• Journal of the Korean GEO-environmental Society
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• v.2 no.3
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• pp.17-35
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• 2001

In this study, we conducted a combined adsorption-sequential extraction analysis(CASA) to investigate temperature effects of single adsorption of lead, copper, zinc and cadmium on natural clays. As a result, it was found that in a single adsorption of lead and copper, about 50% of adsorption was occluded in carbonate phase, and in case of cadmium, about 80% of adsorption was occluded in exchangeable phase. At temperature below $25^{\circ}C$ about 60% of zinc was occluded in exchangeable phase but above $40^{\circ}C$ about 50% of zinc was occluded in carbonate phase. The effect of temperature on each occluded phase was largely observed in Fe-oxide, Mn-oxide and organic occluded phases. Besides, the adsorption of metals on natural clays was an endothermic reaction with the exception of exchangeable phase adsorption.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.8 no.2
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• pp.85-89
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• 1975

Heavy metal content have been determined in baby clams from March 1973 to April 1974 in Depori, Samchunpo, Korea. Monthly changes of mercury, lead, copper ana cadmium in the samples were irregular but as a whole, the content of mercury, lead, copper and cadmium were relatively high in summer season. The content of total mercury, lead, copper and cadmium in the samples ranged from 0.003 to 0.038 ppm, 0.096 to 0.931 ppm, 0.023 to 0.139 ppm and 0.009 to 0.038 ppm respectively. In the consideration of heavy metal content, it was concluded that baby clams in Depori, Samc hunpo, Korea is suitable for processing materials.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.1 no.1
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• pp.82-88
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• 1991

Determination of Cu, Fe, Ni, Pb, and Zn concentrations in coal and respirable coal dust were performed by atomic absorption spectrophotometry. The coal samples of 18 coal mines in Gangneung area were collected and 25 coal mines in Taebaek area. Crushed coal samples were divided into three mesh sizes. The results were as follows : 1. Metal concentrations of coals in Gangneung area by sieve sizes( -100/+200 mesh, -200/+325 mesh, -325 mesh) were as follows: Cu ; 20, 18, 19, Fe ; 1,830, 1,765, 1,107, Pb ; 6, 8, 14, Ni ; 17, 17, 14, Zn ; 4, 2, $4{\mu}g/g$, respectively. Metal concentrations in coals in Taebaek area by sieve sizes(-100/+200 mesh, -200/+325 mesh, -325 mesh) were as follows: Cu ; 30, 32, 26, Fe ; 1,741, 1,822, 1,773, Pb ; 8, 9, 7, Ni ; 13, 13, 13, Zn ; 8, 5, $4{\mu}g/g$, respectively. There were not significant differences of Cu, Fe, Ni, Pb, and Zn concentrations of coals statistically in Gangneung and Taebaek area by sieve size. 2. Metal concentrations of coals in Gangneung and Taeback area were as follows : Cu ; 19, 30, Fe ; 1,514, 1,778, Pb ; 9, 8, Ni ; 16, 13, Zn ; 3, $6{\mu}g/g$, respectively. Differences of copper and zinc concentrations of coal samples were significant between Gangneung and Taebaek area, but those of iron, nickel and lead concentrations were not significant. 3. Copper, iron, lead, nickel and zinc concentrations of coals and respirable coal dust were as follows : Cu ; 30, 6, Fe ; 1,779, 5,075, Pb ; 8, 7,814, Ni ; 13, 5,681, Zn ; 5, $134{\mu}g/g$, respectively. Differences of nickel, lead and zinc concentrations were significant between coals and respirable coal dust but those of copper and iron concentrations were not significant.

• The Journal of the Korea Contents Association
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• v.14 no.2
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• pp.457-466
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• 2014

During irradiation of lesions in cancer treatment with high energy electrons, normal tissue and critical organs are protected by the shielding material. Scattered radiation that generated the shielding materials affect the depth dose and atomic number. Therefore, we want to examine secondary particles and the scattered photons through calculation and its associated analysis, and compare the measurement for the aluminum, copper, and lead shielding substance of which thickness has 95% charge reduction. Dose change rate which effected scattering radiation was found to be +0.88% for material thickness, +0.43% for atomic number, and +19.70%, +15.20%, +12.40% for measurement, +25.00%, +15.10%, +13.70% for calculation on the aluminum, copper, and lead materials of which thickness has 95% charge reduction, respectively, As a result, we found that scattering rate was dependent on thickness than atomic number. In the dose increasing rate, scattered electrons are more important than scattered photon. For the above mentioned reasons, I think that high atomic number materials should be applied to reduce scattered radiation that generated with thickness effect.

• Economic and Environmental Geology
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• v.39 no.2 s.177
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• pp.103-109
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• 2006

Batch adsorption experiments were performed to adsorb cadmium [Cd(II)], copper [Cu(II)], and lead [Pb(II)] onto sphagnum peat moss. According to the results, 10-50 mg/L of Cd(II), Cu(II), and Pb(II) were effectively adsorbed and removed within 1 h by 1.0 g/L of sphagnum peat moss. The amounts of Cd(II), Cu(II), and Pb(II) adsorbed on sphagnum peat moss increased with increasing the initial concentrations. The kinetics for the adsorption of Cd(II), Cu(II), and Pb(II) on sphagnum peat moss was described well using the pseudo-second order model at different initial concentrations. The maximum adsorption capacities calculated from the Langmuir isotherm for Cd(II), Cu(II), and Pb(III) were 33.90, 29.15, and 91.74 mg/g, respectively. Experimental results showed that sphagnum peat moss was a very effective adsorbent on the adsorption of Cd(II), Cu(II), and Pb(II).

• Journal of environmental and Sanitary engineering
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• v.10 no.2
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• pp.46-58
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• 1995

Acute toxicity of heavy metals( Mercury, Cadmium, Lead, Chromium and Copper ), Organophosphorus insecticides( EPN, 2, 4- D, and Parathion ), and other chemicals( Arsenic, Cyanide, and Phenol) to Daphnia magna, and Vibrio fischeri was analysed. Daphnia magna to most toxic chemicals was most sensitive among test organisms alld then Daphnia magna seems to be more useful in toxic test of water. Daphnia magna was more sensitive to heavy metals than insecticides and other chemicals. The sensitivity of Visrio JircAeri to heavy metals was not so different from that to insecticides and the sensitivity to other chemicals was low. Visrio JircAeri appears to be more sensitive to toxic chemicals than Photobacterium phosphoreum, which was compared as recorded values of P.phosphoreum. Toxic chemicals were classified as Group 1 which had a high $EC_{50}$ or $LC_{50}$ value and the low increase rate of toxicity according to the increase of concentration, Group 2 which had a high $EC_{50}$ or $LC_{50}$ value and the high increase rate of toxicity, Group 3 which had a low $EC_{50}$ or $LC_{50}$ value and the high increase rate of toxicity, and Group 4 which had a low $EC_{50}$ or $LC_{50}$ value and the low increase rate of toxicity. To Daphnia magna, Lead, Chromium EPN, and Parathion were included in Group 1 : Mercury and Copper in Group 2 : Arsonic and Cadmium in Group 3 : Cyanide, 2, 4-B, and Phenol in Group 4. To Visrio JircAeri, Lead, Chromiurl 2, 4- D, and Parathion were included in Group 1 : Merecury, Cadmium and Arsenic in Group 2 : Cyanide in Group 3 : EPN, Copper, and Phenol in Group 4.

• YAKHAK HOEJI
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• v.25 no.3
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• pp.89-99
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• 1981

This study was performed to investigate the contamination level of heavy metals in freshwater flshes. The samples of 92 cases were collected at 7 areas located on HanRiver from November to December in 1980. Contents of heavy metals: cadmium, lead, copper, chromium and zinc were analyzed by atomic absorption spectrophotometry. The results were as follows: 1. Generally mean value of the heavy metal contents of fishes collected on lower parts of Han River were higher than those of upper parts. 2. In the cadmium contents, the highest value was $20.52{\pm}5.10$ ppb in Carassius auratus, and the values at Hannam and Noryangjin area were higher than those at other parts on Han River. 3. In the lead contents, the highest was $0.29{\pm}0.03ppm$ in Carassius auratus and that in Parasilurus asotus was the lowest $0.12{\pm}0.02ppm$ Mean contents of lead in the samples of Hannam and Haengjue area were higher than those of other area 4. In the copper contents, the highest value was $3.13{\pm}0.34ppm$ in Carassius auratus and the contents of fishes of Haengjue area was higher than those of any other area. It was significant among the species, but not among the collecting areas in copper contents. 5. In the chromium contents, the highest was $1.16{\pm}0.12ppm$ in Carassius auratus and that in Parasilurus asotus was the lowest $0.21{\pm}0.01ppm$ The contents of samples of Hannam and Noryangjin area were also higher than those of other area. 6. In the zinc contents, that in Arassius auratus was the highest value with $14.06{\pm}1.13ppm$ and that in Parasilurus asotus was the lowest $4.79{\pm}0.53ppm$. On the other hand, it was significant among the species and collecting areas. 7. Accumulation of heavy metals in freshwater fishes is tended to increase with growth.

• Journal of the Korean GEO-environmental Society
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• v.14 no.10
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• pp.59-64
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• 2013

Effects of weathering intensity on the adsorption of heavy metals such as lead(Pb) and copper(Cu) onto decomposed granite soils were investigated by a series of batch tests. The chemical components such as $SiO_2$, $K_2O$ and $Na_2O$ having relatively high solubility were reduced and the oxidized $Fe_2O_3$ content was increased with the increase of weathering intensity. Weathering of granite soils increased the ignition loss and specific surface area, while it decreased the permeability. The lead and copper adsorptions onto the decomposed granites were enhanced with the increase of weathering intensity, mainly due to the increase of specific surface area and clayed contents. Adsorption of lead and copper onto the weathered granites could be more adequately described by the pseudo-second-order kinetic model than the pseudo-first-order model.

• Proceedings of the Korean Society of Applied Pharmacology
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• 2001.11a
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• pp.91-91
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• 2001

Nramp2, also known as DMT1 and DCT1, is a 12-transmembrane domain protein responsible for dietary iron uptake as well as metal ions such as lead, manganese, zinc, copper, nickel, cadmium, and cobalt. High expression of DMT1 increase lead uptake, and DMT1-dependent lead transport was H -dependent and inhibited by iron ions. The molecular mechanism of lead transport in CNS is as yet unknown. although interactions between iron and lead at the level of absorption have been known for some time. The process of lead uptake into astrocytes was not known yet. Nramp2 may mediate transport of heavy metal into astrocytes. We investigated whether Nramp2 mediate transport of lead into astrocytes. And we do whether Nramp2 was expressed highly by deprivation of iron in Astrocytes, and lead uptake into astrocytes was influenced by expression of Nramp2. Immortalized human fetal astrocyte(SV-FHA) cells were cultured in medium containing Dulbecco's modified Eagle's medium and treated with Deferoxamine. Northern blot analysis was done for determining mRNA level of DMT1 and lead uptake assay was done in incubation condition of pH 5.5 and 7.4.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.9 no.3
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• pp.177-184
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• 1976

The concentrations of mercury, cadmium, copper, lead and zinc in sea water of Ulsan Bay were determined at spring and neap tide in August 1976. The range and mean of the heavy metal concentrations are as follows: at spring tide mercury 0.00-0.20ppb, 0.06ppb, cadmium 0.00-1.80ppb, 0,22ppb; copper 0.83-10.60ppb, 1.67ppb; lead 0.00-4.53ppb, 1.35ppb; zinc 0.0-21.8ppb, 4.4ppb, and at neap tide mercury 0.00-0.10ppb, 0.03ppb; cadmium 0.00-0.54ppb, 0.19ppb; copper 0.51-2.60ppb, 0.92ppb; lead 0.00-2.21ppb, 1.00 ppb; zinc 0.0-13.6ppb, 3.3ppb respectively. The concentrations and variations of the heavy metals were higher at spring tide than that at neap tide. The heavy metal levels of Ulsan Bay except Ulsan Harbour area was not higher than those of other coastal area. Low chlorosity, low pH and high heavy metal levels except zinc were determined in Ulsan Harbour at spring tide.