• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.288-288
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• 2013

Lithium-ion battery (LIB) is one of the most important rechargeable battery and portable energy storage for the electric digital devices. In particular, study about the higher energy capacity and longer cycle life is intensively studied because of applications in mobile electronics and electric vehicles. Generally, the LIB's capacity can be improved by replacing anode materials with high capacitance. The graphite, common anode materials, has a good cyclability but shows limitations of capacity (~374 mAh/g). On the contrary, silicon (Si) and germanium(Ge), which is same group elements, are promising candidate for high-performance LIB electrodes because it has a higher theoretical specific capacity. (Si:4200 mAh/g, Ge:1600 mAh/g) However, it is well known that Si volume change by 400% upon full lithiation (lithium insertion into Si), which result in a mechanical pulverization and poor capacity retention during cycling. Therefore, variety of nanostructure group IV elements, including nanoparticles, nanowires, and hollow nanospheres, can be promising solution about the critical issues associated with the large volume change. However, the fundamental research about correlation between the composition and structure for LIB anode is not studied yet. Herein, we successfully synthesized various structure of nanowire such as Si-Ge, Ge-Carbon and Si-graphene core-shell types and analyzed the properties of LIB. Nanowires (NWs) were grown on stainless steel substrates using Au catalyst via VLS (Vapor Liquid Solid) mechanism. And, core-shell NWs were grown by VS (Vapor-Solid) process on the surface of NWs. In order to characterize it, we used FE-SEM, HR-TEM, and Raman spectroscopy. We measured battery property of various nanostructures for checking the capacity and cyclability by cell-tester.

• Journal of the Korean institute of surface engineering
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• v.56 no.1
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• pp.104-114
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• 2023

Three dimensional (3D) porous structures consisting of Cu@CoO core-shell-type nano-dendrites were synthesized and tested as the anode materials in lithium secondary batteries. For this purpose, first, the 3D porous films comprising Cu@Co core-shell-type nano-dendrites with various thicknesses were fabricated through the electrochemical co-deposition of Cu and Co. Then the Co shells were selectively anodized to form Co hydroxides, which was finally dehydrated to get Cu@CoO nanodendrites. The resulting electrodes exhibited very high reversible specific capacity almost 1.4~2.4 times the theoretical capacity of commercial graphite, and excellent capacity retention (~90%@50^th cycle) as compared with those of the existing transition metal oxides. From the analysis of the cumulative irreversible capacity and morphology change during charge/discharge cycling, it proved that the excellent capacity retention was attributed to the unique structural feature of our core-shell structure where only the thin CoO shell participates in the lithium storage. In addition, our electrodes showed a superb rate performance (70.5%@10.8 C-rate), most likely due to the open porous structure of 3D films, large surface area thanks to the dendritic structure, and fast electron transport through Cu core network.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.9-20
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• 2018

When a large-scale photovoltaic (PV) system is introduced into a distribution system, the customer's voltage may exceed the allowable limit ($220V{\pm}6%$) due to voltage variations and reverse power flow in the PV system. In order to solve this problem, we propose a method for adjusting the customer voltage using the existing step voltage regulator (SVR) installed in the primary feeder. However, due to the characteristics of a mechanically operating SVR, the customer voltage during the tap changing time of the SVR is likely to deviate from the allowable limit. In this paper, an energy storage system (ESS) with optimal operation strategies, and an appropriate capacity calculation algorithm are proposed, and the parallel driving scheme between the SVR and the ESS is also proposed to solve the customer voltage problem that may occur during the tap changing time of the SVR. The simulation results show that the allowable limit of the customer voltage is verified by the proposed methods during the tap changing time of the SVR when the large-scale PV system is connected to the distribution system.

• Economic and Environmental Geology
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• v.38 no.6 s.175
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• pp.717-729
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• 2005

Peak cooling load of large buildings is generally greater than their peak heating load. Internal and solar heat gains are used fur selection of adquate equipment in large building in cold winter climate like Canada and even Korea. The cost of geothermal heat exchanger to meet the cooling loads can increase the initial cost of ground source heat pump system to the extend less costly conventional system often chosen. Thermal ice storage system has been used for many years in Korea to reduce chiller capacity and shift Peak electrical time and demand. A distribution system designed to take advantage of heat extracted from the ice, and use of geothermal loop (geothermal heat exchanger) to heat as an alternate heat source and sink is well known to provide many benifits. The use of thermal energy storage (TES) reduces the heat pump capacity and peak cooling load needed in large building by as much as 40 to $60\%$ with less mechanical equipment and less space for mechanical room. Additionally TES can reduce the size and cost of the geothermal loop by 1/3 to 1/4 compared to ground coupled heat pump system that is designed to meet the peak heating and cooling load and also can eliminate difficuties of geothermal loop installation such as space requirements and thermal conditions of soil and rock at the urban area.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.4
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• pp.351-357
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• 2007

The Japanese Government selected Mutsu, Aomori Prefecture as a provisional spent-fuel repository site. This comes as a result of the prefecture's five-year campaign to host the site since 2000. Korea stores spent nuclear fuel within sites of nuclear power plants, and expects the storage capacity to reach its limit by the year 2016. This compels Korea to learn the cases of Japan. Having successfully hosted Gyeongju as a site for low-to-intermediate-level nuclear waste repository, Korea has already learned the potential process of hosting spent fuel storage site. The striking difference between the two countries in the process of hosting the site is that the Korean government had to offer the local city a large amount of subsidy for hosting through competitive citizens' referendum among candidate cities while it was the leadership of the local municipality that enabled the controversial decision in Japan. It is also a distinguishable characteristics of Japan that not a huge subsidy is provided to the local host city. I hope this study offers an idea to Korea's future effort to select a spent-fuel host site.

• Journal of the Korean Society of Safety
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• v.35 no.4
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• pp.74-83
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• 2020

In Korea, about 110,000 LPG small storage tanks of less than three tons have been installed in restaurants, houses and factories, and are used as LPG supply facilities for cooking, heating and industrial use. In the case of combustible liquefied gas storage tanks, the tank may rupture due to the temperature increase of the tank steel plate (approximately 600℃) even when the safety valve is operating normally, causing large-scale damage in an instant. Therefore, in the event of a fire near the LPG small storage tank, it is necessary to accurately predict the timing of the BLEVE(Boiling Liquid Expanding Vapour Explosion) outbreak in order to secure golden time for lifesaving and safely carry out fire extinguishing activities. In this study, we have first investigated the results of a prior study on the prediction of the occurrence of BLEVE in the horizontal tanks. And we have developed thermodynamic models and simulation program on the prediction of BLEVE that can be applied to vertical tanks used in Korea, have studied the effects of the safety valve's ability to vent, heat flux strength of external fires, size of tanks, and gas remaining in tanks on the time of BLEVE occurrence and have suggested future utilization measures.

• Solar Energy
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• v.15 no.3
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• pp.15-27
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• 1995

This study presents experimental and numerical results of the temperature characteristics, the heat transfer phenomema, and the heat storage quantity during the heat storage process with sodium phyrophosphate decahydrate($Na_4P_2O_7{\cdot}10H_2O$)-Phase Change Material(PCM) in a latent heat storage tank(cubic type). It was proved that heat transfer by conduction was dominant because PCM($Na_4P_2O_7{\cdot}10H_2O$) during heating processes was gel phase, not liquid phase The gap ratio(rate of air content) of PCM became smaller, the thermal capacity of PCM became larger, therefore the temperature distribution of PCM slowly increased than that of large gap ratio. There was maximum 15% difference between measured temperatures and calculated temperatures.

• The Transactions of the Korea Information Processing Society
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• v.4 no.3
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• pp.811-820
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• 1997

Disk arrays are using to enhance data trandfer rate and I/O performance in multimedia applications which need a high-performance storage device with large storage capacity and high-speed network.As performance varies with configuration and data layout scheme,disk array characteristic variables must be approrpriately deter-mined in desibning disk array archetecture for a speciffic applicatoin. In this paper,in order to design a disk array architecturte as a storage server of a small-scale VOD system,we evaluate performance of a disk array to chose the number of disks in the array,disk array cinfiguration,a degree of declustering for a given data block size of continous media file system and I/D request size through simulation.Simulation result shows that RAID level 5 with 5 disks ios a suitable candidate for the disk array architecture which privides MPEG-2 files with a rate of 6 Mbps,Moreover,we whow that stripe unit is 64 KB and a layout scheme is contigous placement.

• Journal of the Korean Institute of Gas
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• v.26 no.5
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• pp.49-57
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• 2022

If the hydrogen industry is activated in the future, the LH2 receiving terminal with membrane storage tank is a major way to store and send large capacity hydrogen. Since such a LH2 receiving terminal does not currently exist, the process simulation model of it was completed by referring to the design data on existing LNG receiving terminal with same typed storage tank. Based on this model, the amount of BOG generation according to change of design conditions, which is a very important factor in the operation of LH2 receiving terminal, was predicted. Through this, it was attempted to review the appropriate operating conditions to minimize the amount of BOG generated during unloading in LH2 receiving terminal with membrane storage tank.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.641-649
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• 2023

This study analyzes the cool-down process of liquid hydrogen storage tanks, which have advantages in terms of large-capacity transfer, storage, and utilization as hydrogen demand increases. A hydrogen liquefaction plant is selected for analysis and an efficient tank cooling method is sought by comparing the time required for the cool-down process with the gas consumption in connection with the gassing-up process required for the operation of the liquid hydrogen storage tank. The results of this study can be referred to in the operation process after the initial start-up and maintenance of the hydrogen liquefaction plant.