• 제목/요약/키워드: Layered method

검색결과 1,312건 처리시간 0.023초

Layered Nickel-Based Oxides on Partially Oxidized Metallic Copper Foils for Lithium Ion Batteries

  • Chung, Young-Hoon;Park, Sun-Ha;Kim, Hyun-Sik;Sung, Yung-Eun
    • Journal of Electrochemical Science and Technology
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    • 제2권4호
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    • pp.204-210
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    • 2011
  • Thin film electrodes have been intensively studied for active materials and current collectors to enhance the electrochemical performance. Here, porous structures of nickel-based oxide films, consisting of nickel oxide and copper (II) oxide, which was derived from the copper substrate during the annealing process, were deposited on metallic copper foils. The half-cell tests revealed excellent capacity retention after $80^{th}$ charge/discharge cycles. Some films showed an excess of the theoretical capacity of nickel oxides, which mainly originate from partially oxidized copper substrates during annealing. These results exhibit that both a preparation method of an active materials and partially oxidized current collectors could be important roles to apply thin film electrodes.

The Synthesis of Na0.6Li0.6[Mn0.72Ni0.18Co0.10]O2 and its Electrochemical Performance as Cathode Materials for Li ion Batteries

  • Choi, Mansoo;Jo, In-Ho;Lee, Sang-Hun;Jung, Yang-Il;Moon, Jei-Kwon;Choi, Wang-Kyu
    • Journal of Electrochemical Science and Technology
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    • 제7권4호
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    • pp.245-250
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    • 2016
  • The layered $Na_{0.6}Li_{0.6}[Mn_{0.72}Ni_{0.18}Co_{0.10}]O_2$ composite with well crystalized and high specific capacity is prepared by molten-salt method and using the substitution of Na for Li-ion battery. The effects of annealing temperature, time, Na contents, and electrochemical performance are investigated. In XRD analysis, the substitution of Na-ion resulted in the P2-$Na_{2/3}MO_2$ structure ($Na_{0.70}MO_{2.05}$), which co-exists in the $Na_{0.6}Li_{0.6}[Mn_{0.72}Ni_{0.18}Co_{0.10}]O_2$ composites. The discharge capacities of cathode materials exhibited $284mAhg^{-1}$ with higher initial coulombic efficiency.

PCS용 표면실장형 칩 유전체 세라믹 안테나 설계 (Design of a Surface-mounted Chip Dielectric Ceramic Antenna for PCS Phone)

  • 이종환;우종명;김현학;김경용
    • 한국전자파학회논문지
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    • 제11권1호
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    • pp.55-62
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    • 2000
  • 본 논문에서는 휴대전화 단말기(핸드폰) 안테나를 co-planar 급전 구조의 회로기판상에 표면장착 가능한 칩형태로 설계 하였다. 설계된 안테나는 유전체 세락믹 ($\varepsilon_{\tau}$=23)을 적층하여 직육면체 형태($7.5mm\times4.5mm\times0.4mm$)로 만들고 그 표면에 $\lambda$/4 파장 모노폴 방사소자를 헬리컬 구조로 형성시켜 제작되었다. 제특성 측정 결과 반사 손실 27.36dB,-10dB 대역폭 76MHz(3.97%), H면 평균이득-9.43dBd로 일반적인 모노폴 안테나 방사 특성을 나타내었다.

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Nondestructive Evaluation of Microstructure of SiCf/SiC Composites by X-Ray Computed Microtomography

  • Kim, Weon-Ju;Kim, Daejong;Jung, Choong Hwan;Park, Ji Yeon;Snead, Lance L.
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.378-383
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    • 2013
  • Continuous fiber-reinforced ceramic matrix composites (CFCCs) have a complex distribution of porosity, consisting of interfiber micro pores and interbundle/interply macro pores. Owing to the complex geometry of the pores and fiber architecture, it is difficult to obtain representative microstructural features throughout the specimen volume with conventional, destructive ceramographic approaches. In this study, we introduce X-ray computed microtomography (X-ray ${\mu}CT$) to nondestructively analyze the microstructures of disk shaped and tubular $SiC_f$/SiC composites fabricated by the chemical vapor infiltration (CVI) method. The disk specimen made by stacking plain-woven SiC fabrics exhibited periodic, large fluctuation of porosity in the stacking direction but much less variation of porosity perpendicular to the fabric planes. The X-ray ${\mu}CT$ evaluation of the microstructure was also effectively utilized to improve the fabrication process of the triple-layered tubular SiC composite.

유기-무기 복합소재로부터 CuO합성 (Synthesis of CuO from organic-inorganic hybrid)

  • 허영덕;권석순;국원근
    • 한국결정성장학회지
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    • 제15권5호
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    • pp.193-197
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    • 2005
  • 층상 구조의 유기-무기 복합 소재 $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$를 전구체로 사용하여 CuO를 합성하였다. 외부의 다른 유기화합물 주형이 없이 단순한 $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$의 열분해 방법을 사용하였다 이 방법은 저렴한 가격으로 단일 결정의 CuO 입자를 양산하는 방법을 제공한다 응집된 CuO 입자의 형태는 전구체의 구조에 크게 영향을 받는다.

차륜형 이동로봇의 경로 계획과 자율 주행을 위한 하이브리드 시스템 모델과 제어 (Hybrid System Modeling and Control for Path Planning and Autonomous Navigation of Wheeled Mobile Robots)

  • 임미섭;임준홍
    • 대한전기학회논문지:시스템및제어부문D
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    • 제49권1호
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    • pp.33-40
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    • 2000
  • In this paper, an integrated method for the path planning and motion control of wheeled mobile robots using a hybrid system model and control is presented. The hybrid model including the continuous dynamics and discrete dynamics with the continuous and discrete state vector is derived for a two wheel driven mobile robot. The architecture of the hybrid control system for real time path planning and following is designed which has the 3-layered hierarchical structure : the discrete event system using the digital automata as the higher process, the continuous state system for the wheel velocity controls as the lower process, and the interface system as the interaction process between the continuous system as the low level and the discrete event system as the high level. The reference motion commands for autonomous navigation are generated by the abstracted motion in the discrete event system. The motion control tasks including the feasible path planning and autonomous motion control with various initial conditions are investigated as the applications by the simulation studies.

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Langmuir-Blodgett(LB)법을 이용한 (N-docosyl pyridinium)-TCNQ(1:2) 착체의 초박막 제작 (Fabrication of Ultra Thin Films with (N-docosyl pyridinium)-TCNQ(1:2) Complex by the Langmuir-Blodgett(LB) Method)

  • 강훈;김용태;정순욱;손병청;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1988년도 추계학술대회 논문집
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    • pp.54-57
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    • 1988
  • A film is fabricated by depositing several slices ultra thin films on a slide glass. The UV-absorbance outcomed on a multi-layered bulky ultra thin film with (N-docosyl pyridinium)-TCNQ (1:2) complex results tat the quantity of UV-absorbances becomes more linearly according to the number of layer becomes higher. In addition, it is found that the capacitance of this film gets smaller as the number of layer gets higher. Finally, the conductivity of this film is measured by the direction of the long axis of the TCNQ radical anion, and is resulted in a remarkably low value (about 1.66∼3.78 x 10$\^$-14/S/cm).

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새로운 합성법에 의한 LiV$_3$O$_8$ 의 초음파처리 특성 (The Ultrasonic Treatment Characteristics of LiV$_3$O$_8$ by New Synthesis)

  • 박수길;김종진;손원근;김상욱;류부형;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.151-154
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    • 1998
  • The layered trivanadate, LiV$_3$O$_{8}$ has been investigated as a cathode material for secondary lithium batteries. Early in its development the preparation method of LiV$_3$O$_{8}$ strongly influenced its electrochemical properties, such as discharge capacity, rate capability and cycling efficiency. In the present experiment, a new synthesis route has been applied to obtain LiV$_3$O$_{8}$ . Instead of the conventional high temperature technique leading to the crystalline form, a solution technique producing the amorphous form has been used. This material, after dehydration, shows an electrochemical performance exeeding that of the crystalline one. The rationale for this behavior mainly lies in microscopic factors, i.e., in the possibility for the unit cell of amorphous LiV$_3$O$_{8}$ to insert up to 9 Li$^{+}$, instead of six for crystalline LiV$_3$O$_{8}$ . The ultrasonically treated products in water were characterized by XRD, TGA, DSC, and SEM. These measurements showed that the ultrasonic treatment process of crystalline LiV$_3$O$_{8}$ causes a decrease in crystallinity and considerable increases in specific surface area and interlayer spacing.g.

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Investigating deformations of RC beams: experimental and analytical study

  • Parrotta, Javier Ezeberry;Peiretti, Hugo Corres;Gribniak, Viktor;Caldentey, Alejandro Perez
    • Computers and Concrete
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    • 제13권6호
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    • pp.799-827
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    • 2014
  • In this paper, a theoretical and experimental study of the sectional behaviour of reinforced concrete beams subjected to short-term loads is carried out. The pure bending behaviour is analysed with moment-curvature diagrams. Thus, the experimental results obtained from 24 beams tested by the authors and reported in literature are compared with theoretical results obtained from a layered model, which combines the material parameters defined in Model Code 2010 with some of the most recognized tensions-tiffening models. Although the tests were carried out for short-term loads, the analysis demonstrates that rheological effects can be important and must be accounted to understand the experimental results. Another important conclusion for the beams tested in this work is that the method proposed by EC-2 tends to underestimate the tension-stiffening effects, leading to inaccuracies in the estimations of deflections. Thus, the actual formulation is analysed and a simple modification is proposed. The idea is the separation of the deflection prediction in two parts: one for short-term loads and other for rheological effects (shrinkage). The results obtained are in fairly good agreement with the experimental results, showing the feasibility of the proposed modification.

Evaluation of extension in service life and layer thickness reduction of stabilized flexible pavement

  • Nagrale, Prashant P.;Patil, Atulya
    • Advances in Computational Design
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    • 제3권2호
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    • pp.201-212
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    • 2018
  • Decrease in availability of suitable subbase and base course materials for highway construction leads to a search for economic method of converting locally available troublesome soil to suitable one for highway construction. Present study insights on evaluation of benefits of stabilization of subgrade soils in term of extension in service life (TBR) and layer thickness reduction (LTR). Laboratory investigation consisting of Atterberg limit, Compaction, California Bearing Ratio, unconfined compressive strength and triaxial shear strength tests were carried out on two types of soil for varying percentages of stabilizers. Vertical compressive strains at the top of unstabilized and stabilized subgrade soils were found out by elastoplastic finite element analysis using commercial software ANSYS. The values of vertical compressive strains at the top of unstabilized and stabilized subgrade, were further used to estimate layer thickness reduction or extension in service life of the pavement due to stabilization. Finite element modeling of the flexible pavement layered structure provides modern technology and sophisticated characterization of materials that can be accommodated in the analysis and enhances the reliability for the prediction of pavement response for improved design methodology. If the pavement section is kept same for unstabilized and stabilized subgrade soils, pavement resting on lime, fly ash and fiber stabilized subgrade soil B will have service life 2.84, 1.84 and 1.67 times than that of unstabilized pavement respectively. The flexible pavement resting on stabilized subgrade is beneficial in reducing the construction material. Actual savings would depend on the option exercised by the designer for reducing the thickness of an individual layer.