• 한국분말재료학회지
• /
• 제12권2호
• /
• pp.122-130
• /
• 2005

Layered silicate was synthesized at hydrothermal condition from silica adding to various materials. Nano-clay was synthesized by intercaltion of various amine compounds into synthetic layered silicate. The products were analysed by XRD, SEM, and FT-IR in order to examine the condition of synthesis and intercalation. From the results, it was confirmed that kaolinite was synthesized from precipitated silica and gibbsite at $220^{\circ}C$ during 10 days, and hetorite was synthesized from silica sol at $100^{\circ}C$ during 48 h. Na-Magadiite was synthesized from silica gel at $150^{\circ}C$ during 72 h, and Na-kenyaite was synthesized from silica gel at $160^{\circ}C$ during 84 h. Nano-clay was prepared using synthetic layered silicate intercalated with various amine compounds. Kenyaite was easily intercalated by various organic compounds, and has the highest basal-spacing value among other layered silicates. Basal-spacing was changed according to the length of alkyl chain of amine comopounds. Polymer can be easily intercalated by dispersion with large space of interlayer. Finally, epoxy/nano-clay nanocomposite can be easily prepared.

• 한국해양공학회지
• /
• 제38권1호
• /
• pp.30-42
• /
• 2024

This study examined the jack-up spudcan penetration for a new type of offshore wind substructure newly proposed using the jack-up concept to reduce construction costs. The jack-up spudcan for offshore wind turbines should be designed to penetrate a stable soil layer capable of supporting operational loads. This study evaluated multi-layered soil conditions using centrifuge tests: loose sand over clay and loose sand-clay-dense sand. The penetration resistance profiles of spudcan recorded at the centrifuge tests were compared with the ISO and InSafeJIP methods. In the tests, a spudcan punch-through effect slightly emerged under the sand-over-clay condition, and a spudcan squeezing effect occurred in the clay-over-sand layer. On the other hand, these two effects were not critically predicted using the ISO method, and the InSafeJIP result predicted only punch-through failure. Nevertheless, ISO and InSafeJIP methods were well-matched under the conditions of the clay layer beneath the sand and the penetration resistance profiles at the clay layer of centrifuge tests. Therefore, the ISO and InSafeJIP methods well predict the punch-through effect at the clay layer but have limitations for penetration resistance predictions at shallow depths and strong stratum soil below a weak layer.

• 한국지반공학회논문집
• /
• 제19권1호
• /
• pp.121-129
• /
• 2003

층상점토지반의 극한지지력에 대하여 수치해석적 방법을 이용하여 거친 띠기초, 미끈한 띠기초에 대하여 해석을 수행하였다. 유한요소법과 유한차분법(FLAC)을 사용하여 층상점토 기초지반의 파괴거동 및 전반적인 하중-변위관계, 극한지지력에 대하여 수치해석적 방법으로 검토하였다. 해석된 결과를 분석하여보면, 이러한 수치해석적 방법을 통해서 층상점토 지반의 극한지지력, 진행성 파괴거동을 충분히 검토할 수 있음을 보여주었다. 그러나 정도가 높은 해석결과를 얻기 위해서는 수치해석에 큰 영향을 미치는 조절요인(항복함수선택, 해석증분수)과 두 가지 이상의 수치해석적 방법에 의하여 해석결과를 비교 분석하는 것이 필요하다.

• 한국지열·수열에너지학회논문집
• /
• 제7권2호
• /
• pp.43-50
• /
• 2011

This paper presents how to analyze heat transfer characteristics of double-layered soils. Thermal response tests were conducted to measure the ground thermal conductivities of Joomunjin sand and double layered soils filled in a steel box of which the size is $5m{\times}1m{\times}1m$. Double-layered soils were composed of Joomunjin sand and Kaoline clay. Each thermal conductivity of Joomunjin sand and Kaloine clay was measured by using Heat Flow Meter considering different void ratio. The ground thermal conductivity of double-layered soils was 15% smaller than that of Joomunjin sand.

• 폴리머
• /
• 제27권4호
• /
• pp.377-384
• /
• 2003

직접 중합법으로 내충격성 폴리스티렌과 유기화 층상 실리케이트의 나노복합체를 합성하여 점토 첨가에 의한 고무 입자 크기 및 물성의 영향을 조사하였다. 사용한 유기화 점토 중에서는 벤젠기를 지닌 몬모릴로나이트가 폴리스티렌에 우수한 분산 효과를 나타내었다 유기화 점토를 첨가한 경우 X선 회절 분석에서 층간삽입된 피이크를 관찰할 수 있었으나, 고무의 농도가 증가할수록 낮은 각도쪽으로 이동하는 것으로 보아 유기화 점토는 고무에 더 좋은 분산성을 보이는 것으로 파악된다. 분산상인 고무 입자는 점토를 첨가할수록 평균 입자경이 커지며 넓은 입도 분포를 나타내었는데, 이는 점토 첨가에 의해 폴리스티렌 상에 대한 고무 상의 점도비가 더욱 증가하여 평균 입자가 커졌으며 분산계가 불안정해져 넓은 입도 분포를 갖는 것으로 추정된다. 열중량 분석의 결과 나노복합체는 향상된 열적 물성을 보여주었고, 유변 물성을 측정한 결과 점토가 첨가됨에 따라 재료의 복소 점도 및 저장 탄성률은 향상되었다.

• Macromolecular Research
• /
• 제14권3호
• /
• pp.318-323
• /
• 2006

We investigated the rheological behaviors and orientation of three different types of layered silicate composite systems under external flow: microcomposite, intercalated and exfoliated nanocomposites. Rheological measurements under shear and uniaxial extensional flows, two-dimensional, small-angle X-ray scattering and transmission electron microscopy were conducted to investigate the properties, as well as nano- and micro-structural changes, of polymer/layered silicate nanocomposites. The preferred orientation of the silicate layers to the flow direction was observed under uniaxial extensional flow for both intercalated and exfoliated systems, while the strain hardening behavior was observed only in the exfoliated systems. The degree of compatibility between the polymer matrix and clay determined the microstructure of polymer/clay composites, strain hardening behavior and spatial orientation of the clays under extensional flow.

• 한국지반공학회지:지반
• /
• 제14권3호
• /
• pp.63-72
• /
• 1998

단단한 모래층 하부에 위치한 연약점토층에 설치된 수평 원형 앵커들의 극한 상향 인발력에 대한 실내모형실험 결과들을 제시하였다. 점토층의 한계매립비에 대한 효과를 평가하였다. 순극한상향인발력을 도출할 수 있는 단순화한 방법을 제시하였다.

• 한국마린엔지니어링학회:학술대회논문집
• /
• 한국마린엔지니어링학회 2006년도 전기학술대회논문집
• /
• pp.23-24
• /
• 2006

The International Maritime Organization announced that the regulation of nitrogen oxide put into force for vessels constructed after 2000 from May, 2005 as agenda is satisfied on May, 2004. A honeycomb-typed Pillared Inter-Layered Clay(PILC) catalyst was developed for do-NOx SCR system in 2004. This catalyst has been applied to 9H25/33 engine that is one of the main diesel engines in Engine Machinery Division of the Hyundai Heavy Industries CO., LTD. In addition, we have tried to develop better catalysts in the aspects of easy synthetic method and performance.

• 한국농공학회논문집
• /
• 제48권7호
• /
• pp.45-52
• /
• 2006

A cyclic viscoelastic-viscoplastic constitutive model for clay is incorporated into an effective stress based seismic response analysis to describe viscous effect of clay layer to sand layer during earthquake. The seismic response against main shock of 1995 Hyogoken Nambu Earthquake is analyzed in the present study. Acceleration responses in both clay layer and just upper liquefiable sand layer are damped due to viscous effect of clay. A cyclic viscoelastic-viscoplastic constitutive model for clay was implemented into a FEM code, and $Newmark{\beta}$ method was employed for the time discretization in the finite element formulation. Seismic responses were simulated by numerical method with recorded data at Port Island, Kobe, Japan. As results of this study, it was found that a cyclic viscoelastic-viscoplastic constitutive model can give good description of dynamic behavior characteristics including viscoelastic effect.

• 한국토양비료학회지
• /
• 제49권6호
• /
• pp.807-812
• /
• 2016

Soil amendment, especially addition of clay minerals, has been widely conducted to improve the physical and chemical properties of cultivated soils. However, there are no systematic studies on the effects of the structural type of clay minerals added. This study was conducted to investigate the effects of structural type of clay minerals on physical properties of soils. Two experimental soils, layer-dominant and granule-dominant ones, were mixed with either a layer-type smectite or a granule-type zeolite at a level of 2.0 wt%. It was observed that water permeability of soils was decreased by smectite whereas not significantly changed by zeolite. This effect was much greater in layered clay-dominant soil than in granular clay-dominant soil. Our results clearly indicated that the relationship of structural type between a soil and an amendment plays a decisive role in the soil properties. Therefore, it is highly recommended that the structural types of both soil and amendment be taken into consideration for soil amendment by clay minerals.