• Title/Summary/Keyword: Lee Geun-sam

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Characterization of Acetylene Plasma-Polymer Films: Recovery of Surface Hydrophobicity by Aging

  • Kim, Jeong-Ho;Kim, Tae-Hyung;Oh, Jung-Geun;Noh, Seok-Hwan;Lee, Jeong-Soo;Park, Kyu-Ho;Ha, Sam-Chul;Kang, Heon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2589-2594
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    • 2009
  • Aging phenomena of plasma polymer films were studied by using the surface analysis techniques of contact angle measurement, X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (TOFSIMS), and atomic force microscopy (AFM). The polymer films were grown on an aluminum substrate by using a plasma polymerization method from a gas mixture of acetylene and helium, and the films were subsequently modified to have a hydrophilic surface by oxygen plasma treatment. Aging of the polymer films was examined by exposing the samples to water and air environments. The aging process increased the hydrophobicity of the surface, as revealed by an increase in the advancing contact angle of water. XPS analysis showed that the population of oxygen-containing polar groups increased due to the uptake of oxygen during the aging, whereas TOF-SIMS analysis revealed a decrease in the polar group population in the uppermost surface layer. The results suggest that the change in surface property from hydrophilic to hydrophobic nature results from the restructuring of polymer chains near the surface, rather than compositional change of the surface. Oxidative degradation may enhance the mobility and the restructuring process of polymer chains.

Effect of the Packaging Container on the Freshness of Raw Oysters Crassostrea gigas (생굴(Crassostrea gigas)의 선도 변화에 포장용기가 미치는 영향)

  • Yoon, Na Young;An, Byoung Kyu;In, Jung Jin;Han, Hyeong Gu;Lee, Woo Jin;Seo, Jeong-Hwa;Jeong, Sam Geun;Shim, Kil Bo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.55 no.1
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    • pp.73-77
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    • 2022
  • The shelf life of oysters Crassostrea gigas, in two different types of packaging containers, polyethylene (PE) and polyethylene terephthalate (PET), was determined by evaluating the pH, glycogen and soluble protein content, turbidity, and viable cell count. After 7 days of storage, the pH of the packing water in the PE container decreased to 5.88, while the pH in the PET container decreased to 6.03. In the PE container, the glycogen content of the oysters decreased by 0.85 g/100 g and the soluble protein content and turbidity of the packing seawater increased by 1,927.21 mg/100 g and 3.24 McF, respectively. In the PET container, the glycogen content of the oysters decreased by 0.96 g/100 g and the soluble protein content and turbidity of the packing seawater increased by 1,674.75 mg/100 g and 0.98 McF, respectively. The reaction rate constants (K) were as follows: glycogen content, -0.18 (PE) and -0.10 (PET); soluble protein content, 0.29 (PE) and 0.26 (PET); and turbidity, 0.41 (PE) and 0.06 (PET). These results suggested that PET can be used as a new packaging container material for raw oysters because the quality is maintained and it offers more convenient handling during distribution.

Distribution and Community Structure of Phytoplankton in the Southeast Coastal Waters During Summer 2006 (2006년 여름 남해 동부 연안 식물플랑크톤 군집 변동)

  • Lim, Weol-Ae;Lee, Young-Sik;Lee, Sam-Geun;Lee, Jae-Young
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.12 no.4
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    • pp.370-379
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    • 2007
  • Short-term variations of phytoplankton community structure in the southeast coastal waters of Korea from July to September in 2006 were investigated with data set of phytoplankton, chemical and physical water properties, and meterological data. A total of 11 sampling sites of 4 different depths (surface, 5 m, 10 m, and bottom) were visited on July 11-14, July 24-26, August 7-10, August 21-24 and September 5-8. We identified 151 species in 63 genera of phytoplankton in which diatoms were the most diverse group composed of 92 species in 37 genera. Dinoflagellates were the second diverse group of 52 species in 22 genera. The other groups include 7 species in 4 genera including Raphidophytes, and Euglenophyta. After rainy season, excessive nutrients from adjacent streams to the stratified water column proliferates Chaetoceros group in July. But biomass of phytoplankton and nutrient concentrations were decreased during the period of a drought in August. However, Chaetoceros was the most dominant genera in all depths of the first, second, third and fifth cruises, except the 4th cruise on August 21-24 when dominant group were dinoflagellates including Gymnodinium spp. and Cochlodinium polykrikoides. The characteristic of phytoplankton community and environment condition during summer 2006 can be summarized as: 1) low concentration of nutrients caused by a long lasting drought in August 2) no summer outbreak of C. polykrikoides because the strength of offshore waters was weak than other years, and 3) Chaetoceros spp. was the dominant species despite short period appearance of dinoflagellates.

An Unusual Coastal Environment and Cochlodinium polykrikoides Blooms in 1995 in the South Sea of Korea

  • Kang, Young-Shil;Kim, Hak-Gyoon;Lim, Wol-Ae;Lee, Chang-Kyu;Lee, Sam-Geun;Kim, Sook-Yang
    • Journal of the korean society of oceanography
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    • v.37 no.4
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    • pp.212-223
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    • 2002
  • Cochlodinium polykrikoides bloom in 1995 was studied with a focus on an unusual coastal environment in the South Sea of Korea. Data on temperature, salinity, and zooplankton biomass during 1965-1998 and nutrients during 1990-1998 and chlorophyll-a during 1995-1998 were used in this study. These data were obtained from the serial oceanographic observations in Korean waters carried out by the National Fisheries Research and Development Institute. In 1995 the C. polykrikoides bloom began in the coastal area around Narodo Island in August and consequently occurred to the whole coastal area of the South and East Seas of Korea. During June-October 1995, the coastal environment was unusual compared with the long-term means during 1965-1998. In June 1995, sea surface temperature was 1-2$^{\circ}C$ warmer than in other years in all coastal areas, while salinity was high only to the east of Jeju Island. In August 1995, a strong coastal front appeared inshore of a line between Jeju and Tsushima Islands. In particular, a strong coastal front which showed the characteristics of upwelling front occurred in the coastal area around Narodo and Sorido Islands, not only because of a strong intrusion of the Tsushima Warm Current but also because of the upwelling of cold bottom water. Salinity was low in the neighboring waters of western side of Jeju Island. Nutrients and chlorophyll-a were high in the inshore area between Narodo and Sorido Islands in 1995 in contrast with the other years and areas. Zooplankton showed an unusually high abundance in the coastal area in October 1995. We conclude that the Tsushima Warm Current strongly influenced the South Sea of Korea in 1995 and created strong upwelling front bordering cold upwelled water in the coastal area around Narodo and Sorido Islands. It leads us that these physical structures introduce the favorable environment for the development of C. polykrikoides blooms. We suggest that C. polykrikoides has a bio-physical tolerance of high shear and stress and prefers frontal and upwelling relaxed areas as its habitat. We also find that nutrients were not supplied to the coastal area from the offshore where a low salinity water mass with high nutrients appeared around Jeju Island. Because the strong upwelling front protect the reach of offshore low saline water mass. The main source of nutrients was the upwelled water mass in the coastal area of Wando-Narodo-Sorido.

The Surface Treatment Effect for Nanoimprint Lithography using Vapor Deposition of Silane Coupling Agent (나노임프린트 공정에서 실란커플링제 기상증착을 이용한 표면처리 효과)

  • Lee, Dong-Il;kim, Ki-Don;Jeong, Jun-Ho;Lee, Eung-Sug;Choi, Dae-Geun
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.149-154
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    • 2007
  • Nanoimprint lithography (NIL) is useful technique because of its low cost and high throughput capability for the fabrication of sub-micrometer patterns which has potential applications in micro-optics, magnetic memory devices, bio sensors, and photonic crystals. Usually, a chemical surface treatment of the stamp is needed to ensure a clean release after imprinting and to protect the expensive original master against contamination. Meanwhile, adhesion promoter between resin and substrate is also important in the nanoscale pattern. In this work, we have investigated the effect of surface treatment using silane coupling agent as release layer and adhesion promoter for UV-Nanoimprint lithography. Uniform SAM (self-assembled monolayer) could be fabricated by vapor deposition method. Vapor phase process eliminates the use of organic solvents and greatly simplifies the handling of the sample. It was also proven that 3-acryloxypropyl methyl dichlorosilane (APMDS) could strongly improve the adhesion force between resin and substrate compared with common planarization layer such as DUV-30J or oxygen plasma treatment.

Effects of Scolopendrid Water-Alcohol Extract Injection Applied to the Acupuncture Point on the Neuropathic Pain in Rats (백서(白鼠)에서 오공약침(蜈蚣藥鍼)이 신경병증성(神經病症性) 통증(痛症)에 미치는 영향(影響))

  • Lee, Sam-Ro;Koo, Sung-Tae;Kim, Sung-Nam;Hwang, Woo-Jun;Lee, Geon-Mok;Cho, Nam-Geun;Lim, Kyu-Sang;Kim, Sung-Chul
    • Korean Journal of Acupuncture
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    • v.21 no.2
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    • pp.47-67
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    • 2004
  • Objectives : In the present study, the effect of Scolopendrid Water-Alcohol Extract (SWAE) applied to acupuncture point BL23 (Shinsu) on the neuropathic pain was examined. A common source of persistent pain in humans is the neuropathic pain. Anti-convulsant drugs are used to treat the neuropathic pain. In the oriental medicine, Scolopendrid was used for long time to treat convulsant syndrome and back pain, etc. Methods : On the bases of the Scolopendrid clinical application, the effect of SWAE applied to the acupuncture point was tested in the rat model of neuropathic pain. Neuropathic pain was induced by tight ligation of L5 spinal nerve. When rats developed pain behaviors, One hundred microliter of SWAE was applied into the ipsilateral BL23 point at a dose of 10 mg/ml under enflurane anesthesia. The foot withdraw latency of the hind limb was measured for an indicator of pain level after each manipulation. Results : SWAE injection increased the mechanical threshold of the foot in the rat model of neuropathic pain significantly for the duration of 4h, suggesting a partial alleviation of pain. SWAE applied to BL23 point produced a significant improvement of mechanical sensitivity of the foot lasting for at least 4h. However, neither contralateral BL23 point, ST25 (Chonchu) point, nor LR3 (Taechung) point produce as much increase of mechanical sensitivity as ipsilateral BL23 point. And, this increase of mechanical sensitivity was dose-dependent. The improvement of mechanical threshold was interpreted as an analgesic effect. In addition, the analgesic effect of Scolopendrid 4 mg/kg injection is equivalent to that of gabapentin 50 mg/kg injection. The relations between SWAE-induced analgesia and endogenous nitric oxide(NO), inducible NO synthase (iNOS)/neuronal NO synthase (nNOS) were also examined. Results were turned out that both NO production and nNOS/iNOS protein expression which are increased by nerve injury were suppressed by SWAE injection applied to BL23 point. Conclusions : The data suggest 1) that SWAE produces a potent analgesic effect on the neuropathic pain model in the rat and 2) that SWAE-induced analgesia modulate endogenous NO through the suppression of nNOS/iNOS protein expression.

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Growth Response and Changes of Nitrate and Sucrose Content in Tomato under Salt Stress Condition (염스트레스에 의한 토마토 생장반응과 식물체내 Nitrate 및 Sucrose 변화)

  • Lee, Ju-Young;Jang, Byoung-Choon;Lee, Su-Yeon;Park, Jae-Hong;Choi, Geun-Hyoung;Kim, Sam-Cwaun;Kim, Tae-Wan
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.3
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    • pp.164-169
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    • 2008
  • This experiment was carried out to find the growth response and changes of nitrate and soluble sugar content in tomato leaves with salt stress. Tomato (Solanum lycopericum) seedlings were grown under different electrical conductivity (EC) levels adjusted with $CaCl_2$ as 1, 2, and $6dS\;m^{-1}$. The growth response and contents of nitrate and soluble sugar in tomato plants were examined at 7 and 14 days after salt treatment. Leaf area and dry weight ratio of shoot to root of tomato plants were decreased as EC level increased. Photosynthetic rate of leaves was reduced under high EC level due to the stomatal closure and the reduction of transpiration rate. The soluble sugar and starch content were lower in the tomato leaves grown under high EC level. Total nitrogen and nitrate contents were decreased in high EC level, whereas the ammonium content was increased. High-salt stress induced the accumulation of salt crystal in mesophyll cells of tomato leaf.

Characteristic of Environmental Factors Related to Outbreak and Decline of Cochlodinium polykrikoides Bloom in the southeast coastal waters of Korea, 2007 (2007년 남해동부해역의 Cochlodinium polykrikoides 적조 발생과 소멸에 미치는 환경 특성)

  • Lim, Weol-Ae;Lee, Young-Sik;Lee, Sam-Geun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.4
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    • pp.325-332
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    • 2008
  • To characterize the initiation, propagation and termination of Cochlodinium polykrikoides blooms in the southeast coastal waters of Korea, 2007, we have analyzed the data set of phytoplankton composition, physical and chemical water properties, and meterological data. The development of C. polykrikoides bloom in 2007 can be summarized in three steps. The first stage from middle of July to end of August was characterized by an unusually persistent and strong southerly wind. C. polykrikoides blooms established already by the strong wind in the middle of south coastal waters were advected intermittently into the study area. Accordingly, highly variable cell densities of C. polykrikoides were observed. At the second stage a favorable growing conditions for C. polykrikoides was developed, which was directed by changes in wind direction from south to northeast and thus enhanced transportation of offshore waters into inshore (August 8 to 30). C. polykrikoides bloom occurred through typical mechanism and showed high cell density. The last stage was represented by disappearance of C. polykrikoides. Typoon 'Nari' carrying heavy rain brought an unfavorable habitat to C. polykrikoides. Low saline condition formed in coastal water due to typoon effects continuously drove the dominant species to diatoms and flagellates which were prevailing over C. polykrikoides in this circumstances(from the middle of September). These stepwise processes could be the causative mechanism of the extraordinarily persistent C. polykrikoides bloom observed in southeast coastal water of Korea, 2007.

Evaluation on Stability of Reinforced Earth Wall using Geosynthetic Strip with Rounded Band Anchor (띠형 섬유보강재가 적용된 블록식 보강토옹벽의 안정성 평가)

  • Lee, Kwang-Wu;Cho, Sam-Deok;Han, Jung-Geun;Hong, Ki-Kwon
    • Journal of the Korean Geosynthetics Society
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    • v.11 no.3
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    • pp.43-51
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    • 2012
  • This paper describes the stability evaluation of reinforced earth wall using geosynthetic strip based on field test. The wall facing, which is applied in field, is able to present excellent scenery, and the reinforcement has improvement effect of pullout resistance based on rounded band anchor. The measurement is conducted according to construction elapsed time of structure for earth pressure, horizontal displacement of wall facing and reinforcement strain in field test. The evaluation results show that the measured earth pressure is less than theoretical earth pressure due to dispersion effect of earth pressure by geosynthetic strip. The horizontal displacement of wall facing is also satisfied a empirical criteria. The measured strain of reinforcement had nearly no effect on stability of the reinforced earth wall. Therefore, the geosynthetic strip with rounded band anchor can be applied in the reinforced earth wall, and the reinforced earth wall with geosynthetic strip can be commonly used in field because it has a structural stability.

Evaluation on Bearing Resistance of Transverse Members in Steel Strip Reinforcement using Pullout Tests and Theoretical Equations (인발시험과 이론식을 이용한 강재스트립 보강재에 설치된 지지부재의 지지저항 특성 평가)

  • Han, Jung-Geun;Yoon, Won-Il;Hong, Ki-Kwon;Hong, Won-Pyo;Lee, Kwang-Wu;Cho, Sam-Deok
    • Journal of the Korean Geosynthetics Society
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    • v.9 no.2
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    • pp.33-40
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    • 2010
  • In this study, the pullout tests are conducted to evaluate pullout resistance of steel strip reinforcement with transverse members. The test results are compared with theoretical equations and then the failure mechanism of transverse members is evaluated. The bearing resistance stress(${\sigma}^{\prime}_b$) of transverse members, which is applied pullout force at 50mm displacement, is closed from punching shear failure to general shear failure. The behavior by increment of a number of transverse members became closer to general shear failure. The behavior of transverse members at maximum pullout force, which is closed to general shear failure, is indicated that it is unrelated to normal stress and a number of transverse members. However, if the allowable displacement of reinforced soil wall is considered, it is impossible to apply in design. The test results are compared with bearing resistance evaluations using Prandtl's plastic theory and cylindrical cavity expansion theory. The analysis results are indicated that the bearing resistance by pullout tests is closed to predicted result by Prandtl's plastic theory, which are located between general shear failure and punching shear failure.

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