• 제목/요약/키워드: Laser excitation

검색결과 186건 처리시간 0.022초

Diameter Effect of Silver Nanorod Arrays to Surface-enhanced Raman Scattering

  • Gu, Geun Hoi;Kim, Min Young;Yoon, Hyeok Jin;Suh, Jung Sang
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.725-730
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    • 2014
  • The effect the diameter of silver nanorod arrays whose distance between the nanorods was uniform at 65 nm have on Surface-enhanced Raman Scattering (SERS) has been studied by varying the diameter from 28 to 51 nm. Nanorod length was fixed at approximately 62 nm, which is the optimum length for SERS by excitation with a 632.8 nm laser line. The transverse and longitudinal modes of the surface plasmon of these silver nanorods were near 400 and 630 nm, respectively. The extinction of the longitudinal mode increased with increasing nanorod diameter, while the transverse mode did not change significantly. High-quality SERS spectra of p-aminothiophenol and benzenethiol adsorbed on the tips of the silver nanorods were observed by excitation with a 632.8 nm laser line. The SERS enhancement increased with increasing nanorod diameter. We concluded that the SERS enhancement increases when the diameter of silver nanorods is increased mainly by increasing the excitation efficiency of the longitudinal mode. The enhancement factor for the silver nanorods with a 51 nm diameter was approximately $2{\times}10^7$.

Rail Inspection Using Noncontact Laser Ultrasonics

  • Kim, Nak-Hyeon;Sohn, Hoon;Han, Soon-Woo
    • 비파괴검사학회지
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    • 제32권6호
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    • pp.696-702
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    • 2012
  • In this study, a noncontact laser ultrasonic system is proposed for rail defect detection. An Nd-Yag pulse laser is used for generation of ultrasonic waves, and the corresponding ultrasonic responses are measured by a laser Doppler vibrometer. For the detection of rail surface damages, the shape of the excitation laser beam is transformed into a line. On the other hand, a point source laser beam is used for the inspection of defects inside a rail head. Then, the interactions of propagating ultrasonic waves with defects are examined using actual rail specimens. Amplitude attenuation was mainly observed for a surface crack, and reflections were most noticeable from an internal damage. Finally, opportunities and challenges associated with real-time rail inspection from a high-speed train are discussed.

음파가진에 의한 수소 확산 화염의 NOx 배출저감 및 혼합증진 (NOx Emission Reduction and Mixing Enhancement of Turbulent Hydrogen Diffusion Flame by An Acoustic Excitation)

  • 한정재;김문기;윤상욱;윤영빈
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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    • pp.305-313
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    • 2005
  • Measurements of flame length, width and NOx emissions have been conducted to investigate the effect of an acoustic excitation on flame structure in turbulent hydrogen diffusion flames with coaxial air. The resonance frequency of oscillations was varied between 259 ,514 and 728 Hz with power rate of 0.405 and 2.88w. When these frequencies imposed to hydrogen flames, dramatic reduction of flame length and NOx emission was achieved. And acetone planar laser-induced fluorescence technique was used to measure a concentration of the near field of driven axisymmetric jet. The air-fuel stoichiometric line was plotted to investigate the mixing layer and development of air entrainment to fuel jet. Consequently, acoustic excitation on flame could enhance the air-fuel mixing resulting in abatement of NOx emission quantitatively.

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초음파 여기를 이용한 물체 이송시스템의 메커니즘 연구 (A Study on the Mechanism of Object Transport System using Ultrasonic Excitation)

  • 정상화;최석봉;차경래;김광호;박준호;이경형
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2004년도 춘계학술대회 논문집
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    • pp.149-154
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    • 2004
  • In the semiconductor and the optical industry a new transport system which can replace the conventional sliding system is required. These systems are driven by magnetic field and conveyer belt. The magnetic field damages semiconductor and contact force scratches the optical lens. The ultrasonic wave driven system can solve these problem. In this paper, the relationship of transporting speed according to the change of flexural beam shape and the effect of transporting speed according to the change of weight and amplification voltage are verified. The vibration behavior of flexural beam in the ultrasonic transport system is experimented using Laser Scanning Vibrometer.

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MOVPE 단결정층 성장법 III. 원자층 성장법 (Metal-Organic Vapor Phase Epitaxy III. Atomic Layer Epitaxy)

  • 정원국
    • 한국표면공학회지
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    • 제23권4호
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    • pp.197-207
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    • 1990
  • Atomic layer epitaxy is a relatively new epitaxial pprocess chracterized by the alternate and separate exposure of a susbstrate surface to the reactants contaning the constituent element of a compound semicoductror. The ideal ALE is expected to provide sevral advantageous as petcts for growing complicated heterostrutures such as relativly easy controls of the layer thinkness down to a monolayer and in forming abrupt heterointerfaces though monolayer self-saturatio of the growth. In addition, since ALE is stongly dependent on the surface reaction, the growth can also be controlled by photo-excitation which provides activation can be energies for each step of the reaction paths. The local growth acceleration by photo-excitation can be exploited for growing several device strures on the same wafer, which provides another important practical advantage. The ALE growth of GaAs has advanced to the point the laser opertion has been achieved from AlGs/GaAs quantun well structures where thee active layers were grown by thermal and Ar-laser assisted ALE. The status of the ALE growth of GaAs and other III-V compounds will be reviewed with respect to the growth saturation behavior and the electrical properties of the grown crystals.

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Laser-Induced Fluorescence Excitation Spectrum and $CF_3$ Torsional Potential Energy Function of 7-Amino-4-(trifluoromethyl)coumarin in Its $S_1$ Electrode Excited State

  • 추재범;김택수;최영식
    • Bulletin of the Korean Chemical Society
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    • 제17권5호
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    • pp.461-463
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    • 1996
  • The laser-induced fluorescence excitation spectrum of 7-amino-4-(trifluoromethyl)coumarin in a supersonic jet has been recorded in the 340-352 nm region. The electronic band origin was observed at 28622.8 cm-1. Vibrational assignments for the three fundamental low-frequency modes and eight combination bands have been made for the S1 electronic excited state. The out-of-plane vibrations of this molecule have been characterized from the low-frequency assignments of the spectrum. The periodic potential energy function for the CF3 torsion, which satisfactorily fits the observed data, were also determined to be V(Φ)=95X(1-cos3Φ)-32X(1-cos6Φ) where Φ is the torsional angle. The relatively low torsional barrier of 99 cm-1 in S1 state could be explained by the small steric interactions between the functional groups attached to a bicyclic ring.

레이저유도 플라즈마분광법을 이용한 방사성폐기물 유리의 현장분석 시스템 개발 (Development of in-situ Analysis System for Radwaste Glass Using Laser Induced Breakdown Spectroscopy)

  • 김천우;박종길;신상운;하종현;송명재;이계호
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 학술논문집
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    • pp.137-146
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    • 2004
  • 방사성폐기물 유리화 공전 중 용융로 내에서 유리시료를 직접분석 하기 위한 레이저유도 플라즈마분광법(LIBS: Laser Induced Breakdown Spectroscopy)을 개발 중이다. LIBS 시스템을 구성하기 위하여 분광기, 검출기, 레이저 등의 장비들을 구축하였다. 분광기는 CCD(charge coupled device)가 보정되어 내장되어있는 ESA 3000을 레이저는 Q-switched Nd-YAG인 Brilliant로 구매하여 분석시스템을 구축하였다. 구축된 분석시스템 분야별 성능들을 확인하였으며 최적화 연구를 수행하였다. 첫 번째 단계로 Fe가 함유된 시료에 레이저를 주사하였을 때 발광스펙트럼을 측정하였으며 검출기의 지연시간을 변화시켰을 때의 발광스펙트럼의 특성과 이를 이용한 여기온도를 Einstein-Boltzmann 식을 이용하여 계산하였다. 시료에 532nm Nd-YAG 레이저를 주사하고 검출기의 지연시간을 500, 1000, 1500, 2000ns로 변화시켰을 때의 분광선의 intensity 및 여기온도 변화를 분석하였다. 그 결과 검출시간이 1500㎱ 일 때 여기온도는 7820k로 가장 최적의 상태를 확인하였다. 향후 이 시스템은 유리화 실증시설에 적용되어 용융로 외부로의 유리시료 이송 없이 현장에서 유리성분들의 정량분석을 수행할 예정이다.

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광학적 검출을 위한 PDMS 마이크로렌즈의 제작 (Fabrication of PDMS microlens for optical detection)

  • 박세완;김현철;전국진
    • 대한전자공학회논문지SD
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    • 제46권4호
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    • pp.15-20
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    • 2009
  • 레이저 광 산란을 이용한 검출 시스템 및 레이저를 이용한 광학적 검출에 있어서 높은 발광 강도를 통해 궁극적으로 높은 효율의 광 산란 신호를 광검출기에서 얻기 위해서는 발광 레이저빔을 미세유체 칩의 채널 중앙에 집광하는 것이 매우 중요하다. 본 논문을 통해 레이저 광 산란을 이용한 세포 검출을 위해 PDMS 마이크로렌즈가 집적화된 PDMS 미세유체 칩을 소개하고자 한다. 기존에 제작된 PDMS 미세유체 칩 위에 간편히 정렬하여 올려놓아 사용함으로써 검출 효율을 증가시킬 수 있는 PDMS 마이크로렌즈를 제작하였다. PDMS 마이크로렌즈는 포토레지스트 리플로우와 PDMS 복제 몰딩에 의해 제작되었다. 이 제작 방법은 간단하며 높은 치수 정확성 및 좋은 마이크로렌즈의 성능을 제공한다. PDMS 미세유체 칩 위에 집적화된 PDMS 마이크로렌즈가 적혈구를 이용한 레이저 광 산란을 통한 세포 검출 실험에서 레이저 강도를 증가시켜 신호대잡음비 및 감도를 증가시킴을 검증하였다.

동축류 확산화염의 불안정성과 제어에 관한 실험적 연구 (An experimental study on instability and control of co-flow diffusion flames)

  • 이현호;황준영;정석호;이원남
    • 대한기계학회논문집B
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    • 제21권1호
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    • pp.153-164
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    • 1997
  • Flame oscillation phenomena in a co-flow diffusion flame was experimentally studied with periodic fuel supply using a solenoid valve. The degree of excitation was controlled by changing the volume flux of fuel passing through the valve. Flame oscillation frequencies were measured utilizing a photodiode, a spectrum analyzer, video and high speed movies. Laser planar visualization was employed to study the correlation between the flame oscillation and the toroidal vortices. Observed are three regimes of flame oscillation, where the oscillation frequencies are for the multiples of excitation, the excitation itself and the flame natural oscillation. Both periods of natural oscillation and of excitation induced oscillation exist over one cycle of the excitation in the frequency multiplied regime. It is considered as an effect of balancing the influence of buoyancy driven vortex with that of excitation induced vortex near the excitation rate of 0.2. Flame shapes are become monotonous as increasing the excitation frequency to the range of over two fold of the natural oscillation. The flame oscillation can be modulated to the frequency of either multiples of excitation or excitation itself under certain conditions. This implies that the flame oscillation could be modulated to avoid the resonance frequency of the combustor, and shows the possibility of active control of the flame oscillation.

Two Versions of He-Ne Laser 3.39 μm with Radio Frequency Excitation

  • Kopica, Miroslaw;Choi, Jong-Woon
    • Journal of the Optical Society of Korea
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    • 제12권1호
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    • pp.31-37
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    • 2008
  • To increase output power of a He-Ne laser we propose to use the capacitive rf discharge and implement four channel structure. Most of experiments were carried out with a single laser tube from this structure to optimize the output mirror transmission, pressure and composition of the mixture. A laser tube of 2.8 mm inner diameter and 50 cm discharge length can give an output power of above 5.5 mW at 3.39 ${\mu}m$. Four such tubes in "matrix" structure let us obtain 20 mW of output. Simplified models which can be used to evaluate the behavior of an equivalent electrical circuit with laser plasma and qualitative characteristics of output power of He-Ne laser were also described.