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Surface characteristics and biocompatibility of bioinert nitrides ion plated titanium implant (생불활성 질화물 이온도금된 티타늄 임프란트의 표면특성 및 생체적합성)

  • Chang, Kap-Sung;Kim, Heung-Joong;Park, Joo-Cheol;Kim, Byung-Ock;Han, Kyung-Yoon
    • Journal of Periodontal and Implant Science
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    • v.29 no.1
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    • pp.209-231
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    • 1999
  • Even though titanium(Ti) and its alloys are the most used dental implant materials, there are some problems that Ti wears easily and interferes normal osteogenesis due to the metal ions. Ti coated with bioactive ceramics such as hydroxyapatite has also such problems as the exfoliation or resorption of the coated layer, Recent studies on implant materials have been proceeding to improve physical properties of the implant substrate and biocompatibility of the implant surfaces. The purpose of the present study was to examine the physical property and bone tissue compatibility of bioinert nitrides ion plated Ti, Button type specimens(14mm in diameter, 2.32rrun in height) for the abrasion test and cytotoxicity test and thread type implants(3.75mm in diameter, 6mm in length) for the animal experiments were made from Ti(grade 2) and 316LVM stainless steel. Ti specimens were ion plated with TiN, ZrN by the low temperature arc vapor deposition, and the depth profile of the TiN/Ti, ZrN/Ti ion plated surface was examined by Auger Electron Spectroscopy. Three kind of button type specimens .of TiN/Ti, ZrN/Ti and Ti were used for abrasion test, and HEPAlClC7 cells and CCD cells were cultivated for 4 days with the specimens for cytotoxicity test. Thread type implants of TiN/Ti, ZrN/Ti, Ti, 316LVM were implanted on the femur of 6 adult dogs weighing 10kg-13kg. Two dogs were sacrified for histological examination after 45 days and 90 days, and four dogs were sacrified for the removal torque test of the implant') after 90 days. The removal torque force was measured by Autograph (Shimadzu Co., AGS-1000D series, Japan). Abrasion resistance of TiN/Ti was the highest, and that of ZrN/Ti and Ti were followed. The bioinert nitride ion plated Ti had much better abrasion resistance, compared with Ti, In the cytotoxicity test, the number of both cells were increased in all specimens, and there were no significant difference in cytotoxic reaction among all groups (p>0.1), In histological examination, 316LVM showed the soft tissue engagement in interface between the implant and bone, but the other materials after 45 days noted immature new bone formation in the medullary portion along the implant surface, and those after 90 days showed implant support by new bone formation in both the cortical and the medullary portion, The removal torque force of Tilv/Ti showed significantly higher than that of Ti(p(O,05). The difference in removal torque force between TiN/Ti and ZrN/Ti was not significant(p>0.05), and that of 316LVM was lowest among all groups(p<0.05). These results suggest that bioinert nitrides ion plated Ti can resolve the existing problems of Ti and bioactive ceramics, and it may be clinically applicable to human.

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Integrated Simulation System of GIS and ANN for Land Price Appraisal (GIS 기반 지가산정 및 시뮬레이션 시스템)

  • Moon, Tae-Heon
    • Journal of the Korean Association of Geographic Information Studies
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    • v.3 no.2
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    • pp.1-10
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    • 2000
  • The purpose of this study is to develope a parcel-based automatic simulation system of land price through the integration of urban mathematical model and GIS. The appraisal process of public land price by the local government is simple but is a great time-consuming task. Moreover, it doesn't provide any statistical analysis and spatial presentation tools. So, it is difficult for planners or administrative officials to analyze the variation of land price with spatial idea. From these, a system is developed combining two sub-systems, they are ANN(Artificial Neural Network) for the calculation of land price and GIS for visual presentation. Using Matlab application, ANN model was designed having 3-layer structure and was trained with the sample data taken from Chinju city. With the trained network, the impact of 'road', 'parks', 'height control district' and 'beauty district' on land price in 9 regions(dong) are simulated. The results of the simulation were visualized with ArcView GIS. The automatic simulation system operated through the DDE(Dynamic Data Exchange) conversation between two applications. ArcView was set as client and Matlab as server. Scripting in ArcView and customizing a window of ArcView, this system can execute the whole process of simulation by just clicking a button with mouse. As a conclusion, this system was proved to be an effective and easily controllable planning support system for the land price simulation.

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The retrospective study of survival rate of implants with maxillary sinus floor elevation (상악동 거상술을 동반한 상악구치부에 식립된 임플란트 생존율에 대한 후향적 연구)

  • Kim, Beom-Jin;Lee, Jae-Hoon
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.36 no.2
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    • pp.108-118
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    • 2010
  • Introduction: Maxillary posterior region, compared to the mandible or maxillary anterior region, has a thin cortical bone layer and is largely composed of cancellous bone, and therefore, it is often difficult to achieve primary stability. In such cases, sinus elevation with bone graft is necessary. Materials and Methods: In this research, 121 patients who had implant placement after bone graft were subjected to a follow-up study of 5 years from the moment of the initial surgery. The total survival rate, 5-year cumulative survival rate and the influence of the following factors on implant survival were evaluated; the condition of the patient (sex, age, general body condition), the site of implant placement, diameter and length of the implant, sinus elevation technique, closure method for osseous window, type of prosthesis and opposing teeth. Results: 1. The 5-year cumulative survival rate of total implants was 90.5%, there was no significant difference between sex, age, the site of implant placement, diameter and length of the implant, sinus elevation technique, and the type of opposing teeth. 2. Patients with diabetes mellitus < osteoporosis and smooth-surfaced machined group < hydroxyapatite (HA)-treated group and homogenous demineralized freeze dried allogenic bone (DFDB) bone graft only group had significantly lower survival rate. 3. With less than 4 mm of residual alveolar ridge height, lateral approach without closing the osseous window resulted in a significantly lower survival rate. 4. Restoration of a single implant showed a significantly lower survival rate, compared to cases where the superstructure was joined with several implants in the area. Conclusion: Patients with diabetes or osteoporosis need longer period of time for osseointegration compared to the normal, and the dentists must be prudent when choosing a surface treatment type and the bone graft material. Also, as the vertical dimension of the residual alveolar ridge can influence the result, staged implant placement should be considered when it seems difficult for the implant to gain primary stability from the residual bone with less than 4 mm of vertical dimension. It is recommended to obdurate the bone window and that the superstructure be connected with several impants in the peripheral area.

The Influence of Surface Treatments on Shear Bond Strength between Zirconia Core and Heat Press Ceramic Interface (지르코니아 코어의 표면처리방법이 열 가압 세라믹과의 전단결합강도에 미치는 영향)

  • Park, Hang-Min;Chung, In-Sung
    • Journal of Technologic Dentistry
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    • v.31 no.2
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    • pp.23-30
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    • 2009
  • All-ceramic restorations have gained acceptance among clinicians and patients because of their superior esthetics. Most all-ceramic systems have a 2-layer structure, using a weak veneering ceramic over a strong supporting core. often, failure of all-ceramic restorations occurs when the veneering ceramic fractures, exposing the core material. The purpose of this study was to compare the shear bond strength of heat press ceramic system (Zirpress) to zirconia core with various surface treatments. 10 metal cores and 50 zirconia cores were fabricated and divided into six groups according to surface treatment such as Zirliner application, aluminium oxide blasting, and 9.5% HF etching. Sixty specimens were prepared using Zirpress, veneered 8mm height and 3mm in diameter, over the zirconia cores (n=10). The shear bond strength test was performed in a universal testing machine with a crosshead speed of 1/min. Ultimate shear bond strength data were analyzed with One-way ANOVA and the Scheffe's test (p=.05). Within the limits of this study, the following conclusions were drawn: The mean shear bond strengths (MPa) were: 12.93 for $110{\mu}m$ aluminium oxide blasting/Rexillium III/IPS e.Max Zirpress; 14.92 for $50{\mu}m$ aluminium oxide blasting ${\pm}9.5%$ HF etching/Zirconis core/IPS e.Max Zirpress; 16.37 for $110{\mu}$ aluminium oxide blasting + 9.5% HF etching/Zirconis core/IPS e.Max Zirpress; 12.89 for $200{\mu}$ aluminium oxide blasting + 9.5% HF etching/Zirconis core/IPS e.Max Zirpress; 19.30 for 9.5% HF etching/Zirconis core/IPS e.Max Zirpress; 19.55 for Zirliner/Zirconis core/IPS e.Max Zirpress. The mean shear bond strength for ZNTZH (Zirliner/Zirconis core) and ZNTEH (9.5% HF etching/Zirconis core) were significantly superior to MS110H ($110{\mu}$ aluminium oxide blasting/Rexillium III) and ZS200EH ($200{\mu}$ aluminium oxide blasting + 9.5% HF etching/Zirconis core) (p<0.05).

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Survey on distribution and vegetation environment of Tricholoma matsutake in Kyonggi province, Korea (경기도지역 송이버섯 분포 및 식생환경조사)

  • Ha, Tai-Moon;Kim, Young-Ho;Chi, Jeong-Hyun;Ju, Young-Cheuol;Kim, Hee-Dong;Sung, Jae-Mo
    • Journal of Mushroom
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    • v.2 no.4
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    • pp.175-183
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    • 2004
  • We carried out survey of a pine mushroom picking district and its vegetation environment for increase and maintainment of its production in Kyonggi province. The district which we could pick up pine mushroom among the nineteen surveyed district were sixteen such as Geoleun ri Gangcheon myeon Yeoju gun Kyonggi do, etc. and total yields were 470~600 kg in Kyonggi province. The temperature of atmosphere and earth in Yeoju and Bonghwa were droped to $19^{\circ}C$ at 5~7th september and maintained from $12^{\circ}C{\sim}18^{\circ}C$ during the a pine mushroom picking period. The density of a pine tree per $100m^2$ was 5.1~27.1 trees, the years of it was 15~50years old and height was 4~11 meter. The pine tree in a pine mushroom picking district was competed with oak trees, azaleas, lacquers, etc. The depth of organic materials accumulated on the pine mushroom mycelium layer was 4.5 cm in Yeoju. The soil texture of a pine mushroom picking district was almost sandy, soil pH was 4.3~5.1 and organic material content was 3.91~8.28%.

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Kernel Characteristics and Germination Rate during . the Grain Filling in Super Sweet Corn (초당옥수수 등숙시기에 따른 종실특성 변화와 발아율)

  • 정태욱;김선림;차선우;김달웅
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.45 no.3
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    • pp.176-180
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    • 2000
  • The higher sugar and lower starch in super sweet corn may be due to modified endosperm genes sh, bt series, but its seeds have major limiting factors causing low germination and low seedling vigor, This study was conducted to determine what measurable kernel characteristics during the grain tiling period might be more useful as a guide to optimize harvest date for good seed quality in hybrid super sweet corn production. Artificial crossing in super sweet corn hybrid (Chodangok 1) was made on the same day, and ears were harvested from 18 days to 53 days after pollination at weekly intervals. Kernel weight, moisture content, hardness, endosperm rate, seedling height and storage nutrients such as sugars, protein, starch, and germination rate were measured for the kernels at each harvest. Super sweet corn hybrid, Chodangok 1 presented satisfactory germination rate above 70% when harvested on 39 to 46 days after pollination. Its storage nutrients at that time were 23.7-24.2% in starch content 5.5-5.9% in total sugars, 38.9-46.6% in kernel moisture, and 62.7-64.2% in endosperm rate. Germination rate was extremely high when harvested on 39 days after pollination. The black layer of Chodangok 1 could not be used as an indicator for seed harvest. These results suggested that optimum harvest date seems to be 39 days, and kernel moisture and starch content could be used as indications of kernel maturity in deciding when to harvest fer good seed quality in super sweet corn.

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Community dynamics of Salix species during the sedimentation in Paksil-nup Wetland, Hapcheon (합천 박실늪의 퇴적에 따른 버들류 (Salix sp.)의 군집 동태)

  • Kim, Cheol-Soo;Lee, Pal-Hong;Son, Sung-Gon;Oh, Kyung-Hwan
    • Journal of Wetlands Research
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    • v.2 no.1
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    • pp.19-29
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    • 2000
  • The physico-chemical characteristics of core sediment, community dynamics of Salix species during the sedimentation were investigated in 1990~1997 for the purpose of inquiry to reveal the effects of terrestrialization on the environment and plant community in a natural wetland. The study site, Paksil-nup wetland was a valley blocked lake located near Hwang-River, Hapcheon-gun, Gyeongsangnam-do, Korea. The values of conductivity, organic matter, total nitrogen, exchangeable K, and exchangeable Ca were higher, and pH was lower in the upper layer of the core sediment. Soil properties such as available phosphorus, exchangeable Ca, exchangeable Na increased, and organic matter, total nitrogen, exchangeable K decreased during the sedimentation. Salix nipponica was the dominant species, and Salix glandulosa was subdominant among 10 Salix species. Sahx species were supposed to be the pioneer plants in shrub and tree layers during the succession in Paksil-nup wetland. Age class of SaliX species community from the epilittoral zone to the infralittoral zone were low, and age of Saljx species distributed from 2 years to 11 years. DBH, height, mean number of branches, number of herb species, and light intensity were increased, whereas density was decreased from a lower age to a higher age community. Salix nipponica was superior than Sahx purpurea var. japonica and other Salix species during the interspecific competition among Salix species.

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Environmental and Ecological Characteristics Distribution of Natural Growth Region in Rhododendron Brachycarpum (만병초 자생지의 환경생태학적 특성)

  • Lee, Byung-Chul;Shim, Ie-Sung
    • Journal of Environmental Science International
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    • v.20 no.10
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    • pp.1319-1328
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    • 2011
  • Rhododendron brachycarpum is a evergreen broad-leaved shrub and belongs to the Ericaceae family and the Rhododendron genus. It is well known for its beautiful leaves and flowers. There are 11 species of the Rhododendron genus in Korea. It includes 3 species - Rhododendron brachycarpum, Rhododendron aureum Georgi and Rhododendron brachycarpum var. roseum Koidz. They grow naturally over 1,000 meters above sea level of the Baekdu Mountain Range in Korea. These habitats, according to investigations of 9 Rhododendron brachycarpum natural habitats, are mostly located on the slope of mountains facing north at an altitude of 1,200 m to 1,526 m above sea level with angle of inclination from 30 degrees to 45 degrees. Based on the result of vegetation analysis of dominance species in the quadrates, there are Quercus aliena, Quercus mongolica Fisch. ex Ledeb, Abies holophylla in species of upper trees, and so on. Dominant species of woody plants in tree layer are Quercus aliena, Quercus mongolica Fisch. ex Ledeb, Abies holophylla, Betula platyphylla and Veeatrum patulum Loes. fil, Erythronium japonicum, Dryopteris crassirhizoma, Paeonia japonica var. glabra Makino are founded in herbaceous plants. And we can see another result of the investigation that the flowering rates of the plants with the buds are highly ranked mountains such as Mt. Hambaek 68%, Mt. Gyebang 40%, Mt. Yagksu 9%, Mt. Gaein 7% and Mt. Seolag 0%. The results show that there are 24 over 15-year-old Rhododendron brachycarpums in Mt. Odae and are 56 under 15-year-old trees in Mt. Hambaek and are no trees in Mt. Gyebang and are 9 over 30-year-dead trees only in Mt. Taebaeg. Out of found trees, the highest tree is 7 m in height and 0.6 m in diameter. Also this result shows what are the vulnerability factors of the natural habitats. They are as follows: indiscriminate trails in mountains, damages by mountain climbers, uncareful plant collecting, the fierce competitions with other plants such as Acer pseudosieboldianum var. ishidoyanum Uyeki, Quercus aliena, Celastrus orbiculatus and damages by disease and insect, unusual temperature in natural habitats, etc. Rhododendron brachycarpums have high ornamental value and excellent pharmaceutical effect. But the areas of its habitats decrease dramatically. So we need measures to protect and their natural habitats. It is necessary that we conductfurther investigations to designate conservation area for Rhododendron brachycarpums.

Property and Microstructure Evolution of Nickel Silicides on Nano-thick Polycrystalline Silicon Substrates (나노급 다결정 실리콘 기판 위에 형성된 니켈실리사이드의 물성과 미세구조)

  • Kim, Jong-Ryul;Choi, Young-Youn;Song, Oh-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.1
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    • pp.16-22
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    • 2008
  • We fabricated thermally-evaporated 10 nm-Ni/30 nm and 70 nm Poly-Si/200 nm-$SiO_2/Si$ structures to investigate the thermal stability of nickel silicides formed by rapid thermal annealing(RTA) of the temperature of $300{\sim}1100^{\circ}C$ for 40 seconds. We employed for a four-point tester, field emission scanning electron microscope(FE-SEM), transmission electron microscope(TEM), high resolution X-ray diffraction(HRIXRD), and scanning probe microscope(SPM) in order to examine the sheet resistance, in-plane microstructure, cross-sectional microstructure evolution, phase transformation, and surface roughness, respectively. The silicide on 30 nm polysilicon substrate was stable at temperature up to $900^{\circ}C$, while the one on 70 nm substrate showed the conventional $NiSi_2$ transformation temperature of $700^{\circ}C$. The HRXRD result also supported the existence of NiSi-phase up to $900^{\circ}C$ for the Ni silicide on the 30 nm polysilicon substrate. FE-SEM and TEM confirmed that 40 nm thick uniform silicide layer and island-like agglomerated silicide phase of $1{\mu}m$ pitch without residual polysilicon were formed on 30 nm polysilicon substrate at $700^{\circ}C\;and\;1000^{\circ}C$, respectively. All silicides were nonuniform and formed on top of the residual polysilicon for 70 nm polysilicon substrates. Through SPM analysis, we confirmed the surface roughness was below 17 nm, which implied the advantage on FUSI gate of CMOS process. Our results imply that we may tune the thermal stability of nickel monosilicide by reducing the height of polysilicon gate.

A Numerical Study on the Effects of Buildings and Topography on the Spatial Distributions of Air Pollutants in a Building-Congested District (건물 밀집 지역에서 대기오염물질 분포에 미치는 건물과 지형의 영향에 관한 수치 연구)

  • Kang, Geon;Kim, Jae-Jin;Lee, Jae-Bum
    • Korean Journal of Remote Sensing
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    • v.36 no.2_1
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    • pp.139-153
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    • 2020
  • Using a computationalfluid dynamics(CFD) model, thisstudy evaluated the representativeness of an air quality monitoring system (AQMS) in an urban area and presented a methodology to determine the suitable AQMS locations for specific purposes. For this, we selected a 1.6 km × 1.6 km area around the Eunpyeong-gu AQMS (AQMS 111181) as a target area. We conducted simulationsfor two emission scenarios (scenario one: air pollutants transported from inflow boundaries, scenario two: air pollutants emitted from roads). Urban airflows were markedly influenced by mountainous terrain located in the northeast and southeast of the target area, and complicated airflow patterns occurred around the buildings. The distributions of air pollutants were dependent on the terrain (mountain) in scenario one, but the road location and building height in scenario 2. We evaluated whether the AQMS could represent the air quality in the target area based on the simulations for two scenarios. The concentrations simulated at the AQMS were similar in magnitude to the layer mean concentrations, which indicated good representativeness for the air quality in the target area. We also suggested which locations were suitable for different measurement purposes (hot spots, clean zones, average zones, shelter zones, equi-background zones).