• Bulletin of the Korean Chemical Society
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• 제26권1호
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• pp.51-56
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• 2005

A PVC membrane electrode for lead ion based on 1-phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone (PQDBP) as ionophore was demonstrated. The optimum composition of the membrane was 30 wt% poly(vinyl chloride), 60 wt% dibutyl phthalate as a plasticizer, 4 wt% ionophore and 6 wt% sodium tetraphenylborate as additive. The electrode exhibits a Nernstian response (28.7 mV decade$^{-1}$) for Pb$^{2+}$ over a wide concentration range (1.0 ${\times}$ 10$^{-1}$ to 1 ${\times}$ 10$^{-6}$ M) with a detection limit of 6.0 ${\times}$ 10$^{-7}$ M. This sensor has a short response time and can be used for at least 2 months without any divergence in potentials. The proposed electrode could be used in a pH range of 3.0-6.0 and revealed good selectivities for Pb$^{+2}$ over a wide variety of other metal ions. It was successfully applied as an indicator electrode for the potentiometric titration of lead ion with potassium chromate and for the direct determination of lead in mine.

• Journal of the Korean Society of Manufacturing Process Engineers
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• 제8권2호
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• pp.90-95
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• 2009

This paper presents a new lithium ion unit-cell and pack battery by using a new formulation ratio of material. The three types of formulation ratio for the unit-cell were used. The life cycle and basic properties of the lithium ion unit-cell$({\Psi}18{\times}65(mm))$ about one of them were acquired by the charge-discharge experiment. The nominal voltage, nominal capacity and cycle life output of the lithium ion unit-cell is respectively 3.7V, 2.4Ah, and above 500cycle. Pack type lithium ion battery has the size of $29.5{\times}73.5{\times}115(mm)$ and the weight of 300g. As the results, the weight and bulk of lithium ion battery used to a safety lamp were decreased to 1/4 and 1/7. In addition, the comparison of the new lithium ion battery and lead storge battery for confirming the effectiveness of the new lithium ion battery have been performed.

• Journal of the Korea Academia-Industrial cooperation Society
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• 제16권5호
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• pp.3391-3398
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• 2015

Recently, the large scaled lead-acid battery is widely introduced to efficient operation of the photovoltaic system in many islands. but the demand of lithium-ion battery is getting increased by the operation of wind power and replacement of the lead-acid battery. And also, under the renewable portfolio standard(RPS) and energy efficiency resource standard(EERS) policy of Korea government, the introduction of energy storage system(ESS) has been actively increased. Therefore, this paper presents the operation algorithm of hybrid battery management system(BMS) using the lead-acid and lithium-ion batteries, in order to maximize advantage of each battery. In other words, this paper proposed the algorithm of state of charge(SOC) and hybrid operation algorithm to calculate the optimal composition rate considering the fixed cost and operation cost of each battery. From the simulation results, it is confirmed that the proposed algorithms are an effective tool to evaluate SOC and to optimally operate hybrid ESS.

• Bulletin of the Korean Chemical Society
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• 제26권8호
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• pp.1219-1224
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• 2005

We prepared lead ion-selective PVC membranes that were based on N,N'-bis-thiophene-2-ylmethylene-ethane-1,2-diamine as a membrane carrier. The membrane electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-5}$ and 1.0 ${\times}$ $10^{-1}$ M with a Nernstian slope of 29.79 mV per decade, and its detection limit was 2.04 ${\times}$ $10^{-6}$ M at room temperature. The potentiometric response is independent of the pH of the solution in the pH range of 5-7. The proposed electrode revealed good selectivity and response for $Pb^{2+}$ over a wide variety of other metal ions in pH 5.0 buffer solutions, and there was good reproducibility of the base line on the subsequent measurements. The membrane electrode has a relatively fast response time, satisfactory reproducibility and a relatively long life time.

• Journal of Electrical Engineering and Technology
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• 제13권2호
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• pp.631-636
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• 2018

This paper proposed an optimal operation strategy for a hybrid energy storage system (HESS) with a lithium-ion battery and lead-acid battery for mild hybrid electric vehicles (mild HEVs). The proposed mild HEV system is targeted to mount the electric motor and the battery to a conventional internal combustion engine vehicle. Because the proposed mild HEV includes the motor and energy storage device of small capacity, the system focuses on low system cost and small size. To overcome these limitations, it is necessary to use a lead acid battery which is used for a vehicle. Thus, it is possible to use more energy using HESS with a lithium battery and a lead storage battery. The HESS, which combines the lithium-ion battery and the secondary battery in parallel, can achieve better performance by using the two types of energy storage systems with different characteristics. However, the system requires an operation strategy because accurate and selective control of the batteries for each situation is necessary. In this paper, an optimal operation strategy is proposed considering characteristics of each energy storage system, state-of-charge (SOC), bidirectional converters, the desired output power, and driving conditions in the mild HEV system. The performance of the proposed system is evaluated through several case studies with respect to energy capacity, SOC, battery characteristic, and system efficiency.

• Journal of the Korean Applied Science and Technology
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• 제30권2호
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• pp.356-361
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• 2013

Lead (II) ion selective poly(aniline) solid contact electrode based on Tetramethylthiuram monosulfide ionophore as a sulfur containing sensing material is successfully developed. The electrode exhibits good linear response of 25.6 mV / decade (at $20{\pm}0.2^{\circ}C$, r2=0.995) within the concentration range of $1.0{\times}10^{-1}{\sim}4.0{\times}10^{-7}$ M Pb (II). The composition of this electrode was Ionophore : PVC : dioctylphthalate : potassiumtetrakis(4-chlorophenyl)borate : Oleic acid = 5.0 : 20.0 : 25.0 : 4.0 : 5.0. When we consider the results of using different composition electrodes based on only one potassiumtetrakis(4-chlorophenyl)borate or Oleic acid liphophlic additive, poly(aniline) solid contact electrode based on Tetramethylthiuram monosulfide ionophore with potassiumtetrakis(4-chlorophenyl)borate and Oleic acid liphophlic additive had the best result in response characteristics. The electrode shows good selectivity for lead (II) ion in comparison with alkali, alkaline earth, transition and heavy metal ions. This electrode is suitable for use with aqueous solutions of pH 3.0 ~ 7.0 and their standard deviation in the measured emf differences was ${\pm}2.94$ mV at Tris buffered lead sample solution of $1.0{\times}10^{-2}$ M and ${\pm}2.82$ mV at Tris buffered lead sample solution of $1.0{\times}10^{-3}$ M. Their stabilization time was less than 710 s. and response time was less than 16 s.

• Bulletin of the Korean Chemical Society
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• 제29권3호
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• pp.546-550
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• 2008

The title compound of nicotinato lead(II) complex [Pb$(C_5H_4NCOO)_2$] has been optimized at B3LYP/LANL2DZ and HF/LANL2DZ levels of theory. The calculated results show that the lead(II) ion adopts 2- coordinate geometry, which is the same as its crystal structure and different from the 4-coordinate geometry of isonicotinato lead(II) complex. Atomic charge distributions indicate that during forming the title compound, each nicotinic acid ion transfers their negative charges to central lead(II) ion. The electronic spectra calculated by B3LYP/LANL2DZ level show that there exist two absorption bands, which have some red shifts compared with those of isonicotinato lead(II) complex and the electronic transitions are mainly derived from intraligand $\pi$ -$\pi$ transition and ligand-to-metal charge transfer (LMCT) transition. CIS-HF method is not suitable for the system studied here. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between the properties and temperature have also been obtained. The second order optical nonlinearity was calculated, and the molecular hyperpolarizability was $1.147754{\times}10^{-30}$ esu.

• Mass Spectrometry Letters
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• 제10권1호
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• pp.27-31
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• 2019

In this article, the properties of ${CO_2}^+(CO_2)_n$ clusters in a Paul ion trap have been investigated using mass-selective instability mode which conducted by chosen precursor ions, mainly $Ar^+$ and ${CO_2}^+$ produced by a mixture of Ar and $CO_2$. Exposure of ${CO_2}^+$ ions to $CO_2$ molecules, lead to the formation of ${CO_2}^+(CO_2)_n$ clusters. Here, Ar gas react as a buffer gas and lead to form ${CO_2}^+(CO_2)_n$ cluster by collisional effect.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• 제24권2호
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• pp.127-132
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• 2024

Recently, secondary batteries, commonly known as rechargeable batteries, find widespread applications across various industries. Particularly valued for their compact and lightweight characteristics, they play a crucial role in diverse portable electronic devices such as smartphones, laptops, and tablets, offering high energy density and efficient charge-discharge capabilities. Moreover, they serve as vital components in electric vehicles and contribute significantly to the field of renewable energy as part of Energy Storage Systems(ESS). However, despite advancements in this technology, issues such as reduced lifespan, cracking, damage, and even the risk of fire can arise due to excessive charging and discharging of secondary batteries. To address these challenges, Battery Management System(BMS) are employed to protect against overcharging and improve overall performance. Nevertheless, understanding the protective range settings of BMS using lithium-ion batteries, the most commonly used secondary batteries, and lead-acid batteries can be challenging. Therefore, this paper aims to utilize a battery charge-discharge tester and simulator to investigate the charging and discharging characteristics of lithium-ion batteries and lead-acid batteries, addressing the associated challenges of reduced lifespan, cracking, damage, and fire hazards in secondary batteries.

• Journal of Food Hygiene and Safety
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• 제9권4호
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• pp.229-235
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• 1994

It is very important to investigate the sanitary chemical conditions of farmwaters used for cattle breeding in the dairy farms. For this purpose we examined pH, KMnO4 consumption, total hardness, chloride, sulfate, NH3-N, NO3-N, fluoride, lead, iron, manganese, cadmium, copper, zinc and chrome in the farmwaters sampled 2 times(spring and summer)in Choongcheongnam and Kangwon Province. The pH of farmwaters in Choongcheongnam and Kangwon Province was 6.49$\pm$0.09, 6.70$\pm$0.06, total hardness 90.21$\pm$7.07, 64.53$\pm$6.38 mg/ι, consumption of KMnO4 4.13$\pm$0.62, 4.34$\pm$0.26mg/ι, NO3-N 6.51$\pm$0.55, 3.61$\pm$0.58 mg/ι, chloride ion 20.51$\pm$1.99, 5.41$\pm$1.36 mg/ι and sulfate ion 6.61$\pm$1.02, 7.28$\pm$1.30 mg/ι, respectively. But NH3-N was scarcely detected. Fluoride, iron, lead, cadmium, zinc, manganese and chrome were not detected from the tested farmwaters. There was high significance between each other in total hardness, NO3-N, chloride ion and sulfate ion. There was regional and seasonal significance in only NO3-N but only regional significance in total hardness and chloride ion.