• Title/Summary/Keyword: Li extraction

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Solvent Extraction of Co(II) and Cu(II) from Hydrochloric Acid Solution of Spent Lithium-ion Batteries Containing Li(I), Mn(II), and Ni(II) (Li(I), Mn(II) 및 Ni(II)를 함유한 폐리튬 이온 배터리의 염산침출용액에서 Co(II) 및 Cu(II)의 용매 추출)

  • Le, Minh Nhan;Lee, Man Seung
    • Resources Recycling
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    • v.29 no.5
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    • pp.73-80
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    • 2020
  • In order to develop a process for the recovery of valuable metals from spent LiBs, solvent extraction experiments were performed to separate Cu(II) and/or Co(II) from synthetic hydrochloric acid solutions containing Li(I), Mn(II), and Ni(II). Commercial amines (Alamine 336 and Aliquat 336) were employed and the extraction behavior of the metals was investigated as a function of the concentration of HCl and extractants. The results indicate that HCl concentration affected remarkably the extraction efficiency of the metals. Only Cu(II) was selectively at 1 M HCl concentration, while both Co(II) and Cu(II) was extracted by the amines when HCl concentration was higher than 5 M, leaving the other metal ions in the raffinate. Therefore, it was possible to selectively extract either Cu(II) or Co(II)/Cu(II) by adjusting the HCl concentration.

EXTRACTING COMPLEX BUILDING FROM AIRBORNE LIDAR AND AIRBORNE ORTHIMAGERY

  • Nguyen, Dinh-Tai;Lee, Seung-Ho;Cho, Hyun-Kook
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.177-180
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    • 2008
  • Many researches have been tried to extract building models and created a 3D cyber city from LiDAR data. In this paper, the approach of extracting complex building by using airborne LiDAR data combined with airborne orthoimagery has been performed. The pseudo-building elevations were derived from modified discrete return LiDAR data. Based on information property of the pseudo-height, building features could be extracted. The results of this study indicated the improvement of building extraction.

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Recovery of Cobalt from Waste Cathodic Active Material Generated in Manufacturing Lithium Ion Batteries by Hydrometallugical Process (리튬이온전지 제조공정의 폐양극활물질로부터 습식제련공정에 의한 코발트의 회수)

  • Swain Basudev;Jeong Jinki;Kim Min Seuk;Lee Jae-chun;Sohn Jeong-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.28-36
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    • 2005
  • A hydrometallurgical process to leach cobalt from the waste cathodic active material, $LiCoO_{2}$, and subsequently to separate it by solvent extraction was developed. The optimum leaching conditions for high recovery of colbalt and lithium were obtained: 2.0 M sulfuric acid, 5 $vol.\%$ hydrogen peroxide, $75^{\circ}C$ leaching temperature, 30 minutes leaching time and an initial pulp density of 100 g/L. The respective leaching efficiencies for Co and Li were $93\%$ and $94.5\%$. About $85\%$ Co was extracted from the sulfuric acid leach liquor containing 44.72 g/L Co and 5.43 g/L Li, using 1.5 M Cyanex272 as an extractant at the initial pH 5.0 and in organic to aqueous phase ratio of 1.6:1 under the single stage extraction conditions. The Co in the raraffinate was completely extracted by 0.5 M Na-Cyanex272 at the inital pH 5.0, and an organic to aqueous phase ratio of 1;1. The cobalt sulfate solution of higher than $99.99\%$ purity could be recovered from waste $LiCoO_{2}$, using a series of hydrometallurgical processes: sulfuric acid leaching of waste $LiCoO_{2}$- solvent extraction of Co by Na-Cyanex 271 - scrubbing of Li by sodium carbonate solution - stripping of Co by sulfuric acid solution.

Simplification of LIDAR Data for Building Extraction Based on Quad-tree Structure

  • Du, Ruoyu;Lee, Hyo Jong
    • Proceedings of the Korea Information Processing Society Conference
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    • 2011.11a
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    • pp.355-356
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    • 2011
  • LiDAR data is very large, which contains an amount of redundant information. The information not only takes up a lot of storage space but also brings much inconvenience to the LIDAR data transmission and application. Therefore, a simplified method was proposed for LiDAR data based on quad-tree structure in this paper. The boundary contour lines of the buildings are displayed as building extraction. Experimental results show that the method is efficient for point's simplification according to the rule of mapping.

Automation of Building Extraction and Modeling Using Airborne LiDAR Data (항공 라이다 데이터를 이용한 건물 모델링의 자동화)

  • Lim, Sae-Bom;Kim, Jung-Hyun;Lee, Dong-Cheon
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.27 no.5
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    • pp.619-628
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    • 2009
  • LiDAR has capability of rapid data acquisition and provides useful information for reconstructing surface of the Earth. However, Extracting information from LiDAR data is not easy task because LiDAR data consist of irregularly distributed point clouds of 3D coordinates and lack of semantic and visual information. This thesis proposed methods for automatic extraction of buildings and 3D detail modeling using airborne LiDAR data. As for preprocessing, noise and unnecessary data were removed by iterative surface fitting and then classification of ground and non-ground data was performed by analyzing histogram. Footprints of the buildings were extracted by tracing points on the building boundaries. The refined footprints were obtained by regularization based on the building hypothesis. The accuracy of building footprints were evaluated by comparing with 1:1,000 digital vector maps. The horizontal RMSE was 0.56m for test areas. Finally, a method of 3D modeling of roof superstructure was developed. Statistical and geometric information of the LiDAR data on building roof were analyzed to segment data and to determine roof shape. The superstructures on the roof were modeled by 3D analytical functions that were derived by least square method. The accuracy of the 3D modeling was estimated using simulation data. The RMSEs were 0.91m, 1.43m, 1.85m and 1.97m for flat, sloped, arch and dome shapes, respectively. The methods developed in study show that the automation of 3D building modeling process was effectively performed.

Generation of Building and Contour Layers for Digital Mapping Using LiDAR Data (LiDAR 데이터를 이용한 수치지도의 건물 및 등고선 레이어 생성)

  • Lee Dong-Cheon;Yom Jae-Hong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.23 no.3
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    • pp.313-322
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    • 2005
  • Rapid advances in technology and changes in human and cultural activities bring about changes to the earth surface in terms of spatial extension as well as time frame of the changes. Such advances introduce shorter updating frequency of maps and geospatial database. To satisfy these requirements, recent research efforts in the geoinformatics field have been focused on the automation and speeding up of the mapping processes which resulted in products such as the digital photogrammetric workstation, GPSIINS, applications of satellite imagery, automatic feature extraction and the LiDAR system. The possibility of automatically extracting buildings and generating contours from airborne LiDAR data has received much attention because LiDAR data produce promising results. However, compared with the manually derived building footprints using traditional photogrammetric process, more investigation and analysis need to be carried out in terms of accuracy and efficiency. On the other hand, generation of the contours with LiDAR data is more efficient and economical in terms of the quality and accuracy. In this study, the effects of various conditions of the pre-processing phase and the subsequent building extraction and contour generation phases for digital mapping have on the accuracy were investigated.

Comparison of Soft Tissue Changes between Adolescents and Adults in Class II Malocclusion Treatment (청소년 및 성인 환자에서 II급 부정교합 치료시 연조직 변화에 관한 비교)

  • Chang, Na-Young;Cho, Jin-Hyoung;Lee, You-Mee;Kang, Kyung-Hwa
    • Journal of Oral Medicine and Pain
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    • v.34 no.3
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    • pp.277-294
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    • 2009
  • The purpose of this study was to evaluate the soft tissue changes of class II adolescents and adults in respect to extraction or nonextraction. The study included 68 patients from Wonkwang Dental Hospital were categorized to adolescent extraction group, adolescent nonextraction group, adult extraction group, adult nonextraction group. Cephalometric tracing of each patient was done to compare pretreatment and posttreatment of each group, to compare the changes between groups. And among the variables that showed significancy, correlation analysis and simple linear regression were done. The results were as follows. 1. In both adolescents and adults after extraction treatment, nasolabial angle significantly increased and in both subjects after non extraction treatment, nasolabial angle significantly decreased. 2. In extraction subjects, there were positive correlation between the amount of treatment changes of vertical-U1 and E line-upper lip, the changes of vertical-L1 and E line-lower lip, the changes of vertical-L1 and vertical-Li. 3. In extraction subjects, simple regression equations of E line-upper lip, E line-lower lip, Li were calculated by regression analysis. According to the results above, it could be considered that the effect of the extraction or nonextraction treatment was greater than the effect of growth.

A Study on Lithium Leaching from the Fly Ash of Taean Electric Power Plant (태안화력발전소 비산재로부터 리튬용출연구)

  • Kim, Kang-Joo;Lee, Eun-Gyu;Lee, Jae-Cheol;Hwang, Soo-Yeon;Kim, Chang-Hyeon
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.117-122
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    • 2012
  • The leaching of Li from fly ashes was studied. The fly ash produced from the Taean electric power plant of the Korea Western Power Co., Ltd. was used for this study. The Li leaching was observed according to the changes in solid:solution ratio, solution types (seawater or deionized water), and the $CO_2$ condition in the atmosphere. The results showed that the Li concentrations in the solution increased continuously as the solid:solution ratio increased. The Li leaching per unit mass of fly ash was greater when the deionized water was used for the experiment and when the $CO_2$ dissolution is limited during the reaction because the precipitation of $CaCO_3$ is suppressed under those conditions. At high solid:solution ratio, $Mg^{2+}$, the ion preventing the Li extraction from seawater by adsorption, was effectively removed from the seawater.

A Study on Digital Mapping using LiDAR Data (LiDAR 데이터를 이용한 수치지도 제작 방안 연구)

  • Lee, Hyun-Jik;Kim, Hong-Sub;Ru, Ji-Ho
    • Journal of Korean Society for Geospatial Information Science
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    • v.14 no.2 s.36
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    • pp.33-42
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    • 2006
  • Recently, the studies on the extraction of 3-dimension position information and attribute information of ground surface using LiDAR data. LiDAR data has high locational accuracy, and advantage that can process data more fast because there's not coordinate transform when acquire of Data justly the ground coordinate by Acquiring. The paper using only LiDAR data Manufacture road, building, contour That occupy a many parts of Digital Map. Estimated for possibility of Digital mapping using only LiDAR data As that compare accuracy with Digital map.

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Study of Thermodynamic Mechanism for Using Organic Solvent to Extract Isoflavone from Soybean Residuals (대두 잔기로부터 유기용매에 의한 이소플라본 추출 열역학적 메카니즘 연구)

  • Hua, Li;Guoqin, Hu;Dan, Li
    • Journal of the Korean Chemical Society
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    • v.53 no.4
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    • pp.427-431
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    • 2009
  • The thermodynamical mechanism of the extraction of soybean isoflavones from soybean residuals using organic solvent method has been studied. On the basis of experiments, a simple model for determining the distribution coefficients in organic solvent extraction was employed to calculate the thermodynamical functions between $K,\;{\Delta}H^0,\;{\Delta}S^0\;and\;{\Delta}G^0$ in the soybean isoflavones extraction process. The results show that the soybean isoflavones extraction is an endothermic and an entropy-increasing process: the ${\Delta}G^0$ decreases when the temperature arises.