• 제목/요약/키워드: Layer potential

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In-situ EQCM Study on Growth of Polypyrrole Films Using Gold Electrodes Modified with Self-Assembled Monolayers in an Aqueous Solution (자기 집합 단분자막 개질 금 전극을 이용한 수용액 중 폴리피를 성장에 관한 In-situ EQCM 연구)

  • Seo, Kyoung--Ja;Jeon, Il-Cheol
    • Journal of the Korean Electrochemical Society
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    • v.5 no.3
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    • pp.143-152
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    • 2002
  • The growth of Polypyrrole film has been investigated during electropolymerization in an aqueous solution on bare and SAM modified gold electrodes by in-situ EQCM and ex-situ AFM. According to the result of cyclic voltammetry measurements, in the case of a bare gold electrode, the electrochemical deposition of polypyrrole were dependent on the limiting oxidative potential, but not on scan numbers. When the limiting potential higher than 0.8 V was applied on the electrode, the amount of polypyrrole deposited on a gold electrode was rapidly increased and the abnormal mass change attributed to the rearrangement of polypyrrole films was observed as the scan number increased. The polypyrrole film Prepared on electrodes modified with 1-dodecanethiol SAM or thiophene SAM grew 3-dimensionally with the rearrangement of film. However, in the case of BPUS SAM, 2-dimensional layer-by-layer growth of film was observed without the rearrangement of film. AFM images showed films with chain-shaped and/ or donut-shaped polymers when grown rapidly and a wrinkled film at the steady state condition.

Preparation and Stability of Capsaicin-loaded Nanoemulsions by Microfluidazion (미세유동화법으로 제조한 캡사이신 함유 나노에멀션의 안정성)

  • Kim, Min-Ji;Lee, Soo-Jeong;Kim, Chong-Tai
    • The Korean Journal of Food And Nutrition
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    • v.29 no.6
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    • pp.985-997
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    • 2016
  • The objectives of this study, which filled gaps in previous studies, were: (1) to find the optimal mixing condition of nanoemulsions containing oleoresin capsicum (OC), Tween 80, propylene glycol (PG), and sucrose monostearate (SES) by microfluidization; (2) to investigate their properties and stability depending on such factors as pH, temperature, and heating time; (3) to measure the effect of adding ascorbic acid. In order to test these objectives, the following three experiments were conducted: Firstly, in order to find the optimal mixing ratio, nanoemulsions containing OC - the mean diameter of which is smaller than 100 nm - were prepared through the process of microfluidization; and their mean particle size, zeta potential, and capsaicinoids were measured. The test results indicated that the mixing ratio at OC : Tween 80 : PG + water(1:2) = 1 : 0.2 : 5 was optimal. Secondly, the properties and stability of nanoemulsions were investigated with varying parameters. The test results illustrated that single-layer nanoemulsions and double-layer nanoemulsions coated with alginate were stable, irrespective of all the parameters other than/except for pH 3. Thirdly, the properties of nanoemulsions were then analyzed according to the addition of ascorbic acid. The results demonstrated that the properties of single-layer nanoemulsions were not affected by addition of ascorbic acid. In case of alginate double-layer nanoemulsions, the particle size was reduced, and zeta potential increased with the addition of ascorbic acid. In conclusion, the demonstrated stability of various nanoemulsions under the different conditions in the present study suggests that these findings may constitute a basis in manufacturing various food-grade products which use nanoemulsions-and indicate that food nanoemulsions, if adopted in the food industry, have the potential to satisfy both the functionality and acceptability requirements necessary to produce commercially marketable food-grade products.

Electrochemical Characteristics in Sea Water of Al-3%Mg Arc Spray Coating Layer for Corrosion Protection with Sealing Treatment (후처리 적용에 따른 방식용 Al-3%Mg 용사코팅 층의 해수 내 전기화학적 특성)

  • Park, Il-Cho;Kim, Seong-Jong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.40 no.5
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    • pp.974-980
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    • 2015
  • Arc thermal spray coating using Al-3%Mg thermal spray wire was carried out to prevent steel from corrosion damage under the marine environment. Post-sealing was applied to Al-3%Mg spray coating treatment using organic/inorganic composite ceramics in order to improve the corrosion resistance of the as-sprayed coating. The results of various electrochemical experiments with sealing treatment indicated that the improvement in corrosion resistance was observed due to low current density in all applied potential range during anodic and cathodic polarization experiments. Futhermore, the natural potential measurement exhibited severe potential fluctuation due to influence of micro-crack presence on the surface of sealed thermal spray coating layer. In addition, the sealed layer was easily eliminated during anodic polarization. Nevertheless, Al-3%Mg spray coating layer improved corrosion resistance by sealing treatment because the sealed coating efficiency was determined to be 92.11%, indicating the exterior environment barrier effect which is based on the Tafel analysis.

On the Thick Axisymmetric Boundary Layer and Wake Around the Body of Revolution (몰수분의 두꺼운 경계층 및 반류해석)

  • Gang, Sin-Hyeong;Hyeon, Beom-Su;Lee, Yeong-Gil
    • 한국기계연구소 소보
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    • s.9
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    • pp.141-151
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    • 1982
  • An iterative procedure for the calculation of the thick axisymmetric boundary layer and wake near the stern of a body of revolution is presented. Procedure consists of the potential flow calculation by a method of the integral equation of first kind and the calculation of boundary layer and wake by a differential me¬thod of the boundary layer theory. Additionally, higher order terms are included in the conventional momentum equations and continuity equation for the consider¬ation of the characteristics of axisymmetric flow different from the one of two dimentional flow and the thick boundary layer. These solutions are matched at the edge of boundary layer and wake. The results obtained by the present me¬thod are compared with the experimental data and it is found that the nominal wake distribution at the propeller plane of a axisymmetric body is in good agree¬ment with the experiment.

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THE NUMERICAL STUDY ON THE SUPERSONIC INLET FLOW FIELD WITH A BUMP (Bump가 있는 초음속 흡입구 유동장의 수치적 연구)

  • Kim S. D.;Song D. J.
    • Journal of computational fluids engineering
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    • v.10 no.3 s.30
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    • pp.19-26
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    • 2005
  • The purpose of this paper is the study on the characteristics of an inlet system with shock/boundary layer interactions by using various types of bumps which are substituted for the conventional bleeding system in supersonic inlet. in this study a comprehensive numerical analysis has been performed to understand the three-dimensional flow field including shock/boundary layer interaction and growth of turbulent boundary layer that might occur around a three-dimensional bump in a supersonic inlet. The characteristics of boundary layer seen in the current numerical simulations indicate the potential capability of a three-dimensional bump to control shock/boundary layer interaction in supersonic inlets.

The Numerical Study on the Supersonic Flow field with a Bump (Bump가 있는 초음속 유동장의 수치적 연구)

  • Kim S. D.;Song D. J.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.04a
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    • pp.213-218
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    • 2005
  • The purpose of this study is the characteristics of an innovative inlet system with shock/boundary layer interactions by using various types of bumps which are substituted for the conventional bleeding system in supersonic inlet. This study performs a comprehensive numerical effort that be directed at better understanding the three-dimensional flowfield includes shock/boundary layer interaction and growth of turbulent boundary layer that occur around a three-dimensional bump in a supersonic inlet. The characteristics of boundary layer seen in the current numerical simulations indicates the potential capability of the three-dimensional bump to control shock/boundary layer interaction in supersonic inlets.

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First-Principles Study on the Electronic Structure of Bulk and Single-Layer Boehmite

  • Son, Seungwook;Kim, Dongwook;Na-Phattalung, Sutassana;Ihm, Jisoon
    • Nano
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    • v.13 no.12
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    • pp.1850138.1-1850138.6
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    • 2018
  • Two-dimensional (2D) or layered materials have a great potential for applications in energy storage, catalysis, optoelectronics and gas separation. Fabricating novel 2D or quasi-2D layered materials composed of relatively abundant and inexpensive atomic species is an important issue for practical usage in industry. Here, we suggest the layer-structured AlOOH (Boehmite) as a promising candidate for such applications. Boehmite is a well-known layer-structured material and a single-layer can be exfoliated from the bulk boehmite by breaking the interlayer hydrogen bonding. We study atomic and electronic band structures of both bulk and single-layer boehmite, and also obtain the single-layer exfoliation energy using first-principles calculations.

A Study on the Generation of the Earth Potential and Communication Line Noise. (대지전위와 통신회선 잡음 발생에 대한 고찰)

  • Yeo, Sang-Kun;Park, Chan-Won
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.05a
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    • pp.33-38
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    • 2007
  • This paper presents a experimental evidence of the generation of the earth potential and communication line noise from the electric railway. There is a critical measurement err in case of measuring the electrical power induced noise voltage and degree of cable balance in the field of earth potential generated. As a results, it has been found that the conventional cable has more noise immunity than shielded cable near the railway where the earth current flows through the sheath layer.

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Predicting aerodynamic characteristics of two-dimensional automobile shapes in ground proximity using an iterative viscous-potential flow technique (점성-비점성 유동 반복계산 방법을 이용한 2차원 자동차모형의 공력 특성 예측)

  • 최도형;최철진
    • Journal of the korean Society of Automotive Engineers
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    • v.8 no.1
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    • pp.52-61
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    • 1986
  • An iterative viscous-potential flow procedure has been developed and used to predict aerodynamic characteristics of automobiles in ground proximity. The method is capable of predicting the effects of separated flows. The viscous-potential flow iteration procedure provides the connection between potential flow, boundary layer and wake modules. The separated wake is modeled in the potential flow analysis by thin sheets across which exists a jump in velocity potential. The ground effect is properly accounted for by placing a body image in the potential flow calculation. The agreement between theory and experiment is good and, thus, demonstrates that the method can be used in the preliminary design stage.

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Thin Film Encapsulation with Organic-Inorganic Nano Laminate using Molecular Layer Deposition and Atomic Layer Deposition

  • Yun, Gwan-Hyeok;Jo, Bo-Ram;Bang, Ji-Hong;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.270-270
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    • 2016
  • We fabricated an organic-inorganic nano laminated encapsulation layer using molecular layer deposition (MLD) combined with atomic layer deposition (ALD). The $Al_2O_3$ inorganic layers as an effective single encapsulation layer were deposited at 80 degree C using ALD with alternating surface-saturation reactions of TMA and $H_2O$. A self-assembled organic layers (SAOLs) were fabricated at the same temperature using MLD. MLD and ALD deposition process were performed in the same reaction chamber. The prepared SAOL-$Al_2O_3$ organic-inorganic nano laminate films exhibited good mechanical stability and excellent encapsulation property. The measurement of water vapor transmission rate (WVTR) was performed with Ca test. We controlled thickness-ratio of organic and inorganic layer, and specific ratio showed a lowest WVTR value. Also this encapsulation layer contained very few pin-holes or defects which were linked in whole area by defect test. To apply into real OLEDs panels, we controlled a film stress from tensile to compressive and flexibility defined as an elastic modulus with organic-inorganic ratio. It has shown that OLEDs panel encapsulated with nano laminate layer exhibits better properties than single layer encapsulated in acceleration conditions. These results indicate that the organic-inorganic nano laminate thin films have high potential for flexible display applications.

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