• Journal of Powder Materials
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• v.12 no.2 s.49
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• pp.122-130
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• 2005

Layered silicate was synthesized at hydrothermal condition from silica adding to various materials. Nano-clay was synthesized by intercaltion of various amine compounds into synthetic layered silicate. The products were analysed by XRD, SEM, and FT-IR in order to examine the condition of synthesis and intercalation. From the results, it was confirmed that kaolinite was synthesized from precipitated silica and gibbsite at $220^{\circ}C$ during 10 days, and hetorite was synthesized from silica sol at $100^{\circ}C$ during 48 h. Na-Magadiite was synthesized from silica gel at $150^{\circ}C$ during 72 h, and Na-kenyaite was synthesized from silica gel at $160^{\circ}C$ during 84 h. Nano-clay was prepared using synthetic layered silicate intercalated with various amine compounds. Kenyaite was easily intercalated by various organic compounds, and has the highest basal-spacing value among other layered silicates. Basal-spacing was changed according to the length of alkyl chain of amine comopounds. Polymer can be easily intercalated by dispersion with large space of interlayer. Finally, epoxy/nano-clay nanocomposite can be easily prepared.

• Journal of Ocean Engineering and Technology
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• v.38 no.1
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• pp.30-42
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• 2024

This study examined the jack-up spudcan penetration for a new type of offshore wind substructure newly proposed using the jack-up concept to reduce construction costs. The jack-up spudcan for offshore wind turbines should be designed to penetrate a stable soil layer capable of supporting operational loads. This study evaluated multi-layered soil conditions using centrifuge tests: loose sand over clay and loose sand-clay-dense sand. The penetration resistance profiles of spudcan recorded at the centrifuge tests were compared with the ISO and InSafeJIP methods. In the tests, a spudcan punch-through effect slightly emerged under the sand-over-clay condition, and a spudcan squeezing effect occurred in the clay-over-sand layer. On the other hand, these two effects were not critically predicted using the ISO method, and the InSafeJIP result predicted only punch-through failure. Nevertheless, ISO and InSafeJIP methods were well-matched under the conditions of the clay layer beneath the sand and the penetration resistance profiles at the clay layer of centrifuge tests. Therefore, the ISO and InSafeJIP methods well predict the punch-through effect at the clay layer but have limitations for penetration resistance predictions at shallow depths and strong stratum soil below a weak layer.

• Journal of the Korean Geotechnical Society
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• v.19 no.1
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• pp.121-129
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• 2003

Numerical studies on bearing capacity problems of layered clay are performed for smooth and rough strip footings. The finite element method and finite difference method (FLAC) are used for computations of the bearing capacity, entire load-displacement curve and the failure mechanism. The presented results show that it is possible to analyze the bearing capacity of layered clay and to give a progressive failure mechanism clearly. To obtain high quality solutions, it is necessary to review the results on control parameters(e.g., yield function, number of calculation) and compare the results by two numerical methods.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.7 no.2
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• pp.43-50
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• 2011

This paper presents how to analyze heat transfer characteristics of double-layered soils. Thermal response tests were conducted to measure the ground thermal conductivities of Joomunjin sand and double layered soils filled in a steel box of which the size is $5m{\times}1m{\times}1m$. Double-layered soils were composed of Joomunjin sand and Kaoline clay. Each thermal conductivity of Joomunjin sand and Kaloine clay was measured by using Heat Flow Meter considering different void ratio. The ground thermal conductivity of double-layered soils was 15% smaller than that of Joomunjin sand.

• Polymer(Korea)
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• v.27 no.4
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• pp.377-384
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• 2003

High impact polystyrene/organically modified layered silicate (HIPS/OLS) nanocomposites by in situ polymerization were synthesized to investigate the effect of clay on the particle size and properties of rubber. In the OLS, the montmorillonite having benzyl group showed best dispersion in polystyrene phase. With the addition of clay, the intercalated peak from XRB was confirmed, but the peak gradually shifted to lower angle as rubber concentration increased. Thus, it is speculated that the organoclay disperses better in rubber phase than in polystyrene phase. The average rubber particle size increased and the particle size distribution widened as the amount of clay increased, which may be caused by the increase of the viscosity ratio of rubber to polystyrene phases and the unstable dispersion. The materials having clay showed improved thermal properties from thermogravimetric analysis. Rheological properties such as complex viscosity and storage modulus increased as the amount of clay increased.

• Macromolecular Research
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• v.14 no.3
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• pp.318-323
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• 2006

We investigated the rheological behaviors and orientation of three different types of layered silicate composite systems under external flow: microcomposite, intercalated and exfoliated nanocomposites. Rheological measurements under shear and uniaxial extensional flows, two-dimensional, small-angle X-ray scattering and transmission electron microscopy were conducted to investigate the properties, as well as nano- and micro-structural changes, of polymer/layered silicate nanocomposites. The preferred orientation of the silicate layers to the flow direction was observed under uniaxial extensional flow for both intercalated and exfoliated systems, while the strain hardening behavior was observed only in the exfoliated systems. The degree of compatibility between the polymer matrix and clay determined the microstructure of polymer/clay composites, strain hardening behavior and spatial orientation of the clays under extensional flow.

• Geotechnical Engineering
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• v.14 no.3
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• pp.63-72
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• 1998

Laboratory model test results for ultimate uplift capacity of horizontal circular anchors embedded in soft clay overlain by dense sand are presented. The effect of the critical embedment ratio on the thickness of the clay layer was evalyated. An approximate preocedure for estimating the net ultimate capacity is presented.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.23-24
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• 2006

The International Maritime Organization announced that the regulation of nitrogen oxide put into force for vessels constructed after 2000 from May, 2005 as agenda is satisfied on May, 2004. A honeycomb-typed Pillared Inter-Layered Clay(PILC) catalyst was developed for do-NOx SCR system in 2004. This catalyst has been applied to 9H25/33 engine that is one of the main diesel engines in Engine Machinery Division of the Hyundai Heavy Industries CO., LTD. In addition, we have tried to develop better catalysts in the aspects of easy synthetic method and performance.

• Journal of The Korean Society of Agricultural Engineers
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• v.48 no.7
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• pp.45-52
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• 2006

A cyclic viscoelastic-viscoplastic constitutive model for clay is incorporated into an effective stress based seismic response analysis to describe viscous effect of clay layer to sand layer during earthquake. The seismic response against main shock of 1995 Hyogoken Nambu Earthquake is analyzed in the present study. Acceleration responses in both clay layer and just upper liquefiable sand layer are damped due to viscous effect of clay. A cyclic viscoelastic-viscoplastic constitutive model for clay was implemented into a FEM code, and $Newmark{\beta}$ method was employed for the time discretization in the finite element formulation. Seismic responses were simulated by numerical method with recorded data at Port Island, Kobe, Japan. As results of this study, it was found that a cyclic viscoelastic-viscoplastic constitutive model can give good description of dynamic behavior characteristics including viscoelastic effect.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.6
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• pp.807-812
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• 2016

Soil amendment, especially addition of clay minerals, has been widely conducted to improve the physical and chemical properties of cultivated soils. However, there are no systematic studies on the effects of the structural type of clay minerals added. This study was conducted to investigate the effects of structural type of clay minerals on physical properties of soils. Two experimental soils, layer-dominant and granule-dominant ones, were mixed with either a layer-type smectite or a granule-type zeolite at a level of 2.0 wt%. It was observed that water permeability of soils was decreased by smectite whereas not significantly changed by zeolite. This effect was much greater in layered clay-dominant soil than in granular clay-dominant soil. Our results clearly indicated that the relationship of structural type between a soil and an amendment plays a decisive role in the soil properties. Therefore, it is highly recommended that the structural types of both soil and amendment be taken into consideration for soil amendment by clay minerals.