• Title/Summary/Keyword: Leaching characteristics

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Distribution of Some Environmental Radionuclides in Rocks and Soils of Guemjeong-Gu Area in Busan, Korea (부산시 금정구 일대 암석 및 토양에서 일부 환경방사성 핵종들의 분포 특성)

  • Lee, Hyo-Min;Moon, Ki-Hoon;Kim, Jin-Seop;Ahn, Jung-Keun;Kim, Hyun-Chul
    • The Journal of the Petrological Society of Korea
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    • v.17 no.3
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    • pp.179-190
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    • 2008
  • The distribution characteristics of some major environmental radionuclides ($^{40}K$, $^{228}Ac$, $^{226}Ra$, $^{222}Rn$) and U in rocks, soils and soil gas were studied at Geumjeong-Gu, Busan, Korea. The activities of radionuclides in granitic rocks are decreased in the odor of $^{40}K$>thorium decay series>uranium decay series. This reveals that Th was relatively more enriched in granitic rocks than U. The U content and activity of $^{226}Ra$ and $^{228}Ac$, however, don't reflect the fractionation sequence of granitic rocks in the study area. The activities of all these radionuclides and U content in soils are generally higher than in rocks, and their distribution in rocks, soils and soil gas show very low co-relationship. These facts indicate that the activities of radionuclides in soil and soil gas were greatly affected by leaching and adsorption properties of the radionuclides and their parents during weathering and pedogenetic process rather than their concentrations in parent rocks.

Quality Characteristics of Tea Thermally Processed from Dried Ixeris dentata Root (열처리에 따른 씀바귀 침출차의 품질특성)

  • Lee, Ka-Soon;Kim, Gwan-Hou;Kim, Hyun-Ho;Kim, Eun-Soo;Park, Hae-Min;Oh, Man-Jin
    • Food Science and Preservation
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    • v.15 no.4
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    • pp.524-531
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    • 2008
  • To investigate tea prepared from Ixeris dentata root, color, and levels of free sugars, organic acids, cynaroside, total polyphenolics, and free amino acids were investigated using various thermal processing methods. These included natural drying(ND), hot-air drying(HAD, $75^{\circ}C$), hot-air drying after steam(HADS, steaming at $95^{\circ}C$ for 30 min) and roasting after hot-air drying(RHAD, roasting at $140^{\circ}C$ for $2{\sim}3$ min). Total free sugars, organic acids, cynaroside, and free amino acids contents were highest after ND treatment. Total polyphenolics was highest after RHAD processing. The level of cynaroside, a principal component of Ixeris dentata root, was significantly decreased by HADS. The major free sugars were fructose, glucose and sucrose. Succinic acid was prominent among organic acids, and was present at 2.25%(v/v) after ND treatment. The lightness(L), redness(a), and yellowness(b) of all dried Ixeris dentata root powders were best after RHAD treatment, but analysis of the leaching liquids after hot water treatment yielded variable results. Lightness and redness were the highest after RHAD and yellowness was the highest after ND treatment. Overall, the RHAD drying method was found to be superior to other methods, in sensory evaluation tests.

Quality comparison of hot-water leachate from teabags containing Citrus junos peels dried using different methods (건조방법을 달리한 유자껍질 티백차의 품질특성 비교)

  • Park, Han-Sol;Lee, Hyeon-Jeong;Youn, Kwang-Sup;Kim, Dong-Seob;Kim, Han-Soo;Lee, Young-Guen;Seong, Jong-Hwan;Chung, Hun-Sik
    • Food Science and Preservation
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    • v.24 no.8
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    • pp.1088-1093
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    • 2017
  • This study was conducted to investigate the effects of drying methods for Citrus junos peels on quality characteristics of the hot-water leachate from teabags containing those peels. Fresh peels were hot-air ($50^{\circ}C$), cold-air ($30^{\circ}C$), or freeze-dried ($-45^{\circ}C$), powdered to a size of 40 mesh, packaged with a paper sachet, and then the packaged teabags were leached for 10 min with hot-water ($70^{\circ}C$). $L^*$ value (lightness) and $-a^*$ value (greenness) of the peel powder were the highest in the freeze-dried samples. Soluble solids and titratable acidity of the teabag leachate were in the following order; cold-air, freeze, and hot-air dried samples. Among free sugar contents in all samples, fructose content was the highest, followed by glucose and sucrose. Fructose and glucose contents were not affected by drying methods. There was no significant difference in the flavonoid content among the peels dried using three drying methods. DPPH radical-scavenging activity of the leachate was the highest in the cold-air dried sample. These results suggest that cold-air drying would be an effective method to enhance the quality of hot-water leachate of teabags prepared from C. junos peels.

Filter Media Specifications for Low Impact Development: A Review of Current Guidelines and Applications (LID 시설 여재에 관한 기술지침 및 적용에 관한 고찰)

  • Guerra, Heidi B.;Kim, Lee-Hyung;Kim, Youngchul
    • Journal of Wetlands Research
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    • v.21 no.4
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    • pp.321-333
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    • 2019
  • A primary aspect of low impact development (LID) design that affects performance efficiency, maintenance frequency, and lifespan of the facility is the type of filter media as well as the arrangement or media profile. Several LID guidelines providing media specifications are currently available and numerous studies have been published presenting the effectiveness of these systems. While some results are similar and consistent, some of them still varies and only a few focuses on the effect of filter media type and arrangement on system performance. This creates a certain level of uncertainty when it comes to filter media selection and design. In this review, a synthesis of filter media specifications from several LID design guidelines are presented and relevant results from different laboratory and field studies are highlighted. The LID systems are first classified as infiltration or non-infiltration structures, and vegetated or non-vegetated structures. Typical profiles of the media according to classification are shown including the different layers, materials, and depth. In addition, results from previous studies regarding the effect of filter media characteristics on hydraulic and hydrologic functions as well as pollutant removal are compared. Other considerations such as organic media leaching, clogging, media washing, and handling during construction were also briefly discussed. This review aims to provide a general guideline that can contribute to proper media selection and design for structural LIDs. In addition, it also identifies opportunities for future research.

A Study on the Characterization of Neodymium Oxalate by Reaction Crystallization (반응성 결정화에 의한 네오디뮴 옥살레이트 특성 고찰)

  • Yoon, Ho-Sung;Kim, Chul-Joo;Kim, Joon-Soo
    • Resources Recycling
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    • v.13 no.5
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    • pp.37-44
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    • 2004
  • In this study, neodymium oxalate powders were prepared by injecting oxalic acid to the neodymium chloride solution resulted from the acid leaching solution of NdFeB magnet scrap. The effect of experimental conditions on the characteristics of neodymium oxalate powders were investigated. Neodymium oxalate was aggregated by primary particles formed by nucleation, and average size of aggregates was affected by experimental conditions. In a constant volume, increase of reactants affected the average size of aggregate formed by collision of primary particles. In a constant concentration of reactants, agitation speed decreased the size of aggregate due to breakage of particles attached on the surface of aggregate. The number of primary particles decreased with increasing reaction temperature, and the size of aggregates decreased due to the decrease of collision probability. From the results of decomposition behavior of neodymium oxalate, oxalate decomposed from $400^{\circ}C$, and neodymium oxide began to crystallize at above $620^{\circ}C$.

Correlation between Characteristics of SOD in Coastal Sewage and Predictive Factor (연안 저질 SOD의 특성과 유발 영향인자에 대한 상관관계)

  • Kim, Beom-Geun;Khirul, Md Akhte;Kwon, Sung-Hyun;Cho, Dae-Chul
    • Korean Journal of Environment and Ecology
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    • v.33 no.5
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    • pp.596-604
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    • 2019
  • This study conducted a sediment culture experiment to investigate the effects of sediment oxygen demand (SOD) and environmental factors on sediment and water quality. We installed a leaching tank in the laboratory, cultured it for 20 days, and analyzed the relationship between P and Fe in the sediment. As a result, the dissolved oxygen of the water layer decreased with time, while the oxidation-reduction potential of the sediment progressed in the negative direction to form an anaerobic reducing environment. The SOD was measured to be 0.05 mg/g at the initial stage of cultivation and increased to 0.09 mg/g on the 20th day, indicating the tendency of increasing consumption of oxygen by the sediment. The change is likely to have caused by oxygen consumption from biological-SOD, which is the decomposition of organic matter accumulated on the sediment surface due to the increase of chl-a, and chemical-SOD consumed when the metal-reducing product produced by the reduction reaction is reoxidized. The correlation between SOD and causality for sediment-extracted sediments was positive for Ex-P and Org-P and negative for Fe-P. The analysis of the microbial community in the sediment on the 20th day showed that anaerobic iron-reducing bacteria (FeRB) were the dominant species. Therefore, when the phosphate bonded to the iron oxide is separated by the reduction reaction, the phosphate is eluted into the water to increase the primary productivity. The reduced substance is reoxidized and contributes to the oxygen consumption of the sediment. The results of this study would be useful as the reference information to improve oxygen resin.

Evaluation of Rheological Properties and Acceptance Criteria of Solidifying Agents for Radioactive Waste Disposal Using Waste Concrete Powder (폐콘크리트를 재활용한 방사성 폐기물용 고화제의 레올로지 특성 및 인수기준 특성평가)

  • Seo, Eun-A;Kim, Do-Gyeum;Lee, Ho-Jea
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.276-284
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    • 2022
  • In this study, performance evaluation and rheological characteristics were analyzed for recycling the fine powder of nuclear power plant dismantled waste concrete as a solidifying agent for radioactive waste disposal. The radioactive concrete fine powder was used to prepare a simulated sample, and the test specimen was prepared using Di-water, CoCl2, and 1 mol CsCl aqueous solution as mixing water. Regardless of the aggregate mixing ratio and the type of mixing water, it satisfies the performance standard of 3.45 MPa for compressive strength at 28 days of age. All specimens satisfied the criteria for submersion strength, and the thermal cycle compressive strength satisfies the criteria for all specimens except Plain-50. As a result of evaluating the rheological properties of the solidifying agent, it was found that the increase in the aggregate mixing rate decreased the yield stress and plastic viscosity. The leaching index for cobalt and cesium of all specimens was 6 or higher, which satisfies the standard. In order to secure the stable performance of the solidifying agent, it is considered effective to use 40 % or less of the aggregate component in the solidifying agent.

Stabilization of Two Mine Drainage Treated Sludges for the As and Heavy Metal Contaminated Soils (오염토양 특성별 광산배수처리슬러지의 비소 및 중금속 안정화)

  • Tak, Hyunji;Jeon, Soyoung;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.27 no.4
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    • pp.10-21
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    • 2022
  • In the South Korea, 47% of abandoned mines are suffering from the mining hazards such as the mine drainage (MD), the mine tailings and the waste rocks. Among them the mine drainage which has a low pH and the high concentration of heavy metals can directly contaminate rivers or soil and cause serious damages to human health. The natural/artificial treatment facilities by using neutralizers and coagulants for the mine drainage have been operated in domestic and most of heavy metals in mind drainage are precipitated and removed in the form of metal hydroxide, alumino-silicate or carbonate, generating a large amount of mine drainage treated sludge ('MDS' hereafter) by-product. The MDS has a large surface area and many functional groups, showing high efficiency on the fixation of heavy metals. The purpose of this study is to develop a ingenious heavy metal stabilizer that can effectively stabilize arsenic (As) and heavy metals in soil by recycling the MDS (two types of MDS: the acid mine drainage treated sludge (MMDS) and the coal mine drainage treated sludge (CMDS)). Various analyses, toxicity evaluations, and leaching reduction batch experiments were performed to identify the characteristics of MDS as the stabilizer for soils contaminated with As and heavy metals. As a result of batch experiments, the Pb stabilization efficiency of both of MDSs for soil A was higher than 90% and their Zn stabilization efficiencies were higher than 70%. In the case of soil B and C, which were contaminated with As, their As stabilization efficiencies were higher than 80%. Experimental results suggested that both of MDSs could be successfully applied for the As and heavy metal contaminated soil as the soil stabilizer, because of their low unit price and high stabilization efficiency for As and hevry metals.

Physicochemical characteristics of hot-water leachate prepared from persimmon leaf dried after steaming or freezing treatment (스팀 및 동결 전처리가 건조 감잎 열수추출물의 이화학적 특성에 미치는 영향)

  • Hun-Sik Chung;Kwang-Sup Youn;Jong-Kuk Kim
    • Food Science and Preservation
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    • v.30 no.6
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    • pp.983-990
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    • 2023
  • This study was conducted to develop a preservation technology that can induce changes in physicochemical properties to effectively utilize of persimmon leaves. The application effects of steaming or freezing technique were investigated. Astringent persimmon leaves were steam-blanched (100℃, 30 sec) or frozen (-20℃, 15 d), followed by hot-air drying (50℃). The physicochemical properties of the extract obtained by hot-water leaching from the dried leaves were compared. The extract of leaves dried without pretreatment was used as a control. L* value was higher in steamed than in control and frozen. a* value was highest in the control. The browning index was higher in the frozen and lower in the steamed than in the control. Soluble solids were the highest in the steamed and the lowest in the frozen. Sucrose content was relatively high in the steamed, and the glucose and fructose contents were relatively high in the frozen. Total polyphenol content and DPPH radical scavenging activity were higher in steamed and lower in frozen than in control. Thus, it was confirmed that steam or freeze pretreatment after harvesting persimmon leaves affects the extraction yield, color, antioxidant capacity and component changes of dried persimmon leaves. Unlike steaming, freezing pretreatment showed the effect of promoting decomposition and browning reactions, and it is considered useful when such an effect is needed.

Physicochemical Characteristics of Tailings from the Various Types of Mineral Deposits (광상유형에 따른 광물찌꺼기의 물리화학적 특성)

  • Lee, Pyeong-Koo;Youm, Seung-Jun;Jung, Myung-Chae;Lee, Jin-Soo;Kwon, Hyun-Ho
    • Economic and Environmental Geology
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    • v.43 no.3
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    • pp.235-248
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    • 2010
  • To construct the standard methods for evaluation of physicochemical characteristics of tailings in Korea, specific gravity, paste pH, grain size, mineral compositions and heavy metal concentrations of total 26 tailings from 21 metallic mines were analyzed. Specific gravity of tailings ranged from 2.61 to 4.31 (avg. 3.04), and sand and silt grain were dominant in the tailings. Ranges of paste pH were 2.1-9.5 in tailings (7.1-9.2 at magmatic, skarn and hydrothermal replacement deposits and 2.1-9.5 at hydrothermal vein deposits). Additionally, hydrothermal vein deposits could be reclassified into three categories: (1) paste pH>7.0, (2) 4.0