• 제목/요약/키워드: Langmuir aggregation

검색결과 7건 처리시간 0.019초

Langmuir Aggregation of Fluorescein Isothiocyanate (FITC) on Cetyl Trimethylammonium Bromide (CTAB) and Application to Determination of Anionic Detergent in Sewage

  • Gao, Hong-Wen;Zhou, De-Yan
    • Bulletin of the Korean Chemical Society
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    • 제23권1호
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    • pp.29-34
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    • 2002
  • The microphase adsorption - spectral correction (MPASC) technique was described and applied to study the interaction of fluorescein isothiocyanate (FITC) with cetyl trimethylammonium bromide (CTAB). The synergism mechanism of micelle was analyzed and discussed. The aggregation of FITC on CTAB obeys the Langmuir monolayer adsorption. Results showed that the monomer and micellar aggregate is $FITC-CTAB_3$ and $(FITC-CTAB_3)_{29}$, respectively at pH 9.62. The adsorption constant of the CTAB-FITC aggregate was determined to be $2.10{\times}10^5$. Interestingly, it was observed for the addition of an anionic surfactant to desorb FITC from its CTAB aggregate and this has been applied to the quantitative determination of trace amounts of anionic detergent (AD) in sewage.

Interaction of Indigo Carmine with Cetyltrimethylammonium Bromide and Application to Determination of Cationic Surfactant in Wastewater

  • Wang, Hong-Yan;Gao, Hong-Wen;Zhao, Jian-Fu
    • Bulletin of the Korean Chemical Society
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    • 제24권10호
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    • pp.1444-1448
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    • 2003
  • The microsurface adsorption - spectral correction (MSASC) technique has been applied to the interaction of indigo carmine (IC) with cetyltrimethylammonium bromide (CTAB). The aggregation of IC on CTAB obeys Langmuir isothermal adsorption. The results show that both the monomer complex $IC{\cdot}CTAB$ and the micellar complex $(IC{\cdot}CTAB)_{78}$ were formed. The binding constant of the monomer complex was calculated to be $K_{IC{\cdot}CTAB}$ = 2.20 ${\times}10^5L{\cdot}mol^{-1}$, and the molar absorptivity of the micellar complex was calculated to be ${\varepsilon}_{(IC{\cdot}CTAB)78}\;^{560nm}$ = 8.58 ${\times}10^5L{\cdot}mol^{-1}{\cdot}cm^{-1}$. The aggregation was applied to the determination of cationic surfactant in wastewater.

고분자 Langmuir 박막의 표면형상 (The Surface Morphology of Polymer Langmuir Film)

  • 정치섭
    • 한국전기전자재료학회논문지
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    • 제18권1호
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    • pp.81-88
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    • 2005
  • The Langmuir monolayers of polyamic acid salts with three kinds of alkyl chains have been investigated by means of conventional $\pi$-A isotherms and second harmonic generation measurements proposed in this paper. The surface molecular density dependence of second harmonic intensity clearly shows the region of aggregation while corresponding $\pi$-A isotherm doesn't show any changes in the surface morphology at the same region. The surface morphology analysis based on the second harmonic measurement was consistent with the Brewster angle microscope measurement results.

BAM으로 관측한 PAAS L막의 특성 및 LB막의 광학적, 전기적 특성에 관한 연구 (Optical and electrical properties of the PAAS L films and LB films observed by BAM)

  • 이승엽;김태완;강도열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1725-1727
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    • 1996
  • Brewster angle microscopy(BAM) makes it possible to measure domains of Langmuir films. Especially, formation and phase transition of the PAAS Langmuir monolayers from a gas phase to a solid phase at the air-water interface were observed by the use of BAM. And also we observed the comparative images of films deposited at each phase. The UV/visible absorption spectra of this films showed molecular intensity and aggregation at each state. The electrical properties of this material were measured by current-voltage(I-V) characteristics.

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Tetrapyrazinoindoloporphyrazine Langmuir-Blodgett Films

  • Kim, Jong-Min;Jaung, Jae-Yun;Ahn, Hee-Joon
    • Macromolecular Research
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    • 제16권4호
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    • pp.367-372
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    • 2008
  • We fabricated tetra(5-n-nonyl-8-tert-butyl-2,3-pyrazino[2,3-b]indolo)porphyrazinato copper(II) (Cu-Pc-$C_8$) Langmuir-Blodgett (LB) films. We further investigated the influence of arachidic acid (AA) as a transfer promoter, as well as the effect of dipping speed, on the deposition of the films on hydrophilic and hydrophobic substrates. In the case of pure Cu-Pc-$C_8$ LB deposition on a hydrophilic substrate, the transfer ratio was close to one for up-stroke depositions, but the previously deposited film was peeled off and re-spread onto water at down-stroke depositions. Whereas the stability of the Cu-Pc-$C_8$ LB films was not improved by AA addition on hydrophilic substrates, the deposition of Cu-Pc-$C_8$ was significantly improved by the presence of AA on a hydrophobic substrate. The AA-assisted deposition had transfer ratio of close to 1 and was essentially stable up to 10-layer depositions. Comparison of the UV-visible spectrum of a Cu-Pc-$C_8$/AA LB film with that of Cu-Pc-$C_8$/AA solution in dichloroethane revealed that the Soret and Q bands for the Cu-Pc-$C_8$/AA LB film were broadened and red-shifted due to the aggregation of phthalocyanines upon assembly in the LB film.

MORPHOLOGICAL CHARACTERISTICS OF NONLINEAR OPTICAL MOLECULES AT THE AIR/WATER INTERFACE

  • Lim, Sung-Taek;Park, Mi-Kyung;Shin, Dong-Myung;Kwon, Ohoak
    • Journal of Photoscience
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    • 제5권1호
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    • pp.11-15
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    • 1998
  • The texture change of non-linear optical molecules at the air/water interface was investigated as a function of surface pressure with Brewster angle microscopy. The texture change resulted from the aggregation of dye molecules is important to understand the film uniformity and grain formation process. The 4-Octadecylhydroxy-4'-nitrostilbene (OHNS) generated the small spots of size around 1$\mu$m. The spots exhibit high contrast with other film area and do not show angle dependent reflectivity change. It is interesting to observe that the size of the domain stays the same as the film pressure increases. At high surface pressure, the contrast ratio of domains becomes high, which means dense packing of OHNS. And, the size of domain grows. In the middle of domain, highly contrasted domains are formed. The first and the second order transitions of OHNS observed from surface pressure-area isotherm result from the two types of grains. The N,N-Dihexadecylcyanoaniline (DHCA) formed highly contrasted gains over entire region, and the grains are the double layers. The difference in Langmuir film of OHNS and DHCA at the air/water interface is consistent with the small tilt angle from the surface normal for OHNS and the large tilt angle for DHCA in the Langmuir-Blodgett films.

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Fe-Mn 입자의 안정화를 통한 인산염 효율 향상 (Enhancement of phosphate removal using stabilized Fe-Mn particle)

  • 강서연;신정우;안병렬
    • 상하수도학회지
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    • 제37권6호
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    • pp.375-382
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    • 2023
  • The binary oxide adsorbent using Fe and Mn (Fe-Mn) has been prepared by precipitation method to enhance the removal of phosphate. Different amounts of chitosan, a natural organic polymer, were used during preparation of Fe-Mn as a stabilizer to protect an aggregation of Fe-Mn particles. The optimal amount of chitosan has been determined considering the separation of the Fe-Mn particles by gravity from solution and highest removal efficiency of phosphate (Fe-Mn10). The application of Fe-Mn10 increased removal efficiency at least 15% compared to bare Fe-Mn. According to the Langmuir isotherm model, the maximum uptake (qm) and affinity coefficient (b) were calculated to be 184 and 240 mg/g, and 4.28 and 7.30 L/mg for Fe-Mn and Fe-Mn10, respectively, indicating 30% and 70% increase. The effect of pH showed that the removal efficiency of phosphate was decrease with increase of pH regardless of type of adsorbent. The enhanced removal efficiency for Fe-Mn10 was maintained in entire range of pH. In the kinetics, both adsorbents obtained 70% removal efficiency within 5 min and 90% removal efficiency was achieved at 1 h. Pseudo second order (PSO) kinetic model showed higher correlation of determination (R2), suggesting chemisorption was the primary phosphate adsorption for both Fe-Mn and Fe-Mn10.