• 제목/요약/키워드: Lead determination

검색결과 290건 처리시간 0.022초

Simultaneous Determination of Polycyclic Aromatic Hydrocarbons by Near Infrared Spectroscopy using a Partial Least Squares Regression

  • Nam, Jae-Jak;Lee, Sang-Hak;Park, Ju-Eun
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1276-1276
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    • 2001
  • Polycyclic aromatic hydrocarbons(PAHs) are widely distributed in the environment and are often implicated as potential carcinogens. The chromatographic methods of detection and quantitative determination of PAHs in environmental samples are costly, time consuming, and do not account for all kinds of PAHs. This work describes a quantitative spectroscopic method for the analysis of mixtures of eight PAHs using multivariate calibration models for Fourier transform near infrared(FT-NIR) spectral data. The NIR spectra of mixtures of PAHs (anthracene, pyrene, 1,2-benzanthracene, perylene, chrysene, benzo(a)pyrene, 1-methylanthracene and benzo(ghi)perylene) were measured in the wavelength range from 1100 nm to 2500 nm. The spectral data were processed using a partial least squares regression. We have studied the spectral characteristics of NIR spectra of mixtures of PAHs. It was possible to determine each PAM used in this study at the environmental level(mg L-1) in the laboratory samples. Further development may lead to the rapid determination of more PAHs in typical environmental samples.

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Attitude Determination GPS/INS Integrated Navigation System with FDI Algorithm for a UAV

  • Oh Sang Heon;Hwang Dong-Hwan;Park Chansik;Lee Sang Jeong;Kim Se Hwan
    • Journal of Mechanical Science and Technology
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    • 제19권8호
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    • pp.1529-1543
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    • 2005
  • Recently an unmanned aerial vehicle (UAV) has been widely used for military and civil applications. The role of a navigation system in the UAV is to provide navigation data to the flight control computer (FCC) for guidance and control. Since performance of the FCC is highly reliant on the navigation data, a fault in the navigation system may lead to a disastrous failure of the whole UAV. Therefore, the navigation system should possess a fault detection and isolation (FDI) algorithm. This paper proposes an attitude determination GPS/INS integrated navigation system with an FDI algorithm for a UAV. Hardware for the proposed navigation system has been developed. The developed hardware comprises a commercial inertial measurement unit (IMU) and the integrated navigation package (INP) which includes an attitude determination GPS (ADGPS) receiver and a navigation computer unit (NCU). The navigation algorithm was implemented in a real-time operating system with a multi-tasking structure. To evaluate performance of the proposed navigation system, a flight test has been performed using a small aircraft. The test results show that the proposed navigation system can give accurate navigation results even in a high dynamic environment.

Determination of Trace Amounts of Lead and Copper in Water Samples by Flame Atomic Absorption Spectrometry after Cloud Point Extraction

  • Shemirani, Farzaneh;Abkenar, Shiva Dehghan;Khatouni, Asieh
    • Bulletin of the Korean Chemical Society
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    • 제25권8호
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    • pp.1133-1136
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    • 2004
  • The need for highly reliable methods for the determination of trace metals is recognized in analytical chemistry and environmental science. A method based on the cloud-point extraction (CPE) technique for the trace analysis of Pb and Cu in water samples is described in this study. The analytes in the initial aqueous solution are complexed with pyrogallol, and 0.1%(w/v) Triton X-114 is added as surfactant. Following phase separation at $50^{\circ}C$, based on the cloud point of the mixture and dilution of the surfactant-rich phase with acidified methanolic solution, the enriched analytes are determined by flame atomic absorption spectrometry. After optimization of the complexation and extraction conditions, the enrichment factors of Pb and Cu were found to be 72 and 85, respectively. Under optimum conditions, the preconcentration of 60 mL of samples in the presence of 0.1%(w/v) Triton X-114 permitted the detection of 0.4 ${\mu}gL^{?1}$ of Pb and 0.05 ${\mu}gL^{?1}$ of Cu. The proposed method was applied successfully to the determination of Pb and Cu in water samples.

리드프레임 타발 공정의 최적 전단 조건의 선정 (Determination of Optimal Process Condition for the Precision Blanking of Lend Frame)

  • 서의권;임상헌;심현보
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2001년도 추계학술대회 논문집
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    • pp.71-74
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    • 2001
  • Using the Taguchi method, optimum process condition of lead frame blanking has been determined in the point of view of shape of blanked profile. As the main process parameters, clearance, strip holding pressure and bridge width are selected. According to the orthogonal array table, three levels of experiment have been carried out for each factors. The optimal blanking condition is analyzed with the SN ratio. It has been verified that the optimal process condition can be determined with a combination of basic blanking experiment and experiment design method. Both the effect of each factors and gain can be judged in the quantitative manners from the analysis of SN ratio.

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Direct Determination of Cationic Disordering in Sodium Bismuth Titanate

  • Choi, Si-Young;Ikuhara, Yuichi
    • Applied Microscopy
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    • 제42권3호
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    • pp.164-173
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    • 2012
  • The relaxor ferroelectric feature in lead-free perovskite oxides, where the dipoles are randomly oriented and they can be feasibly aligned parallel to the external bias, is attracting lots of attention in the field of piezoelectric materials science, since it is one of candidates to replace the toxic lead-based materials that are still being commercially used. However, the origin of relaxor characteristic and its related atomic structure are still ambiguous. In this study, $Na_{1/2}Bi_{1/2}TiO_3$, chosen as a model relaxor system, was found to exhibit a cationic-disordered atomic structure; and furthermore the nonpolar atomic structure and its related oxygen tilting were ascertained via annular bright field imaging skill. We also found that this cationic disordering gives rise to the local formation of atomic vacancies.

Determination of joint production and delivery policy with multiple production lines for multiple products

  • Kim, Tae-Bok;Hong, Yu-Shin
    • 한국경영과학회:학술대회논문집
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    • 한국경영과학회 2006년도 추계학술대회
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    • pp.134-137
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    • 2006
  • Satisfying the customer orders with a short lead-time is one of the essential and competitive factors for business units under a mass customization environment. To shorten the lead-time for fulfilling various orders entails the production capacity expansion and efficient operational policy. Most business firms utilize the multiple production lines or facilities to cope with this business and manufacturing environment by making the manufacturing and distribution more flexible. In this study, we introduce the operational problem determining the joint production and delivery policy in an environment where multiple products are manufactured with more than one production lines. Also, we propose the heuristic solution approach for determining the product-line selection and joint lot size for this problem.

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표면실장기술에 있어 설계기준결정에 관한 연구 (Determination of Design Criteria Using 3D Solder Joint Configuration in SMT)

  • 김성관;최동필;유중돈
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 1995년도 특별강연 및 추계학술발표 개요집
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    • pp.145-148
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    • 1995
  • To provide better understanding of a solder joint design criteria, mathematical models have been developed to calculate the shape of the solder fillets formed between the pad and lead. The effects of parameters such as solder volume and pad dimensions are described with this model. In this study, a systematic way to determine the design criteria of the SMT from the predicted 3D solder joint profile is proposed. The solder joint profile is calculated using the available 3D FEM code which minimizes the system energy due to the surface tension and gravity. The solder joint profiles of gullwing-type lead such as QFP and SOP are calculated for design parameters, and acceptable ranges are obtained. The result shows that the pad length is the most significant factor compared with the pad width and pad area.

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원자흡광 분광광도계에 의한 사료중 중김속의 정량 (Determination of Trace Metals in Formula Feed by Atomic Absorption Spectrophotometry)

  • Park, Sung Woo;Lee, Wan Koo
    • 한국환경보건학회지
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    • 제11권2호
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    • pp.55-63
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    • 1985
  • The quantities of chrome, lead, iron, copper and manganese in the formula feed were determined by A.A.S. and the results were summarized as follows 1. The content of chromium in the leather and meat meals(SN-2) were 13-66 times as much as the level of permission. 2. In the meantime, lead content in the meat meal (SN-1) was about 20 times as much as permitted level. 3. The iron which is essential constituent of the formula feed was contained in the meat and leather meals and these values were 2-10 times as much as feeding regulations, on the contrary copper and manganese content in the shaving and flesh were below the feeding regulations.

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수치지형모형을 이용한 최적노선선정에 관한 연구 (A Study on the Optimum Route Determination using Digital Terrain Model)

  • 정영동;박정남;박성규;김진기
    • 한국측량학회지
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    • 제11권2호
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    • pp.17-26
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    • 1993
  • 최근 국토의 효율적인 개발을 목적으로 신설도로의 건설이 급증하고 있다. 그러나 우리나라는 경제 개발사업이 시작되면서 국토개발이 활발히 추진됨에 따라 국토의 자연활경에 많은 손상을 가져 왔던 것도 부인할 수 없는 사실이다. 이런 관점에서 본 연구는 도로개발사업시 효율적인 최적노선을 창출하기 위해 연구대상지를 선정하여 종래 방법과 수치지형모형방법으로 구분하고 최적노선 선정시 현황지형, 토공량 변화에 따른 예측지형 및 주변경관해석의 한 방법을 제시하고자 하였다. 연구결과 수치지형모형으로 노선계획시 토공량변화에 따른 예측지형 및 경관도를 작성할 경우 종래 조감도 및 투시도 방법보다 입체적이고 시각적이며, 대상지의 다양한 지형인자를 삽입하면 최적 노선선정시 토공량산정, 종·횡단면도 작성, 경관도, 조경도 등 모든 노선계획의 수치화가 가능하므로 도로 건설사업시 그 활용도가 기대된다.

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휴대용 X-Ray 형광기기(XRF)를 이용한 공기중 납농도 평가 (Evaluation of Lead levels in Airborne by a portable X-Ray Fluorescence Instrument)

  • 안규동;이종천;조광성;김남수;김진호;이성수;이병국
    • 한국산업보건학회지
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    • 제11권3호
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    • pp.235-240
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    • 2001
  • This study was performed to compare the lead levels of 20 quality control standard samples(KOSHA:18-2000) and 72 field samples in lead-acid battery manufacturing plant between ICP and portable-XRF methods. 1. While the proficiencies of 20 quality control standard samples by ICP were 100%, those of analytic result values by XRF were 75%. 2. The correlation coefficient(r) between the reference values for quality control (REF) and the analytic result values by ICP (ICP) was 1.0(p<0.05), and simple linear regression equation and the coefficient(R2) were REF = -0.0009 + 1.016 ICP and 0.9997, respectively. 3. The correlation coefficient(r) between the analytic result values of quality control standard samples by ICP (ICP) and by XRF (XRF) was 0.975(p<0.05), and simple linear regression equation and the coefficient(R2) were ICP = -0.0003 + 1.002 XRF and 0.950, respectively. 4. The correlation coefficient(r) between the analytic result values for lead samples of a lead-acid battery manufacturing plant by ICP (ICP) and by XRF (XRF) was 0.993(p<0.05), and simple linear regression equation and the coefficient(R2) were ICP = -2.058 + 0.996 XRF and 0.987, respectively. 5. While the frequency distributions of XRF /ICP(Ratio) for each ICP concentration levels in a lead-acid battery manufacturing plant revealed high proportion in ratio range of 0.876-1.125 than in ration range of 1.126-1.375. Also, ICP concentration level in ration range of 0.786-1.125 was increased with increase of frequency distribution of XRF/ICP. 6. The limit of detection of XRF on lead was determined to be $6.11{\mu}g$/filter The data presented in this study indicated that relationship for lead level of quality control samples and field samples in a lead -acid battery manufacturing plant by ICP and portable-XRF methods was proved. The practicing industrial hygienist can use portable-XRF to produce a rapid on-site determination of lead exposure that can immediately becommunicated to workers and help identify appropriate levels of personal protection.

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