• Title/Summary/Keyword: Langmuir-blodgett(LB) method

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Electrical Properties of Organic Thin Films by Stimulus Speed (자극속도에 따른 유기박막의 전기 특성)

  • 박석순;김재민;정헌상;김창석;이권현;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.209-212
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    • 1997
  • Langmuir-Blodgett(LB) method is knowers as a unique method for preparing organic thin films, which can control thickness of the films in molecular level, and many kinds of ultra thin films of functional molecules have been prepared using this method. in this study, the electrical properties of phospholipid monolayers on a water surface was inve stigated by means of stimulus speed(40mm/min, 60mm/min).

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A Comparative Study of The Electrical Properties of Arachidic Acid L-B Film in the Al/LB/Al and Au/LB/Au Electrode Structures (Al/LB/Al, Au/LB/AU 전극구조에서 Arachidic Acid L-B막의 전기적 특성에 관한 비교 연구)

  • 오세중;김형석;이창희;김태완;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.11a
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    • pp.112-115
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    • 1993
  • We have studied a property of arachidic acid Langmuir-Blodgett films at room temperature with two different electrodes ; Al/LB/Al and Au/LB/Au. Since a natural oxide layer is formed on top of the Al electrode, the appropriate structure of AL/LB/Al is Al/Al$_2$O$_3$/LB/Al. To obtain a property of Pure LB film, Aua/LB/Au structure was made. In Al/Al$_2$O$_3$/LB/Al structure, a conductivity of 3.7${\times}$10$\^$-14/ S/cm was obtained by using current-voltage(I-V) characteristics. In Au/LB/AU structure, however, I-V curve was not able to be measured because of short current even in 51 layers of the LB film. A status of defects in the film was confirmed by copper decoration method. We have clearly seen a rather big difference of defect in those two above structures.

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Study on Morphology of Dendritic Silsesquioxane (G3-9Ph) LB Films Deposited on HOPG (HOPG 기판 위에 누적된 Dendritic Silsesquioxane (G3-9Ph) LB 박막의 모폴로지 분석)

  • Sung, Gi-Chan;Lee, Ji-Yoon;Shin, Dae-Sik;Kim, Chung-Kyun;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1234_1235
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    • 2009
  • The Langmuir-Blodgett (LB) method has been one of the most suitable techniques for fabricating organic thin films with well-controlled structures, compositions and thickness at the molecular level. We investigated the surface activity of dendrimer films at air-water interface by $\pi$-A isotherm. Also, we attempted to fabricate a G3-9Ph dendritic silsequioxane LB films. And their surface morphologies were observed by atomic force microscopy (AFM).

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A Study on the $NO_2$ Gas Detection Characteristics and Electrical Conductivity of the Octa-dodecyloxy Copper-phthalocyanine LB Films (Octa-dodecyloxy Copper- phthalocyanine LB 막의 $NO_2$가스 탐지 특성과 전기 전도도에 관한 연구)

  • Goo, Ja-Ryong;Kim, Young-Kwan;Kim, Jung-Soo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.2
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    • pp.80-85
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    • 1999
  • In this paper, $NO_2$ gas detection characteristics of Octa-dodecyloxy copper-phthalocyanine films prepared by LB method was investigated measuring the electrical conductance of these films. The electivity characteristics of these LB films exposed to $NO_2, NO, and SO_2$ gas was also investigated. Conductivity activation energy of these films as a function of temperature was obtained.

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Electric Properties of LB films Using Impedance Analysis of Quartz Crystal (수정진동자의 임피던스 분석을 이용한 LB막의 전기적 특성)

  • Jin, Chel-Nam;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.878-880
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    • 1998
  • Quartz crystal in contact with viscoelastic medium is described directly in terms of the electrical equivalent circuit of the system. Stearic acid is used as viscoelastic medium and deposited on the surface of quartz crystal using the Langmuir-Blodgett(LB) method. Impedance properties of quartz crystal coated with LB films which were investigated and the possibility of applying the technique to chemical sensing introduced.

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The Identification of Organic Vapours Using the Rheological Characteristic Analysis of Polymeric Sensitive LB Films (고분자 감응성 LB막의 유변학적인 특성분석에 의한 유기가스의 식별)

  • 강현욱;김정명;장상목;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.405-408
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    • 1996
  • The rheological changes in sensitive materials was investigated by using QCA. Langmuir-Blodgett method was used to transfer sensitive material to the quartz crystals because of its facility to control the thickness. To develop gas sensor using quartz crystal, the rheological change of sensitive LB films were observed using the resonant resistance concept. And the rheological changes as to adsorption of organic vapours were used to analyze the response mechanism between organic vapours and sensitive LB films. We considered with resonant frequency of quartz crystal to obtain one-channel gas sensor and analytical tools of organic vapours response. In our results, we analyzed the organic vapours response by the rheological changes and mass loading as to adsorption of organic vapours.

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A Study on Electroluminescence Device with Polymer (고분자를 이용한 전계발광소자에 관한 연구)

  • Lee, Jong-Chan;Lee, Cheong-Hak;Park, Su-Gil;Lim, Kee-Joe;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1219-1221
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    • 1997
  • Poly(1,4-phenylene(1-methoxyenthylene)), organic water soluble PPV precursor was synthesized for polymer electroluminescence(EL) device. To control the molecular array, deposition method of emitter was Langmuir-Blodgett(LB). PPV precursor layer was treated thermally to conversion of PPV. Optical, electrical and EL properties of PPV LB thin film was estimated. Homogeneous light emission of greenish-yellow in PPV LB thin film can be easily confirmed under normal lighting even at low driving voltage. Polymer EL device using PPV LB thin film as emitter materials had a possibility to apply to next generation display device.

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Preparation and Characterization of Cellulose Esters Langmuir-Blodgett(LB) Films (셀룰로오스 에스터의 LB 막 제조 및 분석)

  • Kim, Dong Won;Park, Sang Rae
    • Journal of the Korean Chemical Society
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    • v.38 no.2
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    • pp.87-91
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    • 1994
  • The reparation and characterization of cellulose esters LB films with various alkyl chain lengths were studied. Monolayers of cellulose triesters with medium chain length such as trioctanoate(C-8), tridecanoate(C-10), and tridodecanoate(C-12), exhibited a characteristic phase transition from expanded to condensed states. The mechanism of phase transition was discussed on the basis of the temperature dependence of the surface $pressure-area(\pi-A)$ isotherms. By the horizontal dipping method, X-type multilayers of cellulose esters were prepared and characterized using the contact angle and XPS spectra.

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Fabrication of DLPC LB films with MIS structure and I-V characteristics (MIS 구조의 DLPC LB 막의 제작과 전압-전류 특성)

  • 이우선;정용호;정종상;손경춘;김상용;장의구;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.155-158
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    • 1998
  • MLS capacitor with lipid ultra thin films were deposited by Langmuir-Blodgett (LB) method on the sillicon wafer. The current versus voltage and capacitance versus voltage relationships are depend on the applied voltage, electrode area and electrode materials. LB films deposited were made of L-$\alpha$-DLPC, the 1 layer's thickness of 35$\AA$ was measured by ellipsometer. And MLS capacitor with different electrode materials, the work function of these materials was investigated to increase the leakage current. The result indicated the lower leakage current and very high saturation value of capacitance was reached within 700-800 pF when the two electrode was Ag. And $\varepsilon$$_1$, $\varepsilon$$_2$ versus photon energy showed good film formation.

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Organic Gas Response Characteristics of Maleate Copolymer LB Films (말레에이트 공중합체 LB막의 유기 가스 반응 특성)

  • 이을식;김도균;유승엽;최용성;권영수;박재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.415-418
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    • 1998
  • The maleate copolyrner($C_{18}MA-VE_2$) is used as sensitive materials and deposited on the slide-glass substrates at room temperature using Langmuir-Blodgett(LB) method. The results of current-time(1-t) measurements are performed to investigate the gas-detection characteristics of the sensitive LB films in the presence of organic gases just as chloroform, acetone, ethanol, methanol using the apparatus for the gas-detection measurement. Several interesting responses are observed at room temperature, such as reversible response, sensitivity and response time. Response time and sensitivities are evaluated 160~220[sec], minimum 6[times], maximum 70[times] for each organic gas by adsorption and penetration of the organic gases in the relation concentration of 100[%], respectively.

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