• Title/Summary/Keyword: Li-Ion

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Dispersion of Li[Ni0.2Li0.2Mn0.6]O2 Powder by Surfactant for High-power Li-ion Cell

  • Yun, Su-Hyun;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1598-1602
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    • 2009
  • The particle size of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode powder was controlled effectively by dispersion using lauric acid as a surfactant. The samples treated by lauric acid showed smaller particles of approximately half the original size compared to the particles of a pristine sample. A structural change due to the dispersion of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ powder was not detected. The rate performance of the Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode was improved by dispersion using lauric acid, which was likely due to the decrease of the particle size. In particular, a sample dispersed pristine powder using lauric acid (L2) presented a greatly enhanced discharge capacity and capacity retention at a high C rate. The discharge capacity of a pristine sample was only 133 m$Ahg^{-1}$ (3C rate) and 96 m$Ahg^{-1}$ (12C rate) at the tenth cycle. In contrast, the L2 electrode delivered higher discharge capacities of 160 m$Ahg^{-1}$ (3C rate) and 129 m$Ahg^{-1}$ (12C rate) at the tenth cycle. The capacity retention at a rate of 12C/2C was also enhanced from ~ 45% (pristine sample) to 57% (L2) by treatment with lauric acid.

The AC impedance of $LiM_{y}Mn_{2-y}O_{4}$cathode material by charge and discharge temperature (충방전 온도에 따른 $LiM_{y}Mn_{2-y}O_{4}$정극 활물질의 임피던스 특성 분석)

  • 정인성;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.351-354
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    • 2000
  • AC impedance of LiM $n_2$ $O_4$ and LiM $g_{0.1}$M $n_{1.9}$ $O_4$ samples have been studied at various temperature with charge-discharge test. AC impedance of LiM $n_2$ $O_4$ measured at -2$0^{\circ}C$, room temperature and 5$0^{\circ}C$ revealed that initial impedance before charge-discharge test was gradually decreased and become small by becoming law temperature. It indicates that the Li ion diffusion and the transfer resistance of the cathode are related to the temperature of cycling. Impedance at high temperature was suddenly increased because Mn dissolution and decomposition of electrolyte had been increased during cycling, compared to impedance at low temperature. Therefore, charge-discharge capacity was suddenly decreased at high but was slowly at low. In LiM $g_{0.1}$M $n_{1.9}$ $O_4$, impedance and capacity were stability at room temperature than there at 5$0^{\circ}C$, too. Initial impedance at 5$0^{\circ}C$ before charge-discharge test was small and impedance was suddenly increased during cycling than that at room temperature.ure.ure.

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Electrochemical properties of $LiFePO_4$ cathode materials by hydrothermal route

  • Jin, Bo;Li, Hu;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.363-364
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    • 2007
  • Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction at different temperatures. The structural performance of $LiFePO_4$ powders were characterized by X-ray diffraction (XRD). $LiFePO_4$/Li batteries were characterized electrochemically by charge/discharge experiments. The XRD results demonstrate that $LiFePO_4$ powder has an orthorhombic olivine-type structure with a space group of Pnmb. Among the synthesized cathode materials, $LiFePO_4$synthesized at $170^{\circ}C$ and subsequently annealed at $500^{\circ}C$ shows the best electrochemical properties. It shows initial discharge capacity of $167\;mAh\;g^{-1}$ (98% of the theoretical capacity) close to the theoretical capacity of $LiFePO_4$ ($170\;mAh\;g^{-1}$) at 0.1 C rate, which is ascribed to the enhanced degree of crystallinity, better phase purity, more spherical and more finely dispersed nanoparticles, crystallization and activation of small amount impurity.

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Analysis of the Output Ripple of the DC-DC Boost Charger for Li-Ion Batteries

  • Nguyen, Van-Sang;Tran, Van-Long;Choi, Woojin;Kim, Dae-Wook
    • Journal of Power Electronics
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    • v.14 no.1
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    • pp.135-142
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    • 2014
  • In the design of battery chargers, limiting the output ripple current according to the manufacturer's recommendation is important for reliable service and extended battery life. Ripple components can cause internal heating of the battery and thus reduce the service life of the battery. Care must be exerted in the design of the switching converter for the charge application through the accurate estimation of the output current ripple value. This study proposes a method to reduce the output current ripple of the converter and presents a detailed analysis of the output current ripple of the DC-DC boost converter to provide a guideline for the design of the battery charger.

하이브리드커패시터용 활성탄전극의 리튬도핑에 따른 전기화학적 거동

  • Jo, Min-Yeong;No, Gwang-Cheol;Lee, Jae-Won;Park, Seon-Min;Lee, Dong-Ryeol;Han, Sang-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.266-266
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    • 2009
  • For the development of hybrid supercapacitor, increasing energy density is one of the most crucial matters. Since the energy density is the function of capacitance and voltage, it is necessary to enhance energy density for increasing capacitance or voltage. For the high working voltage, it was to enforce Li ion free-doping to activated carbon. As a result, initial capacitance has increased by 11% than raw cell. But capacitance has decreased by Li ion re-solution to electrolyte for increase the number of cycle.

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Study on the Manufacturing of Compact Electronic Shaker for Vibration Test (진동 시험용 소형 전자식 가진기 제작에 관한 연구)

  • Joo, Kangwo;Lee, Jaegyoung;Lee, Bonggun;Yoon, Hyejun;Kim, Kwang sun
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.31-37
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    • 2015
  • This paper is on the design and manufacturing of vibration tester (shaker) for experiments about effects on the performance of semiconductor chips and Li-ion batteries by vibration. Shaker in the market are quite expensive, it is difficult for basic researchers to contact. In this study, in order to improve this, we designed and manufactured with an entry-level into mass production possible approaches in terms of performance required to a minimum. The shaker system is operated by Matlab and LabView. The target performances are 200Hz frequency and 5% error, and these were satisfied.

Development of Target-Controlled Infusion system in Plasma Concentration. PART2: Design and Evaluation (혈중 목표 농도 자동 조절기(TCI) 개발 PART2: 시스템 구현 및 평가)

  • 안재목
    • Journal of Biomedical Engineering Research
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    • v.24 no.1
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    • pp.45-53
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    • 2003
  • Based on the 4-compartmental pharmacokinetic model developed in PART1, target-controlled infusion(TCI) pump system was designed and evaluated. The TCI system consists of digital board including microcontroller and digital signal process(DSP), analog board, motor-driven actuator, user friendly interface, power management and controller. It provides two modes according to the drugs: plasma target concentration and effect target concentration. Anaesthetist controls the depth of anaesthesia for patients by adjusting the required concentration to maintain both plasma and effect site in drug concentration. The data estimated in DSP include infusion rate, initial load dose, and rotation number of motor encoder. During TCI operation, plasma concentration. effect site concentration, awaken concentration, context-sensitive decrement time and system error information are displayed in real time. Li-ion battery guarantees above 2 hours without power line failure. For high reliability of the system, two microprocessors were used to perform independent functions for both pharmacokinetic algorithm and motor control strategy.

Analysis on the Output Ripple of the Non-isolated Boost Charger for the Li-ion Battery

  • Nguyen, Van Sang;Choi, Woojin
    • Proceedings of the KIPE Conference
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    • 2012.11a
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    • pp.46-47
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    • 2012
  • In the design of the battery charger it is important to limit the ripple current and voltage according to the manufacturer's recommendation for the reliable service and the extended life of the battery. However, it is often overlooked that these ripple components can cause internal heating of the battery, thereby reducing its service life. Thus the care must be taken in the design of the switching converter for the charge application through the accurate estimation of the output ripple values. In this research analysis on the output ripple of the dc-dc converter is detailed to provide a guideline for the design of the battery charger.

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A Design of Charger IC for Li-Ion Battery (리튬-이온 배터리 충전 IC의 설계)

  • 이신우;임신일
    • Proceedings of the IEEK Conference
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    • 2003.07b
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    • pp.895-898
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    • 2003
  • 본 논문에서는 휴대폰에 사용하는 리튬-이론 배터리(Li-Ion battery)를 충전하기 위한 충전 IC 의 설계에 대해서 기술한다. 정전류(Constant Current)/ 정전압 (Constant Voltage) 방식을 이용하여 리튬-이론 배터리를 충전을 하였다. 이 충전 과정을 제어하기 위해서 일반적으로 사용되는 ADC, DAC 와 MICOM 을 사용하지 않고, hardwired control logic 을 이용하여 적은 면적을 가지고도 기존의 충전 과정을 수행하도록 하였다. 충전 IC 외부에 사용되는 저항들을 내부에 집적하여 사용하는 부품의 수를 현저히 줄였다. 충전기와 리튬-이온 배터리를 연결하는 선(wire)로 저항에 의한 전압강하(voltage drop)를 외부에서 보상할 수 있도록하여 리튬-이온 배터리가 가장 안정적인 전압인 4.2 V로 충전 될 수 있도록 하였다. 외부 온도 검사 블록에서 저항을 이용한 전압 분배를 사용하지 않고, 정전류원을 이용하여 외부 온도 변화를 측정할 수 있도록 하였다. 리튬-이온 배터가 전정류와 정전압으로 4.2 V로 충전 되었으며, 충전 IC 의 소비 전력은 37 mW(analog part)이다. 충전 IC는 0.6 ㎛ standard CMOS 공정을 이용하여 설계하였다.

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HEV: A Review (하이브리드 전기 자동차(HEV) 기술동향)

  • Nah, Do-Baek;Shin, Hyo-Soon
    • Journal of Energy Engineering
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    • v.19 no.1
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    • pp.39-50
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    • 2010
  • Hybrid Electric Vehicle(HEV) and Plug-in Hybrid Electric Vehicle(PHEV) will replace Conventional Gasolene Engine Vehicle at a rapid rate to eliminate emission gases and improve fuel economy. This review describes Fuzzy Logic Control strategy and Optimization for Parallel Hybrid Electric Vehicle. Recent progress on Electric Motor and Li-ion Battery for HEV and PHEV are given. Analysis on competitiveness of Korean HEV and PHEV technology based on the number of papers published and patents registered are also performed.