• Title/Summary/Keyword: Layered method

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The Effect of Calcination Temperature on the Layered Li1.05Ni0.9Co0.05Ti0.05O2 for Lithium-ion Battery (리튬이온전지용 층상 Li1.05Ni0.9Co0.05Ti0.05O2에 대한 소성 온도의 영향)

  • Ko, Hyoung Shin;Park, Hyun Woo;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.718-724
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    • 2018
  • In this study, the $Ni_{0.9}Co_{0.05}Ti_{0.05}(OH)_2$ precursor was prepared by the concentration gradient co-precipitation method. In order to overcome the structural change due to oxygen desorption in the cathode active material with high nickel content, the physical and electrochemical analysis of the cathode active material according to the calcination temperature were investigated. Physical properties of $Li_{1.05}Ni_{0.9}Co_{0.05}Ti_{0.05}O_2$ were analyzed by FE-SEM, XRD and TGA. The electrochemical performance of the coin cell using a cathode active material and $LiPF_6$(EC:EMC=1:2 vol%) electrolyte was evaluated by the initial charge/discharge efficiency, cycle retention, and rate capabilities. As a result, the initial capacity and initial efficiency of cathode materials were excellent with 244.5~247.9 mAh/g and 84.2~85.8% at the calcination temperature range of $750{\sim}760^{\circ}C$. Also, the capacity retention exhibited high stability of 97.8~99.1% after 50cycles.

Interpretation of Finite HMD Source EM Data using Cagniard Impedance (Cagniard 임피던스를 이용한 수평 자기쌍극자 송신원 전자탐사 자료의 해석)

  • Kwon Hyoung-Seok;Song Yoonho;Seol Soon-Jee;Son Jeong-Sul;Suh Jung-Hee
    • Geophysics and Geophysical Exploration
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    • v.5 no.2
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    • pp.108-117
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    • 2002
  • We have introduced a new approach to obtain the conductivity information of subsurface using Cagniard impedance over two-dimensional (2-D) model in the presence of horizontal magnetic dipole source with the frequency range of $1\;kHz\~1\;MHz$. Firstly, we designed the method to calculate the apparent resistivity from the ratio between horizontal electric and magnetic fields, Cagniard impedance, considering the source effects when the plane wave assumption is failed in finite source EM problem, and applied it to several numerical models such as homogeneous half-space or layered-earth model. It successfully provided subsurface information even though it is still rough, while the one with plane wave assumption is hard to give useful information. Next, through analyzing Cagniard impedance and apparent resistivity considering source effect over 2-D models containing conductive- or resistive-block, we showed that the possibility of obtaining conductivities of background media and anomaly using this approach. In addition, the apparent resistivity considering source effect and phase pseudosections constructed from Cagniard impedance over the isolated conductive- and resistive block model well demonstrated outlines of anomalies and conductivity distribution even though there were some distortions came from sidelobes caused by 2-D body.

The Capacity of Multi-Valued Single Layer CoreNet(Neural Network) and Precalculation of its Weight Values (단층 코어넷 다단입력 인공신경망회로의 처리용량과 사전 무게값 계산에 관한 연구)

  • Park, Jong-Joon
    • Journal of IKEEE
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    • v.15 no.4
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    • pp.354-362
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    • 2011
  • One of the unsolved problems in Artificial Neural Networks is related to the capacity of a neural network. This paper presents a CoreNet which has a multi-leveled input and a multi-leveled output as a 2-layered artificial neural network. I have suggested an equation for calculating the capacity of the CoreNet, which has a p-leveled input and a q-leveled output, as $a_{p,q}=\frac{1}{2}p(p-1)q^2-\frac{1}{2}(p-2)(3p-1)q+(p-1)(p-2)$. With an odd value of p and an even value of q, (p-1)(p-2)(q-2)/2 needs to be subtracted further from the above equation. The simulation model 1(3)-1(6) has 3 levels of an input and 6 levels of an output with no hidden layer. The simulation result of this model gives, out of 216 possible functions, 80 convergences for the number of implementable function using the cot(x) input leveling method. I have also shown that, from the simulation result, the two diverged functions become implementable by precalculating the weight values. The simulation result and the precalculation of the weight values give the same result as the above equation in the total number of implementable functions.

Design and Properties of Laminating Waterborne PSA for Eco-friendly Flexible Food Packaging (식품연포장용 라미네이트 수성 감압점착제의 친환경적 적용에 대한 연구)

  • Lee, Jin-Kyoung;Shim, Myoung-Sik;Chin, In-Joo
    • Journal of Adhesion and Interface
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    • v.17 no.2
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    • pp.49-55
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    • 2016
  • In this study, we designed an environment friendly, water-based adhesive using the acrylic emulsion method as a replacement for solvent-based adhesives, which are most commonly used in layered laminates for flexible food packaging. We designed adhesives with different combinations of anionic, non-ionic, and phosphoric ester surfactants, and with different concentrations of chain transfer agent (CTA). We also examined the effect of the degree of cross-linking by synthesizing and comparing 8 test group adhesives with different types of functional monomers. Additionally, we synthesized 2 other test group pressure-sensitive adhesives (PSA) using styrene/alpha-methyl styrene/acrylic acid (SAA) semipolymer dispersing agents (with molecular weights of 13,000 g/mol and 8,600 g/mol, respectively) to replace the conventional surfactants. We evaluated whether the 10 test group pressure-sensitive adhesives met the basic physical property criteria required for flexible food packaging by carrying out a physical analysis of their glass transition temperature (Tg), particle size, adhesion, and molecular weight. In our test, 2 test group adhesives manufactured with the combination of anionic and non-ionic surfactants, CTA concentration of 0.2%, and functional monomers of hydroxyethyl acrylate (HEA) and glycidyl methacrylate (GMA) demonstrated molecular weight and flexibility suitable for flexible packaging, with low adhesiveness and small particle size.

A Design and Adaptation Technique of UML-based Layered Meta-Model for Component Development (컴포넌트 개발을 위한 UML 기반의 계층형 메타 모델 설계 및 적용기법)

  • Lee, Sook-Hee;Kim, Chul-Jin;Cho, Eun-Sook
    • Journal of the Korea Society for Simulation
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    • v.15 no.2
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    • pp.59-69
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    • 2006
  • Component-based software development is introduced as a new development paradigm in software development method. This approach is different from existing software development approach because it is based on reusable and autonomous unit, component. Therefore, component-based development(CBD)is divided into two stages; component development process and component assembly process; application development process. Component development process is the core of CBD because component has a key for good software. Currently many methodologies or tools have been introduced by various academies or industries. However, those don't suggest systematic and flexible modeling techniques adaptable easily into component development project. Existing approaches have a unique orarbitrary modeling technique or provide heuristic guidelines for component modeling. As a result, many component developers are faced with a difficult problems; how to developcomponent models, when develop which diagrams, and so on. In order to address this problem, we suggest a meta-model driven approach for component development in this paper. We provide meta-models according to both layer and development phase. We expect that suggested meta-models allow component developers to develop appropriate models of the time.

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Preparation and Gas Barrier Properties of Chitosan/Clay Nanocomposite Film (Chitosan/Clay 나노복합재료 필름의 제조와 기체투과 특성)

  • Nam Sang Yong;Park Ji Soon;Rhim Ji Won;Park Byung Gil;Kong Sung-Ho
    • Membrane Journal
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    • v.15 no.3
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    • pp.247-254
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    • 2005
  • Chitosan film has potential applications in agriculture, food, and pharmacy. However, films made only from chitosan lack gas barrier and have poor mechanical properties. For enhanced gas barrier and mechanical properties, chitosan/clay nanocomposites have been prepared with montmorillonite (MMT) which is a layered structure of clays and chitosan. The cationic biopolymer, chitosan is intercalated into $Na^+-montmorillonite$ through cationic exchange and hydrogen bonding process. Diluted acetic acid is used as solvent f3r dissolving and dispersing chitosan. Chitosan was intercalated or exfoliated in MMT and it was confirmed by X-ray diffraction method. D-spacing of the characteristic peak from MMT plate in chitosan/clay nanocomposites was moved and diminished. The thermal stability and the mechanical properties of the nanocomposites are measured by TGA and Universal Testing Machine. Gas permeability through the chitosan/clay nanocomposites films decreased due to increased tortuosity made by intercalation of clay in chitosan.

Impulse Response Filtration Technique for the Determination of Phase Velocities from SASW Measurements (SASW시험에 의한 위상속도 결정을 위한 임펄스 응답필터 기법)

  • ;Stokoe, K.H., Il
    • Geotechnical Engineering
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    • v.13 no.1
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    • pp.111-122
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    • 1997
  • The calculation of phase velocities in Spectral-Analysis -of-Surface -Waves (SASW) meas urements requires unwrapping phase angles. In case of layered systems with strong stiffness contrast like a pavement system, conventional phase unwrapping algorithm to add in teger multiples of 2n to the principal value of a phase angle may lead to wrong phase volocities. This is because there is difficulty in counting the number of jumps in the phase spectrum especially at the receiver spacing where the measurements are in the transition Bone of defferent modes. A new phase interpretation scheme, called "Impulse Response Fil traction ( IRF) Technique," is proposed, which is based on the separation of wave groups by the filtration of the impulse response determinded between two receivers. The separation of a wave group is based on the impulse response filtered by using information from Gabor spectrogram, which visualizes the propagation of wave groups at the frequency -time space. The filtered impulse response leads to clear interpretation of phase spectrum, which eliminates difficulty in counting number of jumps in the phase spectrum. Verification of the IRF technique was performed by theoretical simulation of the SASW measurement on a pavement system which complicates wave propagation.opagation.

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Step-down Piezoelectric Transformer Using PZT PMNS Ceramics

  • Lim Kee-Joe;Park Seong-Hee;Kwon Oh-Deok;Kang Seong-Hwa
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.3
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    • pp.102-110
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    • 2005
  • Piezoelectric transformers(PT) are expected to be small, thin and highly efficient, and which are attractive as a transformer with high power density for step down voltage. For these reasons, we have attempted to develop a step-down PT for the miniaturized adaptor. We propose a PT, operating in thickness extensional vibration mode for step-down voltage. This PT consists of a multi-layered construction in the thickness direction. In order to develop the step-down PT of 10 W class and turn ratio of 0.1 with high efficiency and miniaturization, the piezoelectric ceramics and PT designs are estimated with a variety of characteristics. The basic composition of piezoelectric ceramics consists of ternary yPb(Zr$_{x}$Ti$_{1-x}$)O$_{3}$-(1-y)Pb(Mn$_{1/3}$Nb1$_{1/3}$Sb$_{1/3}$)O$_{3}$. In the piezoelectric characteristics evaluations, at y=0.95 and x=0.505, the electromechanical coupling factor(K$_{p}$) is 58$\%$, piezoelectric strain constant(d$_{33}$) is 270 pC/N, mechanical quality factor(Qr$_{m}$) is 1520, permittivity($\varepsilon$/ 0) is 1500, and Curie temperature is 350 $^{\circ}C$. At y = 0.90 and x = 0.500, kp is 56$\%$, d33 is 250 pC/N, Q$_{m}$ is 1820, $\varepsilon$$_{33}$$^{T}$/$\varepsilon$$_{0}$ is 1120, and Curie temperature is 290 $^{\circ}C$. It shows the excellent properties at morphotropic phase boundary regions. PZT-PMNS ceramic may be available for high power piezoelectric devices such as PTs. The design of step-down PTs for adaptor proposes a multi-layer structure to overcome some structural defects of conventional PTs. In order to design PTs and analyze their performances, the finite element analysis and equivalent circuit analysis method are applied. The maximum peak of gain G as a first mode for thickness extensional vibration occurs near 0.85 MHz at load resistance of 10 .The peak of second mode at 1.7 MHz is 0.12 and the efficiency is 92$\%$.

Thermal Insulation Effect of Inflatable Life Vest on the Drowned Individual estimated by Numerical Analysis (익수자 체온 저하에 미치는 팽창식 구명동의의 단열효과 수치 분석)

  • Kim, Sung Chan;Lee, Kyung Hoon;Hwang, Se Yun;Lee, Jin Sung;Lee, Jang Hyun
    • Journal of Navigation and Port Research
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    • v.39 no.4
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    • pp.285-291
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    • 2015
  • Exposure to cold sea water can be life-threatening to the drowned individual. Although appropriate life jacket can be usually be provided for the buoyance at the drowning accident, heat loss can make the drowned individual experience the hypothermia. Inflatable life jackets filled with inflatable air pocket can increase the thermal protection as well as the buoyancy force. Because it is important to know how the human body behaves unde the different life jacket, present study compares the thermal insulation capacity of solid type life jacket with that of inflatable life jacket. In order to represent the insulation capacity of life jacket, thermal resistance is estimated based on the assumption of steady-state. Also, a transient three-dimensional thermal distribution of the thigh is analyzed by using finite element method implementing the Pennes bioheat equation. The finite element model is a segmental, multi-layered representation of the body section which considers the heat conduction within tissue, bone, fat and local blood flow rate.

A Study for Safety Management on the Basis of Lateral Displacement Rates of Anchored In-situ Walls by Collapse Case Histories (붕괴 사례를 통한 앵커지지 가설흙막이벽체의 수평변위속도에 의한 안전관리 연구)

  • Chung, Dae-Seouk;Lee, Yong-Beom
    • Journal of the Society of Disaster Information
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    • v.14 no.3
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    • pp.367-378
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    • 2018
  • Purpose: The objective of this study is to present a reasonable safety management of the anchored in-situ wall systems constructed in the ground conditions consisting of multi-layered soils underlain by bedrocks in the urban area of Korea. Method: Field measurements collected from collapse case histories with deep excavations were analyzed for the safety management of the wall systems supported by the earth anchors in terms of lateral displacement rates. Results: The average maximum lateral displacement rate in a collapsed zone of the in-situ wall significantly increased upon the completion of the excavation. Particularly, the collapse of the in-situ wall system due to the sliding occurring along the discontinuities of the rock produced a considerably large lateral displacement rate over a relatively short period. Conclusion: For predicting and preventing the collapse of the wall system during or after the excavation work, the utilization of the safety management criteria of the in-situ wall system by the lateral displacement rate was found to be much more reasonable in judging the safety of earthworks than the application of the quantitative management criteria which have been commonly used in the excavation sites.