • 2018
  • Lead free $(1-x)(0.675BiFeO_3-0.325BaTiO_3)-xLiTaO_3$ (BFBTLT, x = 0, 0.01, 0.02, and 0.03, with 0.6 mol% $MnO_2$ and 0.4 mol% CuO) were prepared by a solid state reaction method, followed by air quenching and their crystalline phase, morphology, dielectric, ferroelectric and piezoelectric properties were explored. An X-ray diffraction study indicates that lithium (Li) and tantalum (Ta) were fully incorporated in the BFBT materials with the absence of any secondary phases. Dense ceramic samples (> 92 %) with a wide range of grain sizes from $3.70{\mu}m$ to $1.82{\mu}m$ were obtained in the selected compositions ($0{\leq}x{\leq}0.03$) of BFBTLT system. The maximum temperatures ($T_{max}$) were mostly higher than $420^{\circ}C$ in the studied composition range. The maximum values of maximum polarization ($P_{max}{\approx}31.01{\mu}C/cm^2$), remnant polarization ($P_{rem}{\approx}22.82{\mu}C/cm^2$) and static piezoelectric constant ($d_{33}{\approx}145pC/N$) were obtained at BFBT-0.01LT composition with 0.6 mol% $MnO_2$ and 0.4 mol% CuO. This study demonstrates that the high $T_{max}$ and $d_{33}$ for BFBTLT ceramics are favorable for industrial applications.

Effects of $Nb_2O_5$ and $V_2O_5$ Additions on the Sintering Behavior and B-H Loop Properties of Lithium Ferrite ($Nb_2O_5$$V_2O_5$의 첨가가 Lithium Ferrite의 소결현상과 B-H Loop 특성에 미치는 영향)

  • 김현태;임호빈
    • Journal of the Korean Ceramic Society
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    • v.19 no.4
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    • pp.267-274
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    • 1982
  • The sintering behavior and B-H loop properties of $Li_{0.5O4}$ with the addition of $Nb_2O_5$ and $V_2O_5$ have been investigated by observation of microstructures and measurement of semi-static hysteresis loops. The sintering temperature was lowered by the additions of $Nb_2O_5$ and $V_2O_5$ and the effect of $V_2O_5$ addition was greater than that of $Nb_2O_5$. The abnormal grain growth was observed at about 100$0^{\circ}C$(d:4.6g/㎤) and 85$0^{\circ}C$(d:4.5g/㎤) in the specimens with the addition of $Nb_2O_5$ and $V_2O_5$ respectively. The addition of $Nb_2O_5$ retulted in a large and uniform grain size, and the addition of $V_2O_5$ resulted in a uniform grain size but the final density was lower than that of the pure specimen. The squareness was increased and the coercive force was decreased by the addition of $Nb_2O_5$, and the squareness was decreased and the coercive force was increased by the addition of $V_2O_5$. These effects could be explained by a large and uniform grain size, and by a lower final density of specimens with the addition of $Nb_2O_5$ and $V_2O_5$ respectively.

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Effects of pulsed laser surface remelting on microstructure, hardness and lead-bismuth corrosion behavior of a ferrite/martensitic steel

  • Wang, Hao;Yuan, Qian;Chai, Linjiang;Zhao, Ke;Guo, Ning;Xiao, Jun;Yin, Xing;Tang, Bin;Li, Yuqiong;Qiu, Shaoyu
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.1972-1981
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    • 2022
  • A typical ferritic/martensitic (F/M) steel sheet was subjected to pulsed laser surface remelting (LSR) and corrosion test in lead-bismuth eutectic (LBE) at 550 ℃. There present two modification zones with distinct microstructures in the LSRed specimen: (1) remelted zone (RZ) consisting of both bulk δ-ferrite grains and martensitic plates and (2) heat-affected zone (HAZ) below the RZ, mainly composed of martensitic plates and high-density precipitates. Martensitic transformation occurs in both the RZ and the HAZ with the Kurdjumov-Sachs and Nishiyama-Wassermann orientation relationships followed concurrently, resulting in scattered orientations and specific misorientation characteristics. Hardnesses of the RZ and the HAZ are 364 ± 7 HV and 451 ± 15 HV, respectively, considerably higher than that of the matrix (267 ± 3 HV). In oxygen-saturated and oxygen-depleted LBE, thicknesses of oxide layers developed on both the as-received and the LSRed specimens increase with prolonging corrosion time (oxide layers always thinner under the oxygen-depleted condition). The corrosion resistance of the LSRed F/M steel in oxygen-saturated LBE is improved, which can be attributed to the grain-refinement accelerated formation of dense Fe-Cr spinel. In oxygen-depleted LBE, the growth of oxide layers is very low with both types of specimens showing similar corrosion resistance.

Roughness and micro pit defects on surface of SUS 430 stainless steel strip in cold rolling process

  • Li, Changsheng;Zhu, Tao;Fu, Bo;Li, Youyuan
    • Advances in materials Research
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    • v.4 no.4
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    • pp.215-226
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    • 2015
  • Experiment on roughness and micro pit defects of SUS 430 ferrite stainless steel was investigated in laboratory. The relation between roughness and glossiness with reduction in height, roll surface roughness, emulsion parameters was analyzed. The surface morphology of micro pit defects was observed by SEM, and the effects of micro pit defects on rolling reduction, roll surface roughness, emulsion parameters, lubrication oil in deformation zone and work roll diameter were discussed. With the increasing of reduction ratio strip surface roughness Ra(s), Rp(s) and Rv(s) were decreasing along rolling and width direction, the drop value in rolling direction was faster than that in width direction. The roughness and glossiness were obtained under emulsion concentration 3% and 6%, temperature $55^{\circ}C$ and $63^{\circ}C$, roll surface roughness $Ra(r)=0.5{\mu}m$, $Ra(r)=0.7{\mu}m$ and $Ra(r)=1.0{\mu}m$. The glossiness was declined rapidly when the micro defects ratio was above 23%. With the pass number increasing, the micro pit defects were reduced, uneven peak was decreased and gently along rolling direction. The micro pit defects were increased with the roll surface roughness increase. The defects ratio was declined with larger gradient at pass number 1 to 3, but gentle slope at pass number 4 to 5. When work roll diameter was small, bite angle was increasing, lubrication oil in micro pit of deformation zone was decreased, micro defects were decreased, and glossiness value on the surface of strip was increased.

A Novel IPT System Based on Dual Coupled Primary Tracks for High Power Applications

  • Li, Yong;Mai, Ruikun;Lu, Liwen;He, Zhengyou
    • Journal of Power Electronics
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    • v.16 no.1
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    • pp.111-120
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    • 2016
  • Generally, a single phase H-bridge converter feeding a single primary track is employed in conventional inductive power transfer systems. However, these systems may not be suitable for some high power applications due to the constraints of the semiconductor switches and the cost. To resolve this problem, a novel dual coupled primary tracks IPT system consisting of two high frequency resonant inverters feeding the tracks is presented in this paper. The primary tracks are wound around an E-shape ferrite core in parallel which enhances the magnetic flux around the tracks. The mutual inductance of the coupled tracks is utilized to achieve adjustable power sharing between the inverters by configuring the additional resonant capacitors. The total transfer power can be continuously regulated by altering the pulse width of the inverters' output voltage with the phase shift control approach. In addition, the system's efficiency and the control strategy are provided to analyze the characteristic of the proposed IPT system. An experimental setup with total power of 1.4kW is employed to verify the proposed system under power ratios of 1:1 and 1:2 with a transfer efficiency up to 88.7%. The results verify the performance of the proposed system.

A New Type of CPPM Machine with Stator Axial Magnetic Ring

  • Xie, Kun;Li, Xinhua;Ma, Jimin;Wu, Xiaojiang;Yi, Hong;Hu, Gangyi
    • Journal of Electrical Engineering and Technology
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    • v.13 no.3
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    • pp.1285-1293
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    • 2018
  • This paper proposes a new type of consequent-pole permanent-magnet (CPPM) machine with stator axial magnetic ring that increases torque capability over a wide speed range and enhances efficiency for the built-in rare-earth permanent magnet synchronous machine used in new energy vehicles. The excitation winding of the CPPM hybrid excitation synchronous machine in the stator is replaced by ferrite magnetic ring to simplify the structure and manufacturing process of the machine. The basic structure and magnetic regulation principle of the proposed machine are introduced and compared with the traditional interior rare-earth permanent magnet synchronous machine and CPPM hybrid excitation synchronous machine. Finally, experimental results of a new type of CPPM synchronous motor prototype with axial magnetic ring are introduced in the paper.

BiFeO3-based Lead-free Piezoelectric Ceramics (비스무스 페라이트계 무연 압전 세라믹스)

  • Choi, Jin-Hong;Kim, Hyun-Ah;Han, Seung-Ho;Kang, Hyung-Won;Lee, Hyeung-Gyu;Kim, Jeong-Seog;Cheon, Chae-Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.9
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    • pp.692-701
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    • 2012
  • Recently, many lead-free piezoelectric materials have been investigated for the replacement of existing Pb-based piezoelectric ceramics because of globally increasing environmental interest. There has been remarkable improvement in piezoelectric properties of some lead-free ceramics such as $(Bi,Na)TiO_3-(Bi,K)TiO_3-BaTiO_3$, $(Na,K)NbO_3-LiSbO_3$, and so on. However, no one still has comparable piezoelectric properties to lead-based materials. Therefore, new lead-free piezoelectric ceramics are required. $BiFeO_3$ has a rhombohedrally distorted perovskite structure at room temperature and a very high Curie temperature ($T_C$= 1,100 K). And a very large electric polarization of 50 ~ 60 ${\mu}C/cm^2$ has been reported both in epitaxial thin film and single crystal $BiFeO_3$. Therefore, a high piezoelectric effect is expected also in a $BiFeO_3$ ceramics. The recent research activities on $BiFeO_3$ or $BiFeO_3$-based solid solutions are reviewed in this article.

Fabrication and magnetic properties of hexagonal BaFe12O19 ferrite obtained by magnetic-field-assisted hydrothermal process

  • Zhang, Min;Dai, Jianming;Liu, Qiangchun;Li, Qiang;Zi, Zhenfa
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1426-1430
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    • 2018
  • High magnetic field effects on the microstructure and magnetic properties of $BaFe_{12}O_{19}$ hexaferrites synthesized hydrothermal method have been investigated. The obtained results indicate that the lattice constant decreases gradually as the magnetic field strength increases, which may be attributed to the lattice distortion resulted from the high magnetic field. Polycrystalline $BaFe_{12}O_{19}$ samples prepared under magnetic field strength at zero and 5 T are single phase. It is found that application of external magnetic field during synthesis can induce orientated growth of the hexaferrite crystals along the easy magnetic axis. The magnetic properties can be effectively regulated by an application of high magnetic fields. It is observed that the $BaFe_{12}O_{19}$ prepared under a 5 T magnetic field exhibits a higher room-temperature saturation magnetization (66.3 emu/g) than that of the sample (43.6 emu/g) obtained without magnetic field. The results can be explained as the enhanced crystalline, improvement of $Fe^{3+}$ ions occupancy and the oriented growth induced by the external magnetic field. The growing orientation of particles gives rise to increased coercivity due to the enhancement in shape anisotropy. It is expected that an application of magnetic field during the formation of magnetic nanoparticles could be a promising technique to modify magnetic properties with excellent performance.

A Study OH Mossbauer Spectra Of the $Li_{0.5}Fe_{2.5-x}Al_xO_4$ Ferrite System (Li_{0.5}Fe_{2.5-x}Al_xO_4 페라이트계의 Mossbauer 스펙트럼 연구)

  • 백승도
    • Journal of the Korean Magnetics Society
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    • v.11 no.2
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    • pp.58-62
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    • 2001
  • The L $i_{0.5}$F $e_{2.5-x}$A $l_{x}$ $O_4$ systems (x=0, 0.3, 0.6, 0.9, 1.2, 1.5) were investigated by X-ray diffraction and Mossbauer spectroscopy. The structure of all the samples is cubic spinel type and lattice constant decrease with increasing Al content x. The Moissbauer spectra reveal two sextet for 0$\leq$x$\leq$0.6, two sextet and a doublet for 0.9$\leq$x$\leq$1.2, and a doublet for x=1.5. The cation distribution of the samples is (L $i_{1-a}$$^{+}$F $e_{a}$ $^{3+}$)$^{A}$[L $i_{a-0.5}$$^{+}$A $l_{2.5-a-x}$$^{+}$F $e_{2.5-a-x}$$^{3+}$]$^{B}$ $O_4$$^{2-}$ and substituted $Al^{3+}$ ions decrease the covalency of F $e^{3+}$- $O^{2-}$ bond in B-sites and A-B super-exchange interactions.tions.s.tions.ons.s.

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Development of Thermoluminescence and Optical Stimulated Luminescence Measurements System (열자극발광 및 광자극발광 측정장치의 개발)

  • Park, Chang-Young;Chung, Ki-Soo;Lee, Jong-Duk;Chang, In-Su;Lee, Jungil;Kim, Jang-Lyul
    • Journal of Radiation Protection and Research
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    • v.40 no.1
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    • pp.46-54
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    • 2015
  • The thermoluminescence (TL) and optically stimulated luminescence (OSL) are commonly used to measure and record the expose of individuals to ionization radiation. Design and performance test results of a newly developed TL and OSL measurement system are presented in this paper. For this purpose, the temperature of the TL material can be controlled precisely in the range of $1{\sim}1.5^{\circ}C$ by using high-frequency (35 kHz) heating system. This high-frequency power supply was made of transformer with ferrite core. For optical stimulation, we have completed an optimal combination of the filters with the arrangement of GG420 filter for filtering the stimulating light source and a UG11 filter at the detecting window (PMT). By using a high luminance blue LED (Luxeon V), sufficient luminous intensity could be obtained for optical stimulation. By using various control boards, the TL/OSL reader device was successfully interfaced with a personal computer. A software based on LabView program (National Instruments, Inc.) was also developed to control the TL/OSL reader system. In this study, a multi-functional TL/OSL dosimeter was developed and the performance testing of the system was carried out to confirm its reliability and reproducibility.